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We explore the connections between crustal shortening, volcanism, and mantle dynamics in the Atlas of Morocco. In response to compressional forces and strain localization, this intraplate orogen has evolved far from convergent plate margins. Convective effects, such as lithospheric weakening and plume‐related volcanism, contributed in important ways to the building of high topography. We seek to better understand how crustal and mantle processes interacted during the Atlas' orogeny by combining multiple strands of observations, including new and published data. Constraints on crustal and thermal evolution are combined with new analyses of topographic evolution, petrological, and geochemical data from the Anti‐Atlas volcanic fields, and a simple numerical model of the interactions among crustal deformation, a mantle plume, and volcanism. Our findings substantiate that: (a) crustal deformation and exhumation accelerated during the middle/late Miocene, contemporaneous with the onset of volcanism; (b) volcanism has an anorogenic signature with a deep source; (c) a dynamic mantle upwelling supports the high topography. We propose that a mantle plume and the related volcanism weakened the lithosphere beneath the Atlas and that this favored the localization of crustal shortening along pre‐existing structures during plate convergence. This convective‐tectonic sequence may represent a general mechanism for the modification of continental plates throughout the thermo‐chemical evolution of the supercontinental cycle. Key Points Crustal thickening is limited and cannot account for the topography elevation of the Atlas system Resumption of volcanism is contemporaneous with the acceleration of crustal deformation and topography growing The erosion and weakening of the lower lithosphere, as a consequence of mantle plume, may enhance crustal deformation and exhumation

The Tyrrhenian border of the Italian peninsula has been the site of intense magmatism from Pliocene to recent times. Although calc-alkaline, potassic and ultrapotassic volcanism overlaps in space and time, a decrease of alkaline character in time and space (southward) is observed. Alkaline ultrapotassic and potassic volcanic rocks are characterised by variable enrichment in K and incompatible elements, coupled with consistently high LILE/HFSE values, similar to those of calc-alkaline volcanic rocks from the nearby Aeolian arc. On the basis of mineralogy and major and trace element chemistry two different arrays can be recognised among primitive rocks; a silica saturated trend, which resulted in formation of leucite-free mafic rocks, and a silica undersaturated trend, charactrerised by leucite-bearing rocks. Initial 87Sr/86Sr and 143Nd/144Nd values of Italian ultrapotassic and potassic mafic rocks range from 0.70506 to 0.71672 and from 0.51173 to 0.51273, respectively. 206Pb/204Pb values range between 18.50 and 19.15, 207Pb/204Pb values range between 15.63 and 15.70, and 208Pb/204Pb values range between 38.35 and 39.20. The general kSr vs. kNd array, along with crustal lead isotopic values, clearly indicates that a continental crustal component has played an important role in the genesis of these magmas. The main question is where this continental crustal component has been acquired by the magmas. Volcanological and petrologic data indicate continental crustal contamination to be a leading process along with fractional crystallisation and magma mixing. Considering, however, only the samples thought to represent primary magmas, which have been in equilibrium with their mantle source, a clearer picture emerges. A large variation of kSr vs. kNd is still observed, with kSr from m2 to +180 and kNd from + 2 to m12. A bifurcation of this array is observed in the samples that plot in the lower right quadrant, with mafic leucite-bearing Roman Province rocks buffered at kSr = + 100 whereas the mafic leucite-free potassic and ultrapotassic rocks point to strongly radiogenic Sr compositions. We may argue that mafic leucite-bearing Roman Province rocks point to kSr and kNd values similar to those of Miocene carbonate sediments whereas mafic leucite-free potassic and ultrapotassic rocks point to a silicate upper crust end-member. Lead isotopes plot well inside the field of island arcs, overlapping the values of pelagic sediments as well, but bifurcation between the samples north and south of Rome is observed. The main characteristic for the mantle source of Italian potassic and ultrapotassic magmas is the clear upper crustal signature acquired prior to partial melting through metasomatic agents released by the subducted slab. In addition, one lithospheric mantle source in the north and an asthenospheric mantle source, pointing to an HIMU reservoir, in the south were recognised. The chemical and isotopic differences observed between the northern and southern sectors of the magmatic region were possibly due to the presence of a carbonate-rich component in the crustal enriching agent in the south. One crustal component might have been generated by melting of silicate metasedimentary rocks or sediments from an ancient subducted slab. The second one might reflect the activity of mostly CO2-rich fluid released more recently by the incipient subduction of carbonate sedimentary rocks. [PUBLICATION ABSTRACT]

