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Metastable alpha-AgVO.sub.3 microrods as peroxidase mimetics for colorimetric determination of H.sub.2O.sub.2
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Metastable alpha-AgVO.sub.3 microrods as peroxidase mimetics for colorimetric determination of H.sub.2O.sub.2
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Metastable alpha-AgVO.sub.3 microrods as peroxidase mimetics for colorimetric determination of H.sub.2O.sub.2
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Journal Article
Metastable alpha-AgVO.sub.3 microrods as peroxidase mimetics for colorimetric determination of H.sub.2O.sub.2
2018
Overview
Single phase metastable [alpha]-AgVO.sub.3 microrods with high crystallinity, tetragonal rod-like microstructure, uniform particle size distribution, and good dispersion were synthesized by direct coprecipitation at room temperature. They are shown to be viable peroxidase mimics that catalyze the oxidation of 3,3',5,5'-tetramethylbenzidine in the presence of H.sub.2O.sub.2. Kinetic analysis indicated typical Michaelis-Menten catalytic behavior. The findings were used to design a colorimetric assay for H.sub.2O.sub.2, best measured at 652 nm. The method has a linear response in the 60 to 200 [mu]M H.sub.2O.sub.2 concentration range, with a 2 [mu]M detection limit. Benefitting from the chemical stability of the microrods, the method is well reproducible. It also is easily performed and highly specific.
Publisher
Springer
Subject
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