Journal Article

Carbon Nanofibers Synthesized at Different Pressures for Detection of NOsub.2 at Room Temperature

Bannov, Alexander G, Larina, Tatyana V, Kurdyumov, Dmitry S, Kurmashov, Pavel B, Ishchenko, Arcady V, Chesalov, Yurii A, Lapekin, Nikita I, Sysoev, Vitalii I, Maksimovskiy, Evgene A, Ukhina, Arina V

2023

Overview

In this paper, room-temperature chemiresistive gas sensors for NO[sub.2] detection based on CVD-grown carbon nanofibers (CNFs) were investigated. Transmission electron microscopy, low-temperature nitrogen adsorption, and X-ray diffraction were used to investigate the carbon nanomaterials. CNFs were synthesized in a wide range of pressure (1–5 bar) by CO[sub.x] -free decomposition of methane over the Ni/Al[sub.2] O[sub.3] catalyst. It was found that the increase in pressure during the synthesis of CNFs induced the later deactivation of the catalyst, and the yield of CNFs decreased when increasing pressure. Sensing properties were determined in a dynamic flow-through installation at NO[sub.2] concentrations ranging from 1 to 400 ppm. Ammonia detection was tested for comparison in a range of 100–500 ppm. The obtained sensors based on CNFs synthesized at 1 bar showed high responses of 1.7%, 5.0%, and 10.0% to 1 ppm, 5 ppm, and 10 ppm NO[sub.2] at 25 ± 2 °C, respectively. It was shown that the obtained non-modified carbon nanomaterials can be used successfully used for room temperature detection of nitrogen dioxide. It was found that the increase in relative humidity (RH) of air induced growth of response, and this effect was facilitated after reaching RH ~35% for CNFs synthesized at elevated pressures.

• Publisher: MDPI AG
• Subject: Nanotubes / Production processes