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"Cai, Xin"
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Large cation ethylammonium incorporated perovskite for efficient and spectra stable blue light-emitting diodes
2020
Perovskite light-emitting diodes (PeLEDs) have showed significant progress in recent years; the external quantum efficiency (EQE) of electroluminescence in green and red regions has exceeded 20%, but the efficiency in blue lags far behind. Here, a large cation CH
3
CH
2
NH
2
+
is added in PEA
2
(CsPbBr
3
)
2
PbBr
4
perovskite to decrease the Pb–Br orbit coupling and increase the bandgap for blue emission. X-ray diffraction and nuclear magnetic resonance results confirmed that the EA has successfully replaced Cs
+
cations to form PEA
2
(Cs
1-
x
EA
x
PbBr
3
)
2
PbBr
4
. This method modulates the photoluminescence from the green region (508 nm) into blue (466 nm), and over 70% photoluminescence quantum yield in blue is obtained. In addition, the emission spectra is stable under light and thermal stress. With configuration of PeLEDs with 60% EABr, as high as 12.1% EQE of sky-blue electroluminescence located at 488 nm has been demonstrated, which will pave the way for the full color display for the PeLEDs.
Blue light-emitting diodes (LEDs) are critical for displays. Employing a large organic cation into a quasi-two dimensional perovskite with green emission, Chu et al. achieve LEDs exhibiting a high external quantum efficiency of 12.1% and stable spectra in the sky-blue region.
Journal Article
Color-tunable single-fluorophore supramolecular system with assembly-encoded emission
2020
Regulating the fluorescent properties of organic small molecules in a controlled and dynamic manner has been a fundamental research goal. Although several strategies have been exploited, realizing multi-color molecular emission from a single fluorophore remains challenging. Herein, we demonstrate an emissive system by combining pyrene fluorophore and acylhydrazone units, which can generate multi-color switchable fluorescent emissions at different assembled states. Two kinds of supramolecular tools, amphiphilic self-assembly and γ-cyclodextrin mediated host-guest recognition, are used to manipulate the intermolecular aromatic stacking distances, resulting in the tunable fluorescent emission ranging from blue to yellow, including a pure white-light emission. Moreover, an external chemical signal, amylase, is introduced to control the assembly states of the system on a time scale, generating a distinct dynamic emission system. The dynamic properties of this multi-color fluorescent system can be also enabled in a hydrogel network, exhibiting a promising potential for intelligent fluorescent materials.
Regulating fluorescent properties of small molecules in a controlled manner has been a fundamental research goal but realizing multi-color emission from a single fluorophore remains challenging. Here the authros demonstrate that combined pyrene fluorophore and acylhydrazone units show multi-color switchable fluorescent at different assembled states.
Journal Article
Dynamic Response and Energy Evolution of Sandstone Under Coupled Static–Dynamic Compression: Insights from Experimental Study into Deep Rock Engineering Applications
2020
To deeply understand the rock failure characteristics under actual engineering condition, in which static geo-stress and dynamic disturbance usually act simultaneously, impact tests were conducted on sandstone subjected to axial static pre-stresses varying from 0 to 75 MPa by a modified split Hopkinson pressure bar. The fracturing process of specimens was recorded by a high speed camera. Dynamic parameters of sandstone, such as strain rate, dynamic strength and energy partition were acquired. Fracture mechanisms of pulverized specimens were identified by the method combining the displacement trend line and digital image correlation technique. Moreover, fragments of failed specimens were sieved to obtain the fragment size distribution. Test results revealed that, under the same incident energy, the dynamic compressive strength increases first, then decreases slowly and at last drops rapidly with the increase of pre-stress, and reaches the maximum under 24.4% of uniaxial compressive strength due to the closure of initial defects. Four final patterns were observed, namely intact, axial split, rock burst, and pulverization. The rock burst only occurs when the pre-stress lies in the elastic deformation stage or initial stable crack growth stage and the incident energy is intermediate. For pulverized specimens, the fracture mechanism is transformed into shear/tensile equivalent from tensile-dominated mixed mode as the pre-stress increases. Specimens with 75 MPa pre-stress release strain energy during failure process, contrary to specimens with lower pre-stresses absorbing energy from outside. The crushing degree of pulverized specimens exhibits a positive correlation with the pre-stress as a consequence of higher damage development in rock.
Journal Article
Standard language proficiency as social capital: Impacts on subjective socioeconomic status in China
2025
Although language proficiency—especially in a standard language—has been widely studied as an indicator of social status and mobility, its relationship with subjective socioeconomic status (SES) requires closer examination. Drawing on data from the 2021 China General Social Survey, this study investigates the relationship between Mandarin proficiency and Chinese individuals’ subjective SES, including subjective class identity and perceptions of social mobility. The sample comprises 5,997 individuals aged 18–95 from urban and rural areas nationwide, with balanced sex distribution and diverse educational and occupational backgrounds. Mandarin proficiency is positively associated with static subjective class identity. This association is more pronounced among younger, less-educated, and rural groups. Additionally, proficiency alleviates the downward deviation, where subjective class identity falls below objective SES. This effect is stronger in coastal regions. However, it shows little association to perceptions of past or future mobility. Karlson-Holm-Breen (KHB) decomposition reveals that job and life satisfaction partially mediate the relationship, with life satisfaction exerting a stronger influence. These findings underscore the role of Mandarin proficiency as social capital, reflecting individuals’ perceptions of their social position. The findings also provide empirical evidence to inform state-led language standardization policies that promote social integration and reduce disparities.
