Journal Article

Mercury Ion Selective Adsorption from Aqueous Solution Using Amino-Functionalized Magnetic Fe 2 O 3 /SiO 2 Nanocomposite

Kornaus, Kamil, Youssif, Mahmoud M, El-Attar, Heba G, Małecki, Stanisław, Włoch, Grzegorz, Czapkiewicz, Maciej, Wojnicki, Marek

2024

Overview

This study focuses on the development of new amino-functionalized magnetic Fe O /SiO nanocomposites with varying silicate shell ratios (1:0.5, 1:1, and 1:2) for the efficient elimination of Hg ions found in solutions. The Fe O /SiO -NH adsorbents were characterized for their structural, surface, and magnetic properties using various techniques, including Fourier transform infrared spectrum (FT-IR), powder X-ray diffraction (XRD), scanning electron microscopy (SEM), Braunauer-Emmett-Teller (BET), thermogravimetric analysis (TGA), zeta-potential, and particle size measurement. We investigated the adsorption circumstances, such as pH, dosage of the adsorbent, and duration of adsorption. The pH value that yielded the best results was determined to be 5.0. The Fe O /SiO -NH adsorbent with a silicate ratio of (1:2) exhibited the largest amount of adsorption capacity of 152.03 mg g . This can be attributed to its significantly large specific surface area of 100.1 m g , which surpasses that of other adsorbents. The adsorbent with amino functionalization demonstrated a strong affinity for Hg ions due to the chemical interactions between the metal ions and the amino groups on the surface. The analysis of adsorption kinetics demonstrated that the adsorption outcomes adhere to the pseudo-second-order kinetic model. The study of adsorption isotherms revealed that the adsorption followed the Langmuir model, indicating that the adsorption of Hg ions with the adsorbent occurred as a monomolecular layer adsorption process. Furthermore, the thermodynamic analyses revealed that the adsorption of Hg ions using the adsorbent was characterized by a spontaneous and endothermic process. Additionally, the adsorbent has the ability to selectively extract mercury ions from a complex mixture of ions. The Fe O /SiO -NH nanocomposite, which is loaded with metal, can be easily recovered from a water solution due to its magnetic properties. Moreover, it can be regenerated effortlessly through acid treatment. This study highlights the potential use of amino-functionalized Fe O /SiO magnetic nanoparticles as a highly efficient, reusable adsorbent for the removal of mercury ions from contaminated wastewater.