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This editorial introduces the Special Issue entitled “Phase Change Materials for Building Energy Applications”, which gathers nine original research articles focused on advancing thermal energy storage solutions in the built environment. The selected contributions explore the application of phase change materials (PCMs) across a range of building components and systems, including façades, flooring, glazing, and pavements, aimed at enhancing energy efficiency, reducing peak loads, and improving thermal comfort. This Special Issue highlights both experimental and numerical investigations, ranging from nanomaterial-enhanced PCMs and solid–solid PCM glazing systems to full-scale applications and the modeling of encapsulated PCM geometries. Collectively, these studies reflect the growing potential of PCMs to support sustainable, low-carbon construction and provide new insights into material design, system optimization, and energy resilience. We thank all contributing authors and reviewers for their valuable input and hope that this Special Issue serves as a resource for ongoing innovation in the field.

Accumulating solar and/or environmental heat in walls of apartment buildings or houses is a way to level-out daily temperature differences and significantly cut back on energy demands. A possible way to achieve this goal is by developing advanced composites that consist of porous cementitious materials with embedded phase change materials (PCMs) that have the potential to accumulate or liberate heat energy during a chemical phase change from liquid to solid, or vice versa. This paper aims to report the current state of art on numerical and theoretical approaches available in the scientific literature for modelling the thermal behavior and heat accumulation/liberation of PCMs employed in cement-based composites. The work focuses on reviewing numerical tools for modelling phase change problems while emphasizing the so-called Stefan problem, or particularly, on the numerical techniques available for solving it. In this research field, it is the fixed grid method that is the most commonly and practically applied approach. After this, a discussion on the modelling procedures available for schematizing cementitious composites with embedded PCMs is reported.

Thermal energy storage using phase change materials (PCMs) is a promising technology for improving the thermal performance of buildings and reducing their energy consumption. However, the effectiveness of passive PCMs in buildings depends on their optimal design regarding the building typology and typical climate conditions. Within this context, the present contribution introduces a novel multiobjective computational method to optimize the thermophysical properties of cementitious building panels enhanced with a microencapsulated PCM (MPCM). To achieve this, a parametric model for PCM-based cementitious composites is developed in EnergyPlus, considering as design variables the melting temperature of PCMs and the thickness and thermal conductivity of the panel. A multiobjective genetic algorithm is dynamically coupled with the building energy model to find the best trade-off between annual heating and cooling loads. The optimization results obtained for a case study building in Sofia (Bulgaria-EU) reveal that the annual heating and cooling loads have contradictory performances regarding the thermophysical properties studied. A thick MPCM-enhanced panel with a melting temperature of 22 °C is needed to reduce the heating loads, while a thin panel with a melting temperature of 27 °C is required to mitigate the cooling loads. Using these designs, the annual heating and cooling loads decrease by 23% and 3%, respectively. Moreover, up to 12.4% cooling load reduction is reached if the thermal conductivity of the panels is increased. Therefore, it is also concluded that the thermal conductivity of the cement-based panels can significantly influence the effectiveness of MPCMs in buildings.

Modelling of a mineral dissolution front propagation is of interest in a wide range of scientific and engineering fields. The dissolution of minerals often involves complex physico-chemical processes at the solid–liquid interface (at nano-scale), which at the micro-to-meso-scale can be simplified to the problem of continuously moving boundaries. In this work, we studied the diffusion-controlled congruent dissolution of minerals from a meso-scale phase transition perspective. The dynamic evolution of the solid–liquid interface, during the dissolution process, is numerically simulated by employing the Finite Element Method (FEM) and using the phase–field (PF) approach, the latter implemented in the open-source Multiphysics Object Oriented Simulation Environment (MOOSE). The parameterization of the PF numerical approach is discussed in detail and validated against the experimental results for a congruent dissolution case of NaCl (taken from literature) as well as on analytical models for simple geometries. In addition, the effect of the shape of a dissolving mineral particle was analysed, thus demonstrating that the PF approach is suitable for simulating the mesoscopic morphological evolution of arbitrary geometries. Finally, the comparison of the PF method with experimental results demonstrated the importance of the dissolution rate mechanisms, which can be controlled by the interface reaction rate or by the diffusive transport mechanism.

Energy efficiency in buildings has become a major challenge in both science and industry [...]

The significant energy consumption and contribution to greenhouse gas emissions by the construction sector need careful attention to explore innovative sustainable solutions for improving the energy efficiency and thermal comfort of building envelopes. The integration of phase-change materials (PCMs) into building commodities is a favorable technology for minimizing energy consumption and enhancing thermal performance. This review paper covers the impact of PCM incorporation into construction materials, such as walls, roofs, and glazing units. Additionally, it examines different embedding techniques like direct incorporation, immersion, macro and micro-encapsulation, and form and shape-stable PCM. Factors affecting the thermal performance of PCM-integrated buildings, including melting temperature, thickness, position, volumetric change, vapor pressure, density, optical properties, latent heat, thermal conductivity, chemical stability, and climate conditions, are elaborated. Furthermore, the latest experimental and numerical simulations, as well as modeling techniques, evident from case studies, are investigated. Ultimately, the advantages of PCM integration, including energy savings, peak load reduction, improvement in interior comfort, and reduced heating, ventilation, and air-conditioning dependence, are explained alongside the limitations. Finally, the recent progress and future potential of PCM-integrated construction materials are discussed, focusing on innovations in this field, addressing the status of policies in line with the United Nations Sustainable Development Goals, and outlining research potential for the future.

