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Surfactant Self‐Assembly
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Book Chapter
Surfactant Self‐Assembly
2014
Overview
Systems containing amphiphiles are best classified into homogeneous, or single‐phase, systems and heterogeneous systems of two or more phases. This chapter stresses the difference between homogeneous and heterogeneous systems, the former having a single phase, whereas the latter contain two or more phases; in this case one phase can be dispersed in another forming a dispersion. It discusses the basic aspects of self‐assemblies with the spherical micelle as example. The CMC is the single most important characteristic of a surfactant, useful inter alia in consideration of the practical uses of surfactants. The chapter considers how different factors influence the CMC. A complete characterization of the self‐association of a surfactant would include giving the concentration of all the different species as a function of the total surfactant concentration. These can nowadays be obtained in a single fast experiment using NMR methodology.
Publisher
John Wiley & Sons, Ltd
Subject
ISBN
1119961246, 9781119961246
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