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Efficient Stereo-Selective Fluorination on Vitamin D 3 Side-Chain Using Electrophilic Fluorination
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Efficient Stereo-Selective Fluorination on Vitamin D 3 Side-Chain Using Electrophilic Fluorination
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Journal Article
Efficient Stereo-Selective Fluorination on Vitamin D 3 Side-Chain Using Electrophilic Fluorination
2023
Overview
Our research regarding side-chain fluorinated vitamin D
analogues has explored a series of efficient fluorination methods. In this study, a new electrophilic stereo-selective fluorination methodology at C24 and C22 positions of the vitamin D
side-chain was developed using
-fluorobenzenesulfonimide (NFSI) and CD-ring imides with an Evans chiral auxiliary (
,
,
).
Subject
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