Journal Article

MoO 3 Nanoparticle Coatings on High-Voltage 5 V LiNi 0.5 Mn 1.5 O 4 Cathode Materials for Improving Lithium-Ion Battery Performance

Li, Ying-Jeng James, Hung, Tai-Feng, Tsai, Yi-De, Yang, Chun-Chen, Shih, Jeng-Ywan, Jose, Rajan, Wu, Zong-Han, Karuppiah, Chelladurai

2022

Overview

To reduce surface contamination and increase battery life, MoO nanoparticles were coated with a high-voltage (5 V) LiNi Mn O cathode material by in-situ method during the high-temperature annealing process. To avoid charging by more than 5 V, we also developed a system based on anode-limited full-cell with a negative/positive electrode (N/P) ratio of 0.9. The pristine LiNi Mn O was initially prepared by high-energy ball-mill with a solid-state reaction, followed by a precipitation reaction with a molybdenum precursor for the MoO coating. The typical structural and electrochemical behaviors of the materials were clearly investigated and reported. The results revealed that a sample of 2 wt.% MoO -coated LiNi Mn O electrode exhibited an optimal electrochemical activity, indicating that the MoO nanoparticle coating layers considerably enhanced the high-rate charge-discharge profiles and cycle life performance of LiNi Mn O with a negligible capacity decay. The 2 wt.% MoO -coated LiNi Mn O electrode could achieve high specific discharge capacities of 131 and 124 mAh g at the rates of 1 and 10 C, respectively. In particular, the 2 wt.% MoO -coated LiNi Mn O electrode retained its specific capacity (87 mAh g ) of 80.1% after 500 cycles at a rate of 10 C. The Li Ti O /LiNi Mn O full cell based on the electrochemical-cell (EL-cell) configuration was successfully assembled and tested, exhibiting excellent cycling retention of 93.4% at a 1 C rate for 100 cycles. The results suggest that the MoO nano-coating layer could effectively reduce side reactions at the interface of the LiNi Mn O cathode and the electrolyte, thus improving the electrochemical performance of the battery system.