Asset Details
Do you wish to reserve the book?
Cyanido-bridged one-dimensional systems assembled from ReIVCI4（CN）22- and Mn（cyclam）2＋ （M = Ni, Cu） precursors
Hey, we have placed the reservation for you!
By the way, why not check out events that you can attend while you pick your title.
Oops! Something went wrong.
Looks like we were not able to place the reservation. Kindly try again later.
Are you sure you want to remove the book from the shelf?
Cyanido-bridged one-dimensional systems assembled from ReIVCI4（CN）22- and Mn（cyclam）2＋ （M = Ni, Cu） precursors
Do you wish to request the book?
Cyanido-bridged one-dimensional systems assembled from ReIVCI4（CN）22- and Mn（cyclam）2＋ （M = Ni, Cu） precursors
Please be aware that the book you have requested cannot be checked out. If you would like to checkout this book, you can reserve another copy
We have requested the book for you!
Your request is successful and it will be processed during the Library working hours. Please check the status of your request in My Requests.
Oops! Something went wrong.
Looks like we were not able to place your request. Kindly try again later.
Journal Article
Cyanido-bridged one-dimensional systems assembled from ReIVCI4（CN）22- and Mn（cyclam）2＋ （M = Ni, Cu） precursors
2012
Overview
Three new cyanido-bridged heterometallic ReIVNin and ReIVCu one-dimensional systems were synthesized and extensively characterized both structurally and magnetically. Single-crystal X-ray diffraction analysis revealed that these compounds display a common topology, with chains composed of alternating [RetVc14（CN）2]2- and [Mn（cyclam）]2＋ （M = Ni in 1, Cu in 2） or [Cull（N,N＇-dimethylcyclam）]2＋ （in 3） building units. Two different chain orientations with a tilt angle of ca. 51° to 55° are present in the crystal packing of these compounds. The magnetic susceptibility measurements suggest the presence of intrachain ferromagnetic interactions between the S = 3/2 ReTM centers and the 3d metal ions： S = 1 Ni1I or S = 1/2 CuII. At low temperature, a three-dimensional ordered magnetic phase induced by interchain antiferromagnetic interactions （antiferromagnetic for 1 and 2; canted antiferromagnetic for 3） is detected for the three compounds.
