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Influence of Crystallization on Molecular Dynamics of the Amorphous Phase in Poly( epsilon -caprolactone) and Poly( epsilon -caprolactone)/LiClO sub(4) Complexes Investigated by Dielectric Relaxation Spectroscopy
Influence of Crystallization on Molecular Dynamics of the Amorphous Phase in Poly( epsilon -caprolactone) and Poly( epsilon -caprolactone)/LiClO sub(4) Complexes Investigated by Dielectric Relaxation Spectroscopy
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Influence of Crystallization on Molecular Dynamics of the Amorphous Phase in Poly( epsilon -caprolactone) and Poly( epsilon -caprolactone)/LiClO sub(4) Complexes Investigated by Dielectric Relaxation Spectroscopy
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Influence of Crystallization on Molecular Dynamics of the Amorphous Phase in Poly( epsilon -caprolactone) and Poly( epsilon -caprolactone)/LiClO sub(4) Complexes Investigated by Dielectric Relaxation Spectroscopy
Influence of Crystallization on Molecular Dynamics of the Amorphous Phase in Poly( epsilon -caprolactone) and Poly( epsilon -caprolactone)/LiClO sub(4) Complexes Investigated by Dielectric Relaxation Spectroscopy

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Influence of Crystallization on Molecular Dynamics of the Amorphous Phase in Poly( epsilon -caprolactone) and Poly( epsilon -caprolactone)/LiClO sub(4) Complexes Investigated by Dielectric Relaxation Spectroscopy
Influence of Crystallization on Molecular Dynamics of the Amorphous Phase in Poly( epsilon -caprolactone) and Poly( epsilon -caprolactone)/LiClO sub(4) Complexes Investigated by Dielectric Relaxation Spectroscopy
Journal Article

Influence of Crystallization on Molecular Dynamics of the Amorphous Phase in Poly( epsilon -caprolactone) and Poly( epsilon -caprolactone)/LiClO sub(4) Complexes Investigated by Dielectric Relaxation Spectroscopy

2013
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Overview
The dielectric relaxation spectroscopy results indicate that the relaxation peak of PCL for pure PCL and PCL/LiClO sub(4) complexes shifts to a lower frequency with increasing crystallization temperature, while the amorphous, condensed structure of PCL for pure PCL and PCL/LiClO sub(4) complexes is slightly affected by crystallization temperature. These findings were obtained from small-angle X-ray scattering (SAXS) measurements. To further understand the effect of crystallization temperature on the relaxation behavior of PCL and PCL/LiClO sub(4) complexes, the isothermal crystallization process of PCL and PCL/LiClO sub(4) was probed in situ by dielectric spectra measurement. The analysis indicated that the relaxation dynamics for pure PCL and PCL/LiClO sub(4) complexes decrease continuously during the isothermal crystallization process, even at the crystallization induction period. This paper presents a detailed discussion of the crystallization mechanisms of the PCL and PCL/LiClO sub(4) complexes, and the probable explanation as to the effect of crystallization temperature on the relaxation dynamics of PCL and PCL/LiClO sub(4) .
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