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Ag^sub 2^S/Bi^sub 2^S^sub 3^ co-sensitized TiO2 nanorod arrays prepared on conductive glass as a photoanode for solar cells
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Ag^sub 2^S/Bi^sub 2^S^sub 3^ co-sensitized TiO2 nanorod arrays prepared on conductive glass as a photoanode for solar cells
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Journal Article
Ag^sub 2^S/Bi^sub 2^S^sub 3^ co-sensitized TiO2 nanorod arrays prepared on conductive glass as a photoanode for solar cells
2016
Overview
TiO2 nanorod arrays (TiO2 NRAs) were synthesized through a hydrothermal method. Ag^sub 2^S and Bi^sub 2^S^sub 3^ were then grown on the surface of TiO2 NRAs with successive ionic layer adsorption and reaction method. The pristine rutile TiO2 NRAs, Ag^sub 2^S/TiO2, Bi^sub 2^S^sub 3^/TiO2, and Bi^sub 2^S^sub 3^/Ag^sub 2^S/TiO2 electrodes were characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, ultraviolet-visible absorption spectroscopy, and electrochemical analysis. According to photoelectrochemical (PEC) measurement, an enhanced short circuit current density was obtained for the co-sensitized TiO2 NRAs under simulated sunlight illumination, which was 10.7 times higher than that of the TiO2 NRAs. Appropriate potential positions of conduction band and valence band of Bi^sub 2^S^sub 3^ that match well those of rutile TiO2 NARs and Ag^sub 2^S lead to the improved PEC performance. In addition, the PEC property of the co-sensitized TiO2 NRAs under visible light irradiation was also investigated and showed a dramatically enhanced photocurrent response.
Publisher
Springer Nature B.V
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