Mineral compositions in leucite-bearing and leucite-free rocks from Vico volcano are reported. FeO/MgO partitioning (Kdol/liq) between olivine and latite (0.14-0.22), and between olivine and trachyte (0.06-0.10) indicates a lack of equilibrium between mineral and host rock. This suggests that mingling and/or mixing between magmas was a leading process during magmatic differentiation. In addition, a phono-tephrite olivine population with high (0.84) and equilibrium (0.23-0.29) Kdol/liq values has been produced by the interaction of differently evolved magmas. Zoning in clinopyroxene and plagioclase from these rocks recorded the same processes. In addition, resorbed quartz xenocrysts with coronas of clinopyroxene microlites indicate that digestion of crustal rocks occurred during the residence of magma in a shallow level reservoir. Increasing Fe coupled with decreasing Ca in diopside crystals from some phonolites, together with the petrographic and trace element data, indicate that polybaric fractional crystallisation also may be involved in the genesis of magmas of the second period of Vico activity. Leucite-free trachybasalts erupted in a late stage contain highly forsteritic olivine phenocrysts (forsterite 84-88 mol.%) in-equilibrium (Kdol/liq = 0.24-0.35) with the host rock, which indicate that they did not suffer chemical modification at low pressure. [PUBLICATION ABSTRACT]

Since the Cenozoic, Ethiopia was affected by a widespread volcanic activity related to the geodynamic evolution of the Afar triple junction. The plateau building phase was followed by the formation of the Main Ethiopian Rift (MER) accompanied by a bimodal volcanic activity in both the inner parts of the rift and its shoulders. Outside the rift, a concurrent volcanic activity occurred mainly along transversal tectonic lineaments, the most important of which is the Yerer-Tullu Wellel Volcano-Tectonic Lineament (YTVL) developing for 500 km westward of Addis Abeba. Scattered Pliocene Quaternary volcanoes are reported also inside the plateau such as those outcropping nearby Lake Tana. Here we present the result of a study on carefully screened mafic lavas outcropping in two sectors located off-axis the MER, namely, the YTVL and the southern part of Lake Tana; and in one sector located in the southern tip of the MER close to Megado, in the Sidamo region. The screened samples are petrographically fresh and have SiO2<52 wt.% and MgO>4 wt.%, to minimise crystal fractionation effects. Most of the samples belong to the Late Miocene Quaternary volcanic activity of the East African Rift System (EARS), although a number of samples along the YTVL are representative of the Late Eocene Early Miocene Ethiopian Volcanic Plateau flood basalts. The selected mafic lavas offer the opportunity to assess the geochemical diversity, if any. [PUBLICATION ABSTRACT]

This work assesses the efficiency of polyacrylamides for natural organic matter (NOM) removal from Paraíba do Sul River (Brazil) raw water for drinking purposes. Jar tests were performed following an experimental design protocol. Three kinds of polyacrylamides (anionic, cationic, and non-ionic) at 0.2 mg L−1 were tested. After coagulation, turbidity, DOC, UVA254 and SCAN (UV-absorbing material) were determined. Color and pH were also measured. It was found that polyacrylamides did not reduce the amounts of alum and lime needed in the process and that the amount of alum alone for removing UV-absorbing organic matter is significantly higher. Efficiency of the coagulation process decreased as follows: non-ionic → cationic → anionic → no polyacrylamide. Removal efficiencies for the best case were: 100%, 90%, 83%, and 68% for turbidity, DOC, UVA254, and SCAN, respectively.

The occurrence of rhyolite melts in the mantle has been predicted by high pressure-high temperature experiments but never observed in nature. Here we report natural quartz-bearing rhyolitic melt inclusions and interstitial glass within peridotite xenoliths. The oxygen isotope composition of quartz crystals shows the unequivocal continental crustal derivation of these melts, which approximate the minimum composition in the quartz-albite-orthoclase system. Thermodynamic modelling suggests rhyolite was originated from partial melting of near-anhydrous garnet-bearing metapelites at temperatures ~1000 °C and interacted with peridotite at pressure ~1 GPa. Reaction of rhyolite with olivine converted lherzolite rocks into orthopyroxene-domains and orthopyroxene + plagioclase veins. The recognition of rhyolitic melts in the mantle provides direct evidence for element cycling through earth’s reservoirs, accommodated by dehydration and melting of crustal material, brought into the mantle by subduction, chemically modifying the mantle source, and ultimately returning to surface by arc magmatism. The paper reports the occurrence of quartz-bearing rhyolitic melt inclusions and interstitial glasses within peridotite xenoliths. Their O-isotope composition proves crustal derivation and cycling into the mantle at convergent plate margins.

