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Metal complexes of a novel bis-β-diketone-type ligand and its copper（II） complexes of two-photon biological imaging
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Metal complexes of a novel bis-β-diketone-type ligand and its copper（II） complexes of two-photon biological imaging
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Journal Article
Metal complexes of a novel bis-β-diketone-type ligand and its copper（II） complexes of two-photon biological imaging
2012
Overview
A curcumin derivative ligand, 1,7-bis（3-methoxyl-4-acetoxyl）phenyl-1,6-heptadiene-3,5-diketone （diacetylcurcumin, abbrevi- ated as HL）, and its Cu and Ni complexes have been synthesized and fully characterized by elemental analyses, IR, 1HNMR and molar conductivity. The resulting complexes exhibit two-photon excited fluorescence （TPEF） in DMF, and have been proven to be potentially useful for two-photon microscopy imaging in living cells. In addition, cytotoxicity tests showed that the low-micromolar concentrations of ML2 did not cause significant reduction in cell viability over a period of at least 24 h and should be safe for further biological studies.
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