Journal Article
High-dimensional Schwarzschild black holes in scalar–tensor–vector gravity theory
2021
We obtain a high-dimensional Schwarzschild black hole solution in the scalar–tensor–vector gravity (STVG), and then analyze the influence of parameter α associated with a deviation of the STVG theory from General Relativity on event horizons and Hawking temperature. We calculate the quasinormal mode frequencies of massless scalar field perturbations for the high-dimensional Schwarzschild STVG black hole by using the sixth-order WKB approximation method and the unstable null geodesic method in the eikonal limit. The results show that the increase of parameter α makes the scalar waves decay slowly, while the increase of the spacetime dimension makes the scalar waves decay fast. In addition, we study the influence of parameter α on the shadow radius of this high-dimensional Schwarzschild STVG black hole and find that the increase of parameter α makes the black hole shadow radius increase, but the increase of the spacetime dimension makes the black hole shadow radius decrease. Finally, we investigate the energy emission rate of the high-dimensional Schwarzschild STVG black hole, and find that the increase of parameter α makes the evaporation process slow, while the increase of the spacetime dimension makes the process fast.
Journal Article
Music genre classification based on auditory image, spectral and acoustic features
2022
Music genre is one of the conventional ways to describe music content, and also is one of the important labels of music information retrieval. Therefore, the effective and precise music genre classification method becomes an urgent need for realizing automatic organization of large music archives. Inspired by the fact that humans have a better automatic recognizing music genre ability, which may attribute to our auditory system, even for the participants with little musical literacy. In this paper, a novel classification framework incorporating the auditory image feature with traditional acoustic features and spectral feature is proposed to improve the classification accuracy. In detail, auditory image feature is extracted based on the auditory image model which simulates the auditory system of the human ear and has also been successfully used in other fields apart from music genre classification to our best knowledge. Moreover, the logarithmic frequency spectrogram rather than linear is adopted to extract the spectral feature to capture the information about the low-frequency part adequately. These above two features and the traditional acoustic feature are evaluated, compared, respectively, and fused finally based on the GTZAN, GTZAN-NEW, ISMIR2004 and Homburg datasets. Experimental results show that the proposed method owns the higher classification accuracy and the better stability than many state-of-the-art classification methods.
Journal Article
Dual-response fluorescent switching sensor for sequential detection of Fe3+ and vitamin C in hawthorn
2025
We developed a dual-mode fluorescence sensor based on 4,4′-stilbenedicarboxylic acid (H
2
SDC) for the sequential detection of iron ions (Fe
3+
) and vitamin C (VC) in hawthorn (genus
Crataegus
), a key traditional Chinese medicine (TCM). By leveraging the aggregation-induced emission (AIE) properties of H
2
SDC, the sensor quantifies Fe
3+
quantification via fluorescence quenching (“turn-off”) and subsequently detects VC through Fe
3+
reduction-triggered signal recovery (“turn-on”). This label-free strategy demonstrates high sensitivity, with linear ranges of 5.0–80.0 μmol L
−1
(Fe
3+
) and 5.0–40.0 μmol L
−1
(VC) and detection limits of 0.200 and 0.132 μmol L
−1
, respectively. Real-sample validation in Hawthorn matrices revealed excellent accuracy (spiked recoveries: 98.5–101.7% for Fe
3+
; 97.7–103.0% for VC) and reproducibility (RSD < 3.9%, n = 3). The platform integrates smartphone-assisted analysis to leverage concentration-dependent fluorescence transitions, offering potential for field-deployable threshold screening. As the first AIE-based sensor enabling sequential Fe
3+
/VC detection in herbal medicines, this work provides a rapid, cost-effective alternative to conventional instrumentation (e.g., HPLC/ICP-MS), supporting advancement of quality control for TCM modernization.
Journal Article
Antenna selection for multiple-input multiple-output systems based on deep convolutional neural networks
2019
Antenna selection in Multiple-Input Multiple-Output (MIMO) systems has attracted increasing attention due to the challenge of keeping a balance between communication performance and computational complexity. Recently, deep learning based methods have achieved promising performance in many application fields. This paper proposed a deep learning (DL) based antenna selection technique. First, we generated the label of training antenna systems by maximizing the channel capacity. Then, we adopted the deep convolutional neural network (CNN) on the channel matrices to explicitly exploit the massive latent cues of attenuation coefficients. Finally, we used the adopted CNN to assign the class label and then select the optimal antenna subset. Experimental results demonstrate that our method can achieve better performance than the state-of-the-art baselines for data-driven based antenna selection.
