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Zinc metallurgy is one of the large-scale processes that produces tons of waste every year, which in turn generate environmental pollution. In sustainable industry the circular economy is one of the most important issues, which means that as much waste as possible should be reused. Thus, there is a need to find a proper way to use zinc metallurgical waste in some other application. In this paper, an evaluation of the mechanical and tribological properties of an epoxy-based composite filled with zinc metallurgical wastes such as zinc dust, zinc ash and sifted zinc ash has been performed. Results of the research indicated that tensile and impact strength are reduced in all filled compositions. The smallest decrease in strength was observed in the cases of zinc dust and sifted zinc ash in amounts not greater than 5 wt. %. However, wear volume can be reduced by ca. 80% when the epoxy matrix is filled by at least 5 wt. % of zinc ash or sifted zinc ash. So, due to the decrease in mechanical strength and high reduction in wear volume, the most promising among the investigated fillers is sifted zinc ash introduced into the epoxy matrix in an amount up to 5 wt. %. This composition is characterized by a relatively good compromise between the reduction in mechanical strength and reduction in wear volume among investigated cases. Moreover, the reuse of zinc ash as a filler has a positive effect on the environment because of its management of waste stored mainly in heaps, which in turn falls within the scope of the circular economy.

In this study, composites were developed using a biopolyamide matrix modified with microsilica at varying concentrations (0.5–2% by weight). These composites underwent water absorption analysis, and diffusion velocity was assessed. Based on the findings, hybrid composites incorporating aramid, basalt, and carbon fibers, further modified with 2% microsilica by weight, were fabricated. Investigations into fundamental mechanical properties, microstructure analysis, and accelerated fatigue tests were conducted. The results demonstrate that microsilica positively influences the enhancement of fatigue strength and mechanical properties of the composites. Specifically, microsilica is found to increase the approximate fatigue strength by 15% for the base material modified with 2 wt.% microsilica, by approximately 5% for composites with aramid fiber, and by between 10 and 15% for composites with basalt and carbon fiber. Furthermore, the incorporation of microsilica reduces water absorption in polymer composites, potentially enhancing their durability in humid environments and increasing resistance to degradation.

Various types of coatings are applied to the surface of an object or substrate to improve surface properties or extend service life, which in turn is associated with cost reductions. The main objective of this study was to develop a technique for the additive application of foamed geopolymers to existing structures and vertical surfaces. The base material was a fly ash-based geopolymer modified with sand. Hydrogen peroxide and aluminum powder were used as foaming agents. In this study, the feasibility of using an air gun with variable nozzles to apply the layers of foamed geopolymers was assessed, and the effects of nozzle diameter and the spray gun’s operating pressure were analyzed. The next stage of the study was a visual assessment of the layering of the foamed material. The foamed geopolymer layering tests verified the occurrence of the foaming process, and the applied geopolymer surface showed a reasonably good adhesive bond with the vertical wall. In addition, in this paper, we present the laser particle size results of the base materials and their oxide composition. In addition, thermal conductivity tests for the foamed geopolymer materials, compressive strength tests, and microstructure analysis via scanning electron microscopy were carried out.

This study examines the relationship between the size of copper particles and the properties of epoxy resin. Epoxy resin is a type of thermosetting resin commonly used as a matrix in polymer matrix composite materials reinforced with glass or carbon fibers. As part of this study, three microscale and two nanoscale composite samples modified with copper oxide particles of varying sizes were produced. This study included mechanical property tests such as static tensile tests, static bending tests, and impact tests. The results of the strength tests were compared to modeling results. Additionally, an accelerated thermal aging process was conducted to determine the impact of external conditions on the behavior of the produced composites. This study concluded with an analysis of thermal conductivity. The test results revealed that the size of the copper particles significantly impacted the tested properties. The composites with copper oxide particles on the nanoscale demonstrated the best results. These composites have promising applications in the automotive and aviation industries due to their strength, resistance to external factors, and increased thermal conductivity, suggesting their potential for producing materials that effectively dissipate heat.

This article’s aim is to analyze physical, mechanical, and fracture properties as well as the thermal investigation of geopolymer composites reinforced with flax, glass fiber, and also the hybrid combination of fibers. Two types of matrices were considered as composites matrices. The first composition was based on fly ash and river sand. The second matrix composition contained fly ash and glass spheres. The content of reinforcement was 1% by mass. Compressive strength and three-point bending fracture tests were performed. The values of fracture toughness and fracture energy were determined. The resonance method was used to verify the dynamic characteristics, such as the dynamic modulus of elasticity and the dynamic Poisson ratio. The results show that single-type fibers in composites based on fly ash and glass spheres did not affect compressive strength. However, introducing hybrid reinforcement increased compressive strength by about 10% compared to the reference specimens. Flax fibers and hybrid reinforcement ensured higher fracture toughness and energy. The results also revealed great potential for glass sphere application to geopolymer materials in terms of fracture mechanics and thermal properties. Despite the lower strength properties in relation to geopolymers based on sand aggregate, applying reinforced fibers into the composite with glass spheres enhanced the compressive strength compared to other materials. Materials modified with glass spheres have a thermal conductivity twice as low as that of materials containing river sand.

