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Cybersecurity essentials
\"Cybersecurity Essentials\" provides a comprehensive introduction, with expert coverage of essential topics required for entry-level cybersecurity certificates. It covers the four distinct challenges of creating an effective cybersecurity defense: securing the infrastructure, securing devices, securing local networks, and securing the perimeter. The authors summarize the fundamental concepts of each challenge and include real-world scenarios that show how these vulnerabilities look in everyday computing. The text offers a summary of the key concepts, review questions, and hands-on exercises designed to help assess an understanding of key concepts. -- From publisher's description.
Book
Multiple light signaling pathways control solar tracking in sunflowers
Sunflowers are famous for their ability to track the sun throughout the day and then reorient at night to face east the following morning. This occurs by differential growth patterns, with the east sides of stems growing more during the day and the west sides of stems growing more at night. This process, termed heliotropism, is generally believed to be a specialized form of phototropism; however, the underlying mechanism is unknown. To better understand heliotropism, we compared gene expression patterns in plants undergoing phototropism in a controlled environment and in plants initiating and maintaining heliotropic growth in the field. We found the expected transcriptome signatures of phototropin-mediated phototropism in sunflower stems bending towards monochromatic blue light. Surprisingly, the expression patterns of these phototropism-regulated genes are quite different in heliotropic plants. Most genes rapidly induced during phototropism display only minor differences in expression across solar tracking stems. However, some genes that are both rapidly induced during phototropism and are implicated in growth responses to foliar shade are rapidly induced on the west sides of stems at the onset of heliotropism, suggesting a possible role for red light photoreceptors in solar tracking. To test the involvement of different photoreceptor signaling pathways in heliotropism, we modulated the light environment of plants initiating solar tracking. We found that depletion of either red and far-red light or blue light did not hinder the initiation or maintenance of heliotropism in the field. Together, our results suggest that the transcriptional regulation of heliotropism is distinct from phototropin-mediated phototropism and likely involves inputs from multiple light signaling pathways.
Journal Article
Room-temperature cycling of metal fluoride electrodes: Liquid electrolytes for high-energy fluoride ion cells
Owing to the low atomic weight of fluorine, rechargeable fluoride-based batteries could offer very high energy density. However, current batteries need to operate at high temperatures that are required for the molten salt electrolytes. Davis et al. push toward batteries that can operate at room temperature, through two advances. One is the development of a room-temperature liquid electrolyte based on a stable tetraalkylammonium salt–fluorinated ether combination. The second is a copper–lanthanum trifluoride core-shell cathode material that demonstrates reversible partial fluorination and defluorination reactions. Science , this issue p. 1144 Fluoride ion–conducting liquid electrolytes enable room-temperature cycling of fluoride ion electrochemical cells. Fluoride ion batteries are potential “next-generation” electrochemical storage devices that offer high energy density. At present, such batteries are limited to operation at high temperatures because suitable fluoride ion–conducting electrolytes are known only in the solid state. We report a liquid fluoride ion–conducting electrolyte with high ionic conductivity, wide operating voltage, and robust chemical stability based on dry tetraalkylammonium fluoride salts in ether solvents. Pairing this liquid electrolyte with a copper–lanthanum trifluoride (Cu@LaF 3 ) core-shell cathode, we demonstrate reversible fluorination and defluorination reactions in a fluoride ion electrochemical cell cycled at room temperature. Fluoride ion–mediated electrochemistry offers a pathway toward developing capacities beyond that of lithium ion technology.