Journal Article
Biomechanical study of oblique lumbar interbody fusion (OLIF) augmented with different types of instrumentation: a finite element analysis
2022
Background
To explore the biomechanical differences in oblique lumbar interbody fusion (OLIF) augmented by different types of instrumentation.
Methods
A three-dimensional nonlinear finite element (FE) model of an intact L3-S1 lumbar spine was built and validated. The intact model was modified to develop five OLIF surgery models (Stand-alone OLIF; OLIF with lateral plate fixation [OLIF + LPF]; OLIF with unilateral pedicle screws fixation [OLIF + UPSF]; OLIF with bilateral pedicle screws fixation [OLIF + BPSF]; OLIF with translaminar facet joint fixation + unilateral pedicle screws fixation [OLIF + TFJF + UPSF]) in which the surgical segment was L4–L5. Under a follower load of 500 N, a 7.5-Nm moment was applied to all lumbar spine models to calculate the range of motion (ROM), equivalent stress peak of fixation instruments (ESPFI), equivalent stress peak of cage (ESPC), equivalent stress peak of cortical endplate (ESPCE), and equivalent stress average value of cancellous bone (ESAVCB).
Results
Compared with the intact model, the ROM of the L4–L5 segment in each OLIF surgery model decreased by > 80%. The ROM values of adjacent segments were not significantly different. The ESPFI, ESPC, and ESPCE values of the OLIF + BPSF model were smaller than those of the other OLIF surgery models. The ESAVCB value of the normal lumbar model was less than the ESAVCB values of all OLIF surgical models. In most postures, the ESPFI, ESPCE, and ESAVCB values of the OLIF + LPF model were the largest. The ESPC was higher in the Stand-alone OLIF model than in the other OLIF models. The stresses of several important components of the OLIF + UPSF and OLIF + TFJF + UPSF models were between those of the OLIF + LPF and OLIF + BPSF models.
Conclusions
Our biomechanical FE analysis indicated the greater ability of OLIF + BPSF to retain lumbar stability, resist cage subsidence, and maintain disc height. Therefore, in the augmentation of OLIF, bilateral pedicle screws fixation may be the best approach.
Journal Article
Quantum teleportation of multiple degrees of freedom of a single photon
2015
The quantum teleportation of composite quantum states of a single photon encoded in both spin and orbital angular momentum is achieved, with a teleportation fidelity above the classical limit, by quantum non-demolition measurement assisted discrimination of the Bell states describing the entanglement of the two degrees of freedom.
Quantum teleportation of two states of one photon
In the process known as quantum teleportation, quantum information encoded in a quantum particle, for example a photon, is transferred from one place to the other without ever moving the photon. Although quantum teleportation has been demonstrated with a variety of different systems, all have so far been limited in one crucial aspect: they only allow teleporting one degree of freedom. Here, Nai-Le Liu and colleagues demonstrate quantum teleportation of two degrees of freedom — spin and orbital angular momentum — in a single photon. Their experimental implementation is very complex and entails various innovative techniques, most notably a hybrid Bell-state measurement scheme. The intricacy of this scheme illustrates how difficult it will be to implement quantum teleportation of more complex quantum systems with more degrees of freedom. But this work represents a first and significant step in this direction.
Quantum teleportation
1
provides a ‘disembodied’ way to transfer quantum states from one object to another at a distant location, assisted by previously shared entangled states and a classical communication channel. As well as being of fundamental interest, teleportation has been recognized as an important element in long-distance quantum communication
2
, distributed quantum networks
3
and measurement-based quantum computation
4
,
5
. There have been numerous demonstrations of teleportation in different physical systems such as photons
6
,
7
,
8
, atoms
9
, ions
10
,
11
, electrons
12
and superconducting circuits
13
. All the previous experiments were limited to the teleportation of one degree of freedom only. However, a single quantum particle can naturally possess various degrees of freedom—internal and external—and with coherent coupling among them. A fundamental open challenge is to teleport multiple degrees of freedom simultaneously, which is necessary to describe a quantum particle fully and, therefore, to teleport it intact. Here we demonstrate quantum teleportation of the composite quantum states of a single photon encoded in both spin and orbital angular momentum. We use photon pairs entangled in both degrees of freedom (that is, hyper-entangled) as the quantum channel for teleportation, and develop a method to project and discriminate hyper-entangled Bell states by exploiting probabilistic quantum non-demolition measurement, which can be extended to more degrees of freedom. We verify the teleportation for both spin–orbit product states and hybrid entangled states, and achieve a teleportation fidelity ranging from 0.57 to 0.68, above the classical limit. Our work is a step towards the teleportation of more complex quantum systems, and demonstrates an increase in our technical control of scalable quantum technologies.
Journal Article