Extra virgin olive oil (EVOO) is a valuable product and is highly appreciated by consumers for its great nutritional value. However, to date, there has been a lack of uniform systems capable of ranking the nutritional value of EVOO based on its chemical composition in terms of macro- and micronutrients (including phenolic compounds and tocopherols). The aim of this study was to propose a scoring algorithm to rank the nutritional value of EVOO samples, considering their chemical composition in macro- and micronutrients and their sensitivity to oxidation phenomena. Data from more than 1000 EVOO samples were used to assess the variability of the data, considering the selected negative parameters (free acidity, peroxide value, spectrophotometric indices) and positive components (composition in tocopherols via HPLC-DAD, phenolic compounds via HPLC-DAD, and fatty acids via GC-MS) so as to ensure the universal validity of the scoring algorithm. The dataset included samples from the main producing countries worldwide, in addition to Australia, across several production years; data were selected to represent different production realities. A mathematical model was set up for each chemical component, resulting in six variable values. By combining these values with a dimensionless constant value, the algorithm for computing the nutritional value score (NVS) was defined. It allows the nutritional value of an oil to be ranked on a scale of 0 to 100 based on its chemical composition. The algorithm was then successfully tested using chemical data from about 300 EVOO samples obtained from laboratories from different Italian regions. The proposed NVS is a simple and objective tool for scoring the nutritional value of an EVOO, easy to understand for both producers and consumers.

The northern and northwestern margins of the Arabian Plate are a locus of a diffuse and long-lasting (early Miocene to Pleistocene) Na-alkali basaltic volcanism, sourced in the asthenosphere mantle. The upwelling asthenosphere at the Africa–Arabia margin produces very limited magma volumes in the axial zone. Therefore, portions of hot, fertile mantle continue their eastward migration and are stored at shallower depths under the 100-km thick Arabian lithosphere, which is much thinner than the African one (≈175 km): this causes the occurrence and 20-Ma persistence of magma supply under the study area. Erupted basalts sampled a continuous variation of the mantle source, with a striking correlation among temperature, pressure and isotopic composition shifting between two end members: a 100 km-deep, more depleted source, and a 60 km-deep, more enriched one. In particular, we observed an unusual variation in boron isotopes, which in the oceanic domain does not vary between more depleted and more enriched mantle sources. This study shows that, at least in the considered region, subcontinental mantle is more heterogeneous than the suboceanic one, and able to record for very long times recycling of shallow material.

In accordance with SDG N11.7, each city should work on providing “by 2030, universal access to safe, inclusive and accessible, green and public spaces, in particular for women and children, older persons and persons with disabilities”. This target became even more crucial during the COVID-19 pandemic restrictions. This paper presents and discuss a method for (i) assessing the current distribution and accessibility of urban green spaces (UGSs) in a city using hierarchical network distances; and (ii) quantifying the per capita values of accessible UGSs, also in light of the restrictions in place, namely social distancing during the COVID-19 pandemic. The methods have been tested in the city of Bologna, and the results highlight urban areas that suffer from a scarcity of accessible UGSs and identify potentially overcrowded UGSs, assessing residents’ pressure over diverse UGSs of the city in question. Based on our results, this work allows for the identification of priorities of intervention to overcome these issues, while also considering temporary solutions for facing the eventual scarce provision of UGSs and related health and wellbeing benefits in periods of movement restrictions.

Recent seismic events and the damages related to them have highlighted the crucial role of urban planning in coping with the fragility and intrinsic vulnerability of cities. The paper presents a methodology for assessing seismic risk at an urban scale, expanding from a single-building investigation to an urban-scale analysis by adopting an empirical method for assessing the vulnerability of the urban fabric. Data collection and analysis have been conducted through the Geographic Information System (GIS). The methodology has been applied to the Italian city of Castelfranco Emilia, in the Emilia-Romagna region, where the current regional urban planning law is guiding municipalities towards the development of strategies mostly oriented toward the retrofit of the existing building stock and the overall regeneration of the urbanized territory, in accordance with the target of no net land take by 2050. The novelty of the method stands in the transposition of approaches born in the civil engineering and protection domains to the urban planning sphere, stressing the importance of developing urban planning instruments which are well-integrated with vulnerability assessments and, therefore, able to successfully incorporate risk considerations in the decision making.