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PRECISE WAVELENGTHS OF 4P right arrow nd sup.2D.sub.3/2,5/2 RYDBERG TRANSITIONS IN NEUTRAL POTASSIUM CALCULATED VIA THE SCREENING CONSTANT PER UNIT NUCLEAR CHARGE METHOD
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PRECISE WAVELENGTHS OF 4P right arrow nd sup.2D.sub.3/2,5/2 RYDBERG TRANSITIONS IN NEUTRAL POTASSIUM CALCULATED VIA THE SCREENING CONSTANT PER UNIT NUCLEAR CHARGE METHOD
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PRECISE WAVELENGTHS OF 4P right arrow nd sup.2D.sub.3/2,5/2 RYDBERG TRANSITIONS IN NEUTRAL POTASSIUM CALCULATED VIA THE SCREENING CONSTANT PER UNIT NUCLEAR CHARGE METHOD
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Journal Article
PRECISE WAVELENGTHS OF 4P right arrow nd sup.2D.sub.3/2,5/2 RYDBERG TRANSITIONS IN NEUTRAL POTASSIUM CALCULATED VIA THE SCREENING CONSTANT PER UNIT NUCLEAR CHARGE METHOD
2023
Overview
Photoionization of neutral potassium K I is investigated in the framework of the screening constant per unit nu-clear charge (SCUNC) method. Transition energies and wavelengths belonging to 4p([sup.2][P.sub.1/2] [right arrow] nd [sup.2][D.sub.3/2] and 4p([sup.2][P.sub.3/2]) [right arrow] nd [D.sub.3/2,5/2] Rydberg transitions are reported. Accurate transition energies and wavelengths originating from 4p([sup.2][P.sub.1/2,3/2]) levels of KI are tabulated for 20 [less than or equal to] n [less than or equal to] 100. The SCUNC wavelengths are believed to be the first calculations that agree excellently with the existing experimental measurements up to n = 70 using linearly polarized laser light. The maximum shift in wavelengths relative to the experimental data is at 0.03 nm up to n = 70. New wavelengths are tabulated for n = 71-100 along with new transition energies for n = 20-100.
Publisher
Springer
Subject
