Journal Article

Superior Strength-Ductility Synergy Enabled by Dual-Level Heterostructure of L1sub.2 Precipitates and Local Chemical Order in a MPEA

Zhang, Jingjing, Shen, Yongfeng, Fan, Zhijian, Xue, Wenying

2026

Overview

The trade-off between strength and ductility remains a pivotal challenge in the development of multi-principal element alloys (MPEAs) for structural applications. Here, we report a dual-scale ordering strategy to achieve triple strengthening in a Ni-26.6Co-18.4Cr-5.4Nb-4.1Mo-2.3Al-0.3Ti-0.05Y (wt.%) MPEA through the synergistic interplay of L1[sub.2] nanoprecipitates and local chemical order (LCO). The alloy was processed via cold rolling followed by aging at 750 °C for 8 h, resulting in a high density of coherent L1[sub.2] precipitates (average size 47 ± 1 nm, volume fraction 27%) with an ultra-low lattice misfit of 0.5%. Additionally, sub-nanoscale LCO domains with an average diameter of 0.62 nm were identified within the face-centered cubic matrix. This hierarchical microstructure yields an exceptional combination of mechanical properties at room temperature: yield strength of 1480 ± 6 MPa, ultimate tensile strength of 1678 ± 10 MPa, and a total elongation of 13.9 ± 0.2%. Quantitative strengthening analysis reveals that precipitation strengthening (697 MPa) is the dominant contributor, followed by dislocation strengthening (397 MPa). Transmission electron microscopy characterization of deformed samples reveals that the low stacking fault energy, promoted by LCO, facilitates the dissociation of perfect dislocations and the formation of extensive stacking faults. The intersection of stacking faults on different 111 planes generates a large number of Lomer–Cottrell locks, which significantly enhance work hardening and delay plastic instability. The findings demonstrate that engineering dual-scale ordered structures offers a promising pathway for developing MPEAs with a superior strength-ductility combination.

• Publisher: MDPI AG
• Subject: Alloys