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Terminology of metal–organic frameworks and coordination polymers (IUPAC Recommendations 2013)
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Terminology of metal–organic frameworks and coordination polymers (IUPAC Recommendations 2013)
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Journal Article
Terminology of metal–organic frameworks and coordination polymers (IUPAC Recommendations 2013)
2013
Overview
A set of terms, definitions, and recommendations is provided for use in the
classification of coordination polymers, networks, and metal–organic frameworks
(MOFs). A hierarchical terminology is recommended in which the most general term
is coordination polymer. Coordination networks are a subset of coordination
polymers and MOFs a further subset of coordination networks. One of the criteria
an MOF needs to fulfill is that it contains potential voids, but no physical
measurements of porosity or other properties are demanded per se. The use of
topology and topology descriptors to enhance the description of crystal
structures of MOFs and 3D-coordination polymers is furthermore strongly
recommended.
Publisher
De Gruyter,Walter de Gruyter GmbH
Subject