Journal Article
Healable and conductive sulfur iodide for solid-state Li–S batteries
Solid-state Li–S batteries (SSLSBs) are made of low-cost and abundant materials free of supply chain concerns. Owing to their high theoretical energy densities, they are highly desirable for electric vehicles
1
–
3
. However, the development of SSLSBs has been historically plagued by the insulating nature of sulfur
4
,
5
and the poor interfacial contacts induced by its large volume change during cycling
6
,
7
, impeding charge transfer among different solid components. Here we report an S
9.3
I molecular crystal with I
2
inserted in the crystalline sulfur structure, which shows a semiconductor-level electrical conductivity (approximately 5.9 × 10
−7
S cm
−1
) at 25 °C; an 11-order-of-magnitude increase over sulfur itself. Iodine introduces new states into the band gap of sulfur and promotes the formation of reactive polysulfides during electrochemical cycling. Further, the material features a low melting point of around 65 °C, which enables repairing of damaged interfaces due to cycling by periodical remelting of the cathode material. As a result, an Li–S
9.3
I battery demonstrates 400 stable cycles with a specific capacity retention of 87%. The design of this conductive, low-melting-point sulfur iodide material represents a substantial advancement in the chemistry of sulfur materials, and opens the door to the practical realization of SSLSBs.
A conductive, low-melting-point and healable sulfur iodide material aids the practical realization of solid-state Li–S batteries, which have high theoretical energy densities and show potential in next-generation battery chemistry.
Journal Article
Mobility and phone call behavior explain patterns in poverty at high-resolution across multiple settings
Call detail records (CDRs) from mobile phone metadata are a promising data source for mapping poverty indicators in low- and middle-income countries. These data provide information on social networks, call behavior, and mobility patterns in a population, which are correlated with measures of socioeconomic status. CDRs are passively collected and provide information with high spatial and temporal resolution. Identifying features from these data that are generalizable and able to predict poverty and wealth beyond a single context could promote broader usage of mobile data, contribute to a reduction in the cost of socioeconomic data collection and processing, as well as complement existing census and survey-based methods of poverty estimation with improved temporal resolution. This is especially important within the context of the sustainable development goals (SDGs), where poverty and related health indicators are to be reduced significantly across subnational geographies by 2030. Here we utilize measures of cell phone user behavior derived from three CDR datasets within a Bayesian modeling framework to map poverty and wealth patterns across Namibia, Nepal, and Bangladesh. We demonstrate five metrics of user mobility and call behavior that are able to explain between 50% and 65% of the variance in socioeconomic status nationally for these three countries. These key metrics prove useful in very different contexts and can be readily provided as part of an existing CDR platform or software package. This paper provides a key contribution in this regard by identifying such metrics relevant to estimating poverty. We highlight the inclusion of ancillary data and local context as an important factor in understanding model outputs when targeting poverty alleviation strategies.
Journal Article
Room-temperature cycling of metal fluoride electrodes: Liquid electrolytes for high-energy fluoride ion cells
Fluoride ion batteries are potential “next-generation” electrochemical storage devices that offer high energy density. At present, such batteries are limited to operation at high temperatures because suitable fluoride ion–conducting electrolytes are known only in the solid state. We report a liquid fluoride ion–conducting electrolyte with high ionic conductivity, wide operating voltage, and robust chemical stability based on dry tetraalkylammonium fluoride salts in ether solvents. Pairing this liquid electrolyte with a copper–lanthanum trifluoride (Cu@LaF3) core-shell cathode, we demonstrate reversible fluorination and defluorination reactions in a fluoride ion electrochemical cell cycled at room temperature. Fluoride ion–mediated electrochemistry offers a pathway toward developing capacities beyond that of lithium ion technology.
Journal Article
Multiple light signaling pathways control solar tracking in sunflowers
Sunflowers are famous for their ability to track the sun throughout the day and then reorient at night to face east the following morning. This occurs by differential growth patterns, with the east sides of stems growing more during the day and the west sides of stems growing more at night. This process, termed heliotropism, is generally believed to be a specialized form of phototropism; however, the underlying mechanism is unknown. To better understand heliotropism, we compared gene expression patterns in plants undergoing phototropism in a controlled environment and in plants initiating and maintaining heliotropic growth in the field. We found the expected transcriptome signatures of phototropin-mediated phototropism in sunflower stems bending towards monochromatic blue light. Surprisingly, the expression patterns of these phototropism-regulated genes are quite different in heliotropic plants. Most genes rapidly induced during phototropism display only minor differences in expression across solar tracking stems. However, some genes that are both rapidly induced during phototropism and are implicated in growth responses to foliar shade are rapidly induced on the west sides of stems at the onset of heliotropism, suggesting a possible role for red light photoreceptors in solar tracking. To test the involvement of different photoreceptor signaling pathways in heliotropism, we modulated the light environment of plants initiating solar tracking. We found that depletion of either red and far-red light or blue light did not hinder the initiation or maintenance of heliotropism in the field. Together, our results suggest that the transcriptional regulation of heliotropism is distinct from phototropin-mediated phototropism and likely involves inputs from multiple light signaling pathways.
