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Controlled Synthesis of Statistical Polycarbonates Based on Epoxides and CO2
by
Troll, Carsten
, Rieger, Bernhard
, Denk, Alina
, Fulajtar, Emilia
in
aliphatic polycarbonates
/ Bisphenol A
/ Carbon dioxide
/ copolymer engineering
/ Differential scanning calorimetry
/ dosing systems
/ Epoxides
/ Gel chromatography
/ Gel diffusion
/ Limonene
/ Magnetic resonance spectroscopy
/ Monomers
/ NMR
/ NMR spectroscopy
/ Nuclear magnetic resonance
/ Polymerization
/ Polymers
/ Propylene oxide
/ Spectroscopic analysis
/ statistical terpolymers
/ Statistics
/ Synthesis
/ Terpolymerization
/ Terpolymers
2023
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Controlled Synthesis of Statistical Polycarbonates Based on Epoxides and CO2
by
Troll, Carsten
, Rieger, Bernhard
, Denk, Alina
, Fulajtar, Emilia
in
aliphatic polycarbonates
/ Bisphenol A
/ Carbon dioxide
/ copolymer engineering
/ Differential scanning calorimetry
/ dosing systems
/ Epoxides
/ Gel chromatography
/ Gel diffusion
/ Limonene
/ Magnetic resonance spectroscopy
/ Monomers
/ NMR
/ NMR spectroscopy
/ Nuclear magnetic resonance
/ Polymerization
/ Polymers
/ Propylene oxide
/ Spectroscopic analysis
/ statistical terpolymers
/ Statistics
/ Synthesis
/ Terpolymerization
/ Terpolymers
2023
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Controlled Synthesis of Statistical Polycarbonates Based on Epoxides and CO2
by
Troll, Carsten
, Rieger, Bernhard
, Denk, Alina
, Fulajtar, Emilia
in
aliphatic polycarbonates
/ Bisphenol A
/ Carbon dioxide
/ copolymer engineering
/ Differential scanning calorimetry
/ dosing systems
/ Epoxides
/ Gel chromatography
/ Gel diffusion
/ Limonene
/ Magnetic resonance spectroscopy
/ Monomers
/ NMR
/ NMR spectroscopy
/ Nuclear magnetic resonance
/ Polymerization
/ Polymers
/ Propylene oxide
/ Spectroscopic analysis
/ statistical terpolymers
/ Statistics
/ Synthesis
/ Terpolymerization
/ Terpolymers
2023
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Controlled Synthesis of Statistical Polycarbonates Based on Epoxides and CO2
Journal Article
Controlled Synthesis of Statistical Polycarbonates Based on Epoxides and CO2
2023
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Overview
The controlled synthesis of terpolymer structures is often limited by the intrinsic reactivities of the monomers. For the synthesis of a statistical terpolymer from cyclohexene oxide (CHO) and propylene oxide (PO) with CO2, an instrumental solution is demanded. Implementing a setup where one monomer can be added to the reaction mixture over the whole course of the reaction, the random distribution of the epoxides over the whole chain is realized. The successful terpolymerization can be determined with diffusion‐ordered nuclear magnetic resonance spectroscopy and gel permeation chromatography measurements while the statistical microstructure of the generated polymers is indicated in NMR spectroscopy and differential scanning calorimetry measurements. Furthermore, the concept is transferred to the terpolymerization of limonene oxide with PO and CO2 underlining the versatility of the setup.
Publisher
John Wiley & Sons, Inc,Wiley-VCH
Subject
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