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Interwoven Metal-Organic Framework on a Periodic Minimal Surface with Extra-Large Pores
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Interwoven Metal-Organic Framework on a Periodic Minimal Surface with Extra-Large Pores
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Journal Article
Interwoven Metal-Organic Framework on a Periodic Minimal Surface with Extra-Large Pores
2001
Overview
Interpenetration (catenation) has long been considered a major impediment in the achievement of stable and porous crystalline structures. A strategy for the design of highly porous and structurally stable networks makes use of metal-organic building blocks that can be assembled on a triply periodic P-minimal geometric surface to produce structures that are interpenetrating-more accurately considered as interwoven. We used 4,4′,4″-benzene-1,3,5-triyl-tribenzoic acid (H3BTB), copper(II) nitrate, and N, N′-dimethylformamide (DMF) to prepare Cu3(BTB)2(H2O)3· (DMF)9(H2O)2(MOF-14), whose structure reveals a pair of interwoven metal-organic frameworks that are mutually reinforced. The structure contains remarkably large pores, 16.4 angstroms in diameter, in which voluminous amounts of gases and organic solvents can be reversibly sorbed.
Publisher
American Society for the Advancement of Science,American Association for the Advancement of Science,The American Association for the Advancement of Science
Subject
/ Atoms
/ Colloidal state and disperse state
/ Condensed matter: structure, mechanical and thermal properties
/ Exact sciences and technology
/ General and physical chemistry
/ Physics
/ Porosity
/ Solvents
/ Sorption
/ Structure of solids and liquids; crystallography
/ Structure of specific crystalline solids
/ Vertices
