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A self-assembled （H2O）20（CH3OH）4 binary cluster containing a grail-shaped hexadecameric water cluster trapped in the cavity of a metal-ligand hybrid
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A self-assembled （H2O）20（CH3OH）4 binary cluster containing a grail-shaped hexadecameric water cluster trapped in the cavity of a metal-ligand hybrid
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A self-assembled （H2O）20（CH3OH）4 binary cluster containing a grail-shaped hexadecameric water cluster trapped in the cavity of a metal-ligand hybrid
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Journal Article
A self-assembled （H2O）20（CH3OH）4 binary cluster containing a grail-shaped hexadecameric water cluster trapped in the cavity of a metal-ligand hybrid
2012
Overview
A discrete centrosymmetric （H2O）20（CH3OH）4 binary cluster was confined in the cavity of a metaMigand hybrid [Ag4（bpda）2（bpp）4＂ 14H2O.2CH3OH], （1） （where bpp = 1,3-bis（4-pyridyl）propane and H2bpda = 2,2＇-biphenyldicarboxylic acid） The novel mixed water-methanol cluster consists of one grail-shaped hexadecameric cluster, four dangling water and four hanging methanol molecules. The （H2O）16 cluster is composed of two pairs of edge-sharing （H2O）5 rings attached to one （H2O）4 core with twenty hydrogen bonds. Alternatively, the （H2O）16 cluster is structurally similar to a complicated hydrocarbon generated by undergoing [2＋2] cycloaddition of 1,2,3,4,5,6-hexahydropentalene, which reveals the resemblance between water clusters and organic compounds.
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