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Discovery of argon in air-hydrate crystals in a deep ice core using scanning electron microscopy and energy-dispersive X-ray spectroscopy
by
Uchida, Tsutomu
, Goto-Azuma, Kumiko
, Homma, Tomoyuki
, Kawamura, Kenji
, Shigeyama, Wataru
, Nakazawa, Fumio
, Dahl-Jensen, Dorthe
, Oyabu, Ikumi
in
Air bubbles
/ Air hydrate
/ Air temperature
/ Analytical methods
/ Argon
/ Bubbles
/ Compressed air
/ Cores
/ Crystals
/ Dispersion
/ Electron microscopes
/ Electron microscopy
/ Energy dispersive X ray spectroscopy
/ Gases
/ Glaciation
/ Hydrates
/ Ice
/ Ice cores
/ Ice sheets
/ Inert gases
/ Low temperature
/ Measurement methods
/ Neem
/ NEEM ice core
/ Nitrogen
/ Oxygen
/ Raman spectroscopy
/ Rare gases
/ Scanning electron microscopy
/ Spectrum analysis
/ Temperature changes
/ X rays
/ X-ray spectroscopy
2022
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Discovery of argon in air-hydrate crystals in a deep ice core using scanning electron microscopy and energy-dispersive X-ray spectroscopy
by
Uchida, Tsutomu
, Goto-Azuma, Kumiko
, Homma, Tomoyuki
, Kawamura, Kenji
, Shigeyama, Wataru
, Nakazawa, Fumio
, Dahl-Jensen, Dorthe
, Oyabu, Ikumi
in
Air bubbles
/ Air hydrate
/ Air temperature
/ Analytical methods
/ Argon
/ Bubbles
/ Compressed air
/ Cores
/ Crystals
/ Dispersion
/ Electron microscopes
/ Electron microscopy
/ Energy dispersive X ray spectroscopy
/ Gases
/ Glaciation
/ Hydrates
/ Ice
/ Ice cores
/ Ice sheets
/ Inert gases
/ Low temperature
/ Measurement methods
/ Neem
/ NEEM ice core
/ Nitrogen
/ Oxygen
/ Raman spectroscopy
/ Rare gases
/ Scanning electron microscopy
/ Spectrum analysis
/ Temperature changes
/ X rays
/ X-ray spectroscopy
2022
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Discovery of argon in air-hydrate crystals in a deep ice core using scanning electron microscopy and energy-dispersive X-ray spectroscopy
by
Uchida, Tsutomu
, Goto-Azuma, Kumiko
, Homma, Tomoyuki
, Kawamura, Kenji
, Shigeyama, Wataru
, Nakazawa, Fumio
, Dahl-Jensen, Dorthe
, Oyabu, Ikumi
in
Air bubbles
/ Air hydrate
/ Air temperature
/ Analytical methods
/ Argon
/ Bubbles
/ Compressed air
/ Cores
/ Crystals
/ Dispersion
/ Electron microscopes
/ Electron microscopy
/ Energy dispersive X ray spectroscopy
/ Gases
/ Glaciation
/ Hydrates
/ Ice
/ Ice cores
/ Ice sheets
/ Inert gases
/ Low temperature
/ Measurement methods
/ Neem
/ NEEM ice core
/ Nitrogen
/ Oxygen
/ Raman spectroscopy
/ Rare gases
/ Scanning electron microscopy
/ Spectrum analysis
/ Temperature changes
/ X rays
/ X-ray spectroscopy
2022
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Discovery of argon in air-hydrate crystals in a deep ice core using scanning electron microscopy and energy-dispersive X-ray spectroscopy
Journal Article
Discovery of argon in air-hydrate crystals in a deep ice core using scanning electron microscopy and energy-dispersive X-ray spectroscopy
2022
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Overview
Tiny samples of ancient atmosphere in air bubbles within ice cores contain argon (Ar), which can be used to reconstruct past temperature changes. At a sufficient depth, the air bubbles are compressed by the overburden pressure under low temperature and transform into air-hydrate crystals. While the oxygen (O2) and nitrogen (N2) molecules have indeed been identified in the air-hydrate crystals with Raman spectroscopy, direct observational knowledge of the distribution of Ar at depth within ice sheet and its enclathration has been lacking. In this study, we applied scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDS) to five air-hydrate crystals in the Greenland NEEM ice core, finding them to contain Ar and N. Given that Ar cannot be detected by Raman spectroscopy, the method commonly used for O2 and N2, the SEM-EDS measurement method may become increasingly useful for measuring inert gases in deep ice cores.
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