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Highly ordered arrays of hat-shaped hierarchical nanostructures with different curvatures for sensitive SERS and plasmon-driven catalysis
by
Shao, Mingrui
, Li, Zhen
, Ji, Chang
, Zhang, Chao
, Yu, Jing
, Li, Zhaoxiang
, Wang, Guangcan
, Zhao, Xiaofei
, Qiu, Si
, Lu, Weixi
in
Catalysis
/ Catalytic converters
/ Curvature
/ Energy harvesting
/ hat-shaped nanostructures
/ Hybrid structures
/ Metal particles
/ Molybdenum disulfide
/ Nanoparticles
/ Nanostructure
/ Polystyrene resins
/ Raman spectra
/ Self-assembly
/ SERS
/ Substrates
/ surfacecatalyticreaction
2022
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Highly ordered arrays of hat-shaped hierarchical nanostructures with different curvatures for sensitive SERS and plasmon-driven catalysis
by
Shao, Mingrui
, Li, Zhen
, Ji, Chang
, Zhang, Chao
, Yu, Jing
, Li, Zhaoxiang
, Wang, Guangcan
, Zhao, Xiaofei
, Qiu, Si
, Lu, Weixi
in
Catalysis
/ Catalytic converters
/ Curvature
/ Energy harvesting
/ hat-shaped nanostructures
/ Hybrid structures
/ Metal particles
/ Molybdenum disulfide
/ Nanoparticles
/ Nanostructure
/ Polystyrene resins
/ Raman spectra
/ Self-assembly
/ SERS
/ Substrates
/ surfacecatalyticreaction
2022
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Highly ordered arrays of hat-shaped hierarchical nanostructures with different curvatures for sensitive SERS and plasmon-driven catalysis
by
Shao, Mingrui
, Li, Zhen
, Ji, Chang
, Zhang, Chao
, Yu, Jing
, Li, Zhaoxiang
, Wang, Guangcan
, Zhao, Xiaofei
, Qiu, Si
, Lu, Weixi
in
Catalysis
/ Catalytic converters
/ Curvature
/ Energy harvesting
/ hat-shaped nanostructures
/ Hybrid structures
/ Metal particles
/ Molybdenum disulfide
/ Nanoparticles
/ Nanostructure
/ Polystyrene resins
/ Raman spectra
/ Self-assembly
/ SERS
/ Substrates
/ surfacecatalyticreaction
2022
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Highly ordered arrays of hat-shaped hierarchical nanostructures with different curvatures for sensitive SERS and plasmon-driven catalysis
Journal Article
Highly ordered arrays of hat-shaped hierarchical nanostructures with different curvatures for sensitive SERS and plasmon-driven catalysis
2022
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Overview
Regulation of hot spots exhibits excellent potential in many applications including nanolasers, energy harvesting, sensing, and subwavelength imaging. Here, hat-shaped hierarchical nanostructures with different space curvatures have been proposed to enhance hot spots for facilitating surface-enhanced Raman scattering (SERS) and plasmon-driven catalysis applications. These novel nanostructures comprise two layers of metal nanoparticles separated by hat-shaped MoS
films. The fabrication of this hybrid structure is based on the thermal annealing and thermal evaporation of self-assembled polystyrene spheres, which are convenient to control the metal particle size and the curvature of hat-shaped nanostructures. Based on the narrow gaps produced by the MoS
films and the curvature of space, the constructed platform exhibits superior SERS capability and achieves ultrasensitive detection for toxic molecules. Furthermore, the surface catalytic conversion of p-nitrothiophenol (PNTP) to p, p′-dimercaptobenzene (DMAB) was
monitored by the SERS substrate. The mechanism governing this regulation of hot spots is also investigated via theoretical simulations.
Publisher
De Gruyter,John Wiley & Sons, Inc,Wiley
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