Asset Details
Do you wish to reserve the book?
{Gd III 7 } and {Gd III 14 } Cluster Formation Based on a Rhodamine 6G Ligand with a Magnetocaloric Effect
Hey, we have placed the reservation for you!
By the way, why not check out events that you can attend while you pick your title.
Oops! Something went wrong.
Looks like we were not able to place the reservation. Kindly try again later.
Are you sure you want to remove the book from the shelf?
{Gd III 7 } and {Gd III 14 } Cluster Formation Based on a Rhodamine 6G Ligand with a Magnetocaloric Effect
Do you wish to request the book?
{Gd III 7 } and {Gd III 14 } Cluster Formation Based on a Rhodamine 6G Ligand with a Magnetocaloric Effect
Please be aware that the book you have requested cannot be checked out. If you would like to checkout this book, you can reserve another copy
We have requested the book for you!
Your request is successful and it will be processed during the Library working hours. Please check the status of your request in My Requests.
Oops! Something went wrong.
Looks like we were not able to place your request. Kindly try again later.
Journal Article
{Gd III 7 } and {Gd III 14 } Cluster Formation Based on a Rhodamine 6G Ligand with a Magnetocaloric Effect
2024
Overview
Heptanuclear {Gd
} (complex
) and tetradecanuclear {Gd
} (complex
) were synthesized using the rhodamine 6G ligand HL (rhodamine 6G salicylaldehyde hydrazone) and characterized. Complex
has a rare disc-shaped structure, where the central Gd ion is connected to the six peripheral Gd
ions via CH
O
/μ
-OH
bridges. Complex
has an unexpected three-layer double sandwich structure with a rare μ
-O
ion in the center of the cluster. Magnetic studies revealed that complex
exhibits a magnetic entropy change of 17.4 J kg
K
at 3 K and 5 T. On the other hand, complex
shows a higher magnetic entropy change of 22.3 J kg
K
at 2 K and 5 T.
Publisher
MDPI AG