The main purpose of the article is to present the differences in the parameters of geopolymer foams obtained in the same way, which is associated with difficulties in controlling the foaming process. Difficulties in controlling the foaming process of geopolymers are the direct reason for the lack of implementation of such materials nowadays. The article shows the results for experimental research, especially research into insulation, physical, and mechanical properties for the designated foamed materials. Microspheres (75%), sand (5%) and fly ash (20%) were used to produce foamed geopolymers. Hydrogen peroxide was the foaming agent. Heat conduction coefficients of 0.08-0.07 W/mK were obtained. The material density was obtained at the level of 363-375 [kg/m3] and the compressive strength was 520-683 [kPa]. The results showed that geopolymers can be a good alternative to conventional insulation materials, but the foaming technology should be developed so that it is stable and allows for reproducible material parameters.

The aim of this study is to analyze the strength and antibacterial properties of composites based on structural polyoxymethylene. The base material was modified with the most used antibacterial additives, such as silver nanoparticles, copper oxide, zinc oxide, and titanium oxide. Basic strength and low-cycle fatigue tests were conducted to determine the dissipation energy of the material. The composites were also tested for antibacterial properties against two strains of bacteria: Escherichia coli ATCC 8739 and Staphylococcus aureus ATCC 6538. Strength properties showed no significant changes in the mechanical behavior of the tested composites against the matrix material. The best antibacterial additive was the addition of titanium oxide nanoparticles, providing 100% efficacy against Escherichia coli and almost 100% biocidal efficacy against Staphylococcus aureus. The other antibacterial additives showed biocidal efficacy of about 30–40% against the unmodified material. The added value of the work is the consistency in the methodology of testing materials modified with antibacterial additives, as well as the same compactness of the introduced additives. This study makes it clear which of the introduced additives has the highest biocidal activity.

This study investigated the influence of the steel and melamine fibers hybridization on the flexural and compressive strength of a fly ash-based geopolymer. The applied reinforcement reduced the geopolymer brittleness. Currently, there are several types of polymer fibers available on the market. However, the authors did not come across information on the use of melamine fibers in geopolymer composites. Two systems of reinforcement for the composites were investigated in this work. Reinforcement with a single type of fiber and a hybrid system, i.e., two types of fibers. Both systems strengthened the base material. The research results showed the addition of melamine fibers as well as steel fibers increased the compressive and flexural strength in comparison to the plain matrix. In the case of a hybrid system, the achieved results showed a synergistic effect of the introduced fibers, which provided better strength results in relation to composites reinforced with a single type of fiber in the same amount by weight.

This paper presents the results of research on geopolymer composites based on fly ash with the addition of melamine fibers in amounts of 0.5%, 1% and 2% by weight and, for comparison, without the addition of fibers. The melamine fibers used in the tests retain their melamine resin properties by 100% and are characterized by excellent acoustic and thermal insulation as well as excellent filtration. In addition, these fibers are nonflammable, resistant to chemicals, resistant to UV radiation, characterized by high temperature resistance and, most importantly, do not show thermal-related shrinking, melting and dripping. This paper presents the results of density measurements, compressive and flexural strength as well as the results of the measurement of thermal radiation changes in samples subjected to a temperature of 600 °C. The results indicate that melamine fibers can be used as geopolymer reinforcement. The best result was achieved for 0.5% by weight amount of reinforcement, approximately 53 MPa, compared to 41 MPa for a pure matrix. In the case of flexural strength, the best results were obtained for the samples made of unreinforced geopolymer and samples with the addition of 0.5% by weight of melamine fibers, which were characterized by bending strength values above 9 MPa, amounting to 10.7 MPa and 9.3 MPa, respectively. The thermal radiation measurements and fire-jet test did not confirm the increasing thermal and fire resistance of the composites reinforced by melamine fiber.

This study aims to analyze strength properties and low-cycle dynamic tests of composite materials modified with glass and basalt fibers. Biopolyamide 4.10 was used as the matrix, and the fiber contents were 15, 30, and 50% by weight. Static tensile tests, impact tests, and determination of mechanical hysteresis loops were carried out as strength tests. The length of the fibers in the produced composites and their processing properties were determined. The composite materials were compared with commercially available glass fiber-reinforced composites with 30 and 50% fiber contents. The results showed that such composites can successfully replace composite materials based on petroleum-based polymeric materials, providing high strength properties and reducing the negative environmental impact by using renewable sources. Composites with 30% basalt fiber composition were characterized by higher tensile strength by about 60% compared to commercially available composites with 30% glass fiber composition and an almost doubly increased Young’s modulus. Increasing the content of basalt fibers to 50% results in a further increase in strength properties. Despite the lower tensile strength compared to polyamide 6 with 50% glass fiber content, basalt fibers provided an approximately 10% higher modulus of elasticity.