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Imaging Bond Formation Between a Gold Atom and Pentacene on an Insulating Surface
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Journal Article
Imaging Bond Formation Between a Gold Atom and Pentacene on an Insulating Surface
2006
Overview
A covalent bond between an individual pentacene molecule and a gold atom was formed by means of single-molecule chemistry inside a scanning tunneling microscope junction. The bond formation is reversible, and different structural isomers can be produced. The single-molecule synthesis was done on ultrathin insulating films that electronically isolated the reactants and products from their environment. Direct imaging of the orbital hybridization upon bond formation provides insight into the energetic shifts and occupation of the molecular resonances.
Publisher
American Association for the Advancement of Science,The American Association for the Advancement of Science
Subject
/ Condensed matter: electronic structure, electrical, magnetic, and optical properties
/ Condensed matter: structure, mechanical and thermal properties
/ Exact sciences and technology
/ Gold
/ Isomers
/ Physics
/ scanning tunneling microscopy
/ Solid surfaces and solid-solid interfaces
/ Surface and interface electron states
/ Surfaces and interfaces; thin films and whiskers (structure and nonelectronic properties)
