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Simultaneously enhanced ferroelectric and magnetic properties in 0.675BiFe^sub 1-x^Cr^sub x^O3-0.325PbTiO3 (x = 0-0.05) ceramics
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Simultaneously enhanced ferroelectric and magnetic properties in 0.675BiFe^sub 1-x^Cr^sub x^O3-0.325PbTiO3 (x = 0-0.05) ceramics
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Simultaneously enhanced ferroelectric and magnetic properties in 0.675BiFe^sub 1-x^Cr^sub x^O3-0.325PbTiO3 (x = 0-0.05) ceramics
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Journal Article
Simultaneously enhanced ferroelectric and magnetic properties in 0.675BiFe^sub 1-x^Cr^sub x^O3-0.325PbTiO3 (x = 0-0.05) ceramics
2017
Overview
Multiferroic ceramics of 0.675BiFe1-xCrxO3-0.325PbTiO3 (x = 0, 0.01, 0.025, 0.05) were prepared and comparatively investigated. The rhombohedral-tetragonal morphotropic phase boundary (MPB) was formed in 0.675BiFeO3-0.325PbTiO3. The B-site Cr-substitution changes the structure from MPB to rhombohedral phase gradually, accompanied with monotonously decreased ferroelectric Curie temperature and average grain size. More interestingly, Such Cr-substitution enhances room temperature ferroelectric and magnetic properties simultaneously. The underlying mechanism is mainly attributed to the substitution enhanced local Fe3+-Cr3+ magnetic interaction and the suppressed oxygen vacancy effect. We believe these results are helpful supplements for optimizing structures and room temperature multiferroic properties of BiFeO3-based materials.
Publisher
Springer Nature B.V
Subject
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