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Ambient Electrochemical Ammonia Synthesis: From Theoretical Guidance to Catalyst Design
by
Luo, Wen‐Bin
, Liu, Zhao‐Meng
, Gao, Xuan‐Wen
, Yu, Tong
, Yang, Huicong
, Li, Feng
, Sun, Zhenhua
, Mu, Jianjia
, Gu, Qin‐Fen
, Zhao, Lu‐Kang
in
Ammonia
/ Chemical bonds
/ electrocatalyst design
/ electrochemical ammonia synthesis
/ Energy consumption
/ Environmental impact
/ High temperature
/ Hydrogenation
/ nitrate reduction reaction
/ Nitrogen
/ nitrogen reduction reaction
/ Review
/ Reviews
2024
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Ambient Electrochemical Ammonia Synthesis: From Theoretical Guidance to Catalyst Design
by
Luo, Wen‐Bin
, Liu, Zhao‐Meng
, Gao, Xuan‐Wen
, Yu, Tong
, Yang, Huicong
, Li, Feng
, Sun, Zhenhua
, Mu, Jianjia
, Gu, Qin‐Fen
, Zhao, Lu‐Kang
in
Ammonia
/ Chemical bonds
/ electrocatalyst design
/ electrochemical ammonia synthesis
/ Energy consumption
/ Environmental impact
/ High temperature
/ Hydrogenation
/ nitrate reduction reaction
/ Nitrogen
/ nitrogen reduction reaction
/ Review
/ Reviews
2024
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While trying to remove the title from your shelf something went wrong :( Kindly try again later!
Do you wish to request the book?
Ambient Electrochemical Ammonia Synthesis: From Theoretical Guidance to Catalyst Design
by
Luo, Wen‐Bin
, Liu, Zhao‐Meng
, Gao, Xuan‐Wen
, Yu, Tong
, Yang, Huicong
, Li, Feng
, Sun, Zhenhua
, Mu, Jianjia
, Gu, Qin‐Fen
, Zhao, Lu‐Kang
in
Ammonia
/ Chemical bonds
/ electrocatalyst design
/ electrochemical ammonia synthesis
/ Energy consumption
/ Environmental impact
/ High temperature
/ Hydrogenation
/ nitrate reduction reaction
/ Nitrogen
/ nitrogen reduction reaction
/ Review
/ Reviews
2024
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Ambient Electrochemical Ammonia Synthesis: From Theoretical Guidance to Catalyst Design
Journal Article
Ambient Electrochemical Ammonia Synthesis: From Theoretical Guidance to Catalyst Design
2024
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Overview
Ammonia, a vital component in the synthesis of fertilizers, plastics, and explosives, is traditionally produced via the energy‐intensive and environmentally detrimental Haber–Bosch process. Given its considerable energy consumption and significant greenhouse gas emissions, there is a growing shift toward electrocatalytic ammonia synthesis as an eco‐friendly alternative. However, developing efficient electrocatalysts capable of achieving high selectivity, Faraday efficiency, and yield under ambient conditions remains a significant challenge. This review delves into the decades‐long research into electrocatalytic ammonia synthesis, highlighting the evolution of fundamental principles, theoretical descriptors, and reaction mechanisms. An in‐depth analysis of the nitrogen reduction reaction (NRR) and nitrate reduction reaction (NitRR) is provided, with a focus on their electrocatalysts. Additionally, the theories behind electrocatalyst design for ammonia synthesis are examined, including the Gibbs free energy approach, Sabatier principle, d‐band center theory, and orbital spin states. The review culminates in a comprehensive overview of the current challenges and prospective future directions in electrocatalyst development for NRR and NitRR, paving the way for more sustainable methods of ammonia production. This review delves into the decades‐long research into electrocatalytic ammonia synthesis, highlighting the evolution of fundamental principles, theoretical descriptors, and reaction mechanisms and paving the way for more sustainable methods of ammonia production.
Publisher
John Wiley & Sons, Inc,John Wiley and Sons Inc,Wiley
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