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Nanoporous Fe-doped BiVO.sub.4 Modified with MIL-53
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Nanoporous Fe-doped BiVO.sub.4 Modified with MIL-53
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Journal Article
Nanoporous Fe-doped BiVO.sub.4 Modified with MIL-53
2019
Overview
Great interest has been attracted to enhancing the photoelectrochemical performances of BiVO.sub.4. However, there have rarely been reported about addressing their PEC stability. Herein, it is proposed that Fe ions doping could enhance the stability and PEC performances of BiVO.sub.4, which may because it could improve the crystalline structure and eliminates the crystal defects of BiVO.sub.4. Moreover, it is found that metal-organic framework can play a co-catalyst role during the PEC experiments. We designed and fabricated nanoporous Fe-doped BiVO.sub.4 modified with MIL-53(Fe), which exhibits much higher PEC performance and stability than pristine BiVO.sub.4 and Fe-doped BiVO.sub.4. It is believed that MIL-53(Fe) can capture the photogenerated holes and thus facilitates the charge separation efficiency.
Publisher
Springer
Subject