Journal Article
Healable and conductive sulfur iodide for solid-state Li–S batteries
Solid-state Li-S batteries (SSLSBs) are made of low-cost and abundant materials free of supply chain concerns. Owing to their high theoretical energy densities, they are highly desirable for electric vehicles. However, the development of SSLSBs has been historically plagued by the insulating nature of sulfur and the poor interfacial contacts induced by its large volume change during cycling, impeding charge transfer among different solid components. Here we report an S9.3I molecular crystal with I2 inserted in the crystalline sulfur structure, which shows a semiconductor-level electrical conductivity (approximately 5.9 × 10-7 S cm-1) at 25 °C; an 11-order-of-magnitude increase over sulfur itself. Iodine introduces new states into the band gap of sulfur and promotes the formation of reactive polysulfides during electrochemical cycling. Further, the material features a low melting point of around 65 °C, which enables repairing of damaged interfaces due to cycling by periodical remelting of the cathode material. As a result, an Li-S9.3I battery demonstrates 400 stable cycles with a specific capacity retention of 87%. The design of this conductive, low-melting-point sulfur iodide material represents a substantial advancement in the chemistry of sulfur materials, and opens the door to the practical realization of SSLSBs.
Journal Article
An inequality of Kostka numbers and Galois groups of Schubert problems
We show that the Galois group of any Schubert problem involving lines in projective space contains the alternating group. Using a criterion of Vakil and a special position argument due to Schubert, this follows from a particular inequality among Kostka numbers of two-rowed tableaux. In most cases, an easy combinatorial injection proves the inequality. For the remaining cases, we use that these Kostka numbers appear in tensor product decompositions of$\\mathfrak{sl}_2\\mathbb{C}$-modules. Interpreting the tensor product as the action of certain commuting Toeplitz matrices and using a spectral analysis and Fourier series rewrites the inequality as the positivity of an integral. We establish the inequality by estimating this integral. On montre que le groupe de Galois de tout problème de Schubert concernant des droites dans l'espace projective contient le groupe alterné. En utilisant un critère de Vakil et l'argument de position spéciale due à Schubert, ce résultat se déduit d'une inégalité particulière des nombres de Kostka des tableaux ayant deux rangées. Dans la plupart des cas, une injection combinatoriale facile montre l’inégalité. Pour les cas restants, on utilise le fait que ces nombres de Kostka apparaissent dans la décomposition en produit tensoriel des$\\mathfrak{sl}_2\\mathbb{C}$ -modules. En interprétant le produit tensoriel comme l'action de certaines matrices de Toeplitz commutant entre elles, et en utilisant de l'analyse spectrale et les séries de Fourier, on réécrit l’inégalité comme la positivité d'une intégrale. L’inégalité sera établie en estimant cette intégrale.
Journal Article
Galois groups of Schubert problems of lines are at least alternating
We show that the Galois group of any Schubert problem involving lines in projective space contains the alternating group. This constitutes the largest family of enumerative problems whose Galois groups have been largely determined. Using a criterion of Vakil and a special position argument due to Schubert, our result follows from a particular inequality among Kostka numbers of two-rowed tableaux. In most cases, a combinatorial injection proves the inequality. For the remaining cases, we use the Weyl integral formulas to obtain an integral formula for these Kostka numbers. This rewrites the inequality as an integral, which we estimate to establish the inequality.
Journal Article