The integration/combination of seismic and energy retrofit measures has been a subject of study for the past decade, exhibiting promising prospects. The main objective of these interventions is to mitigate seismic vulnerability while concurrently enhancing the energy performance and efficiency of new and existing buildings. Integrated approaches can hold the potential for substantial cost savings, time efficiency, and minimal disruption to occupants. The current body of literature emphasizes exploring the benefits of incorporating innovative methods/materials into conventional uncoupled retrofit initiatives. This study focuses on evaluating integrated measures at the panel scale for the prevalent Unreinforced Masonry (URM) typologies in Italy. A design framework has been introduced, aimed at enhancing the seismic capacity of buildings while concurrently improving energy efficiency through the integration of new materials (e.g., highly latent thermal energy storage systems achieved through the integration of Phase Change Materials - PCMs) into retrofit materials. To assess the reduction of the seismic vulnerability, the improvement of the shear strength is estimated by modifying the failure domains, while energy efficiency and thermal-energy storage enhancements are evaluated by using enthalpy-based theories, implemented into open-source software (i.e., FEM-based and through EnergyPlus). Thus, the design variables are those defined by the URM typologies, the adopted retrofitting technique, and the considered envelope. The adopted integrated (seismic and energy retrofitting) solutions will be compared with the standard reference one in terms of the energy consumed by the enclosed building to keep the indoor thermal comfort which also guarantees the target level of structural performance.

The growing global energy demand requires solutions that improve energy efficiency in all sectors. The civil construction sector is responsible for a large part of global energy consumption. In this context, phase change materials (PCMs) can be incorporated into construction materials to improve the energy efficiency of buildings. The purpose of this study was to incorporate a PCM to jute fabric, applying it in civil construction as a reinforcement for cement matrices. In order to do that, a method of immersing jute fabric in liquid phase change material, and then coating it with a polymer, was proposed. Treated jute fabric was then used to produce a laminated composite with a cementitious matrix. Morphological, mechanical and chemical characterization of jute textiles was performed, as well as an analysis of the composites’ mechanical and thermal behavior. The results verified that jute textiles absorbed 102% PCM in weight, which was successfully contained in the capillary porosity of jute. The PCM was able to delay the composite’s temperature increase by up to 24 °C. It was concluded that this method can be used to incorporate PCM to natural textiles, producing composites with thermal energy storage properties.

High temperature effect on cement-based composites, such as concrete or mortars, represents one of the most important damaging process that may drastically affect the mechanical and durability characteristics of structures. In this paper, the results of an experimental campaign on cement mortars submitted to high temperatures are reported and discussed. Particularly, two mixtures (i.e., Normal (MNS) and High Strength Mortar (MHS)) having different water-to-binder ratios were designed and evaluated in order to investigate the incidence of both the mortar composition and the effects of thermal treatments on their physical and mechanical properties. Mortar specimens were thermally treated in an electrical furnace, being submitted to the action of temperatures ranging from 100 to 600 °C. After that and for each mortar quality and considered temperature, including the room temperature case of 20 °C, water absorption was measured by following a capillary water absorption test. Furthermore, uniaxial compression, splitting tensile and three-points bending tests were performed under residual conditions. A comparative analysis of the progressive damage caused by temperature on physical and mechanical properties of the considered mortars types is presented. On one hand, increasing temperatures produced increasing water absorption coefficients, evidencing the effect of thermal damages which may cause an increase in the mortars accessible porosity. However, under these circumstances, the internal porosity structure of lower w/b ratio mixtures results much more thermally-damaged than those of MNS. On the other hand, strengths suffered a progressive degradation due to temperature rises. While at low to medium temperatures, strength loss resulted similar for both mortar types, at higher temperature, MNS presented a relatively greater strength loss than that of MHS. The action of temperature also caused in all cases a decrease of Young’s Modulus and an increase in the strain corresponding to peak load. However, MHS showed a much more brittle behavior in comparison with that of MNS, for all temperature cases. Finally, the obtained results demonstrated that mortar quality cannot be neglected when the action of temperature is considered, being the final material performance dependent on the physical properties which, in turn, mainly depend on the mixture proportioning.

This paper aims at further advancing the knowledge about the cyclic behavior of FRP strips glued to quasi-brittle materials, such as concrete. The results presented herein derive from a numerical model based on concepts of based on fracture mechanics and already presented and validated by the authors in previous works. Particularly, it assumes that fracture processes leading to debonding develop in pure mode II, as is widely accepted in the literature. Starting from this assumption (and having clear both its advantages acnd shortcomings), the results of a parametric analysis are presented with the aim of investigating the role of both the mechanical properties of the interface bond–slip law and a relevant geometric quantity such as the bond length. The obtained results show the influence of the interface bond–slip law and FRP bond length on the resulting cyclic response of the FRP-to-concrete joint, the latter characterized in terms of S-N curves generally adopted in the theory of fatigue. Far from deriving a fully defined correlation among those parameters, the results indicate general trends that can be helpful to drive further investigation, both experimental and numerical in nature.