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result(s) for
"El-Sayed, Marwa A."
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Bridging the scalability gap in van der Waals light guiding with high refractive index MoTe2
by
Ermolaev, Georgy A.
,
Grudinin, Dmitriy V.
,
Romanov, Roman I.
in
all-dielectric nanophotonics
,
Anisotropy
,
Chemical synthesis
2025
van der Waals transition metal dichalcogenides, distinguished by a high refractive index and giant optical anisotropy, are promising materials for integrated photonic devices. However, their superior optical properties are nowadays limited to exfoliated samples with only a micrometer scale, whereas industrial integration requires at least cm-scale dimensions. Here, we resolve this problem for MoTe
by demonstrating that chemical vapor deposition synthesis can provide an identical optical response to the benchmark exfoliated samples in a broad spectral range (250–5,000 nm). It allows us to show high-performance waveguiding properties of MoTe
with a subwavelength footprint of ∼
/8 for telecommunication wavelengths. Therefore, our findings reveal MoTe
as an ideal platform for the next-generation nanophotonics.
Journal Article
Non-Additive Optical Response in Transition Metal Dichalcogenides Heterostructures
by
Ermolaev, Georgy A.
,
El-Sayed, Marwa A.
,
Tselin, Andrey P.
in
Chalcogenides
,
Chemical vapor deposition
,
Ellipsometry
2022
Van der Waals (vdW) heterostructures pave the way to achieve the desired material properties for a variety of applications. In this way, new scientific and industrial challenges and fundamental questions arise. One of them is whether vdW materials preserve their original optical response when assembled in a heterostructure. Here, we resolve this issue for four exemplary monolayer heterostructures: MoS2/Gr, MoS2/hBN, WS2/Gr, and WS2/hBN. Through joint Raman, ellipsometry, and reflectance spectroscopies, we discovered that heterostructures alter MoS2 and WS2 optical constants. Furthermore, despite the similarity of MoS2 and WS2 monolayers, their behavior in heterostructures is markedly different. While MoS2 has large changes, particularly above 3 eV, WS2 experiences modest changes in optical constants. We also detected a transformation from dark into bright exciton for MoS2/Gr heterostructure. In summary, our findings provide clear evidence that the optical response of heterostructures is not the sum of optical properties of its constituents.
Journal Article
Optical Constants of Chemical Vapor Deposited Graphene for Photonic Applications
by
Ermolaev, Georgy A.
,
Romanov, Roman I.
,
Volkov, Valentyn S.
in
Chemical vapor deposition
,
dielectric properties
,
Ellipsometry
2021
Graphene is a promising building block material for developing novel photonic and optoelectronic devices. Here, we report a comprehensive experimental study of chemical-vapor deposited (CVD) monolayer graphene’s optical properties on three different substrates for ultraviolet, visible, and near-infrared spectral ranges (from 240 to 1000 nm). Importantly, our ellipsometric measurements are free from the assumptions of additional nanometer-thick layers of water or other media. This issue is critical for practical applications since otherwise, these additional layers must be included in the design models of various graphene photonic, plasmonic, and optoelectronic devices. We observe a slight difference (not exceeding 5%) in the optical constants of graphene on different substrates. Further, the optical constants reported here are very close to those of graphite, which hints on their applicability to multilayer graphene structures. This work provides reliable data on monolayer graphene’s optical properties, which should be useful for modeling and designing photonic devices with graphene.
Journal Article
Broadband Optical Constants and Nonlinear Properties of SnS2 and SnSe2
by
Ermolaev, Georgy A.
,
Volkov, Valentyn S.
,
Slavich, Aleksandr S.
in
Broadband
,
Chemical vapor deposition
,
Crystal structure
2022
SnS2 and SnSe2 have recently been shown to have a wide range of applications in photonic and optoelectronic devices. However, because of incomplete knowledge about their optical characteristics, the use of SnS2 and SnSe2 in optical engineering remains challenging. Here, we addressed this problem by establishing SnS2 and SnSe2 linear and nonlinear optical properties in the broad (300–3300 nm) spectral range. Coupled with the first-principle calculations, our experimental study unveiled the full dielectric tensor of SnS2 and SnSe2. Furthermore, we established that SnS2 is a promising material for visible high refractive index nanophotonics. Meanwhile, SnSe2 demonstrates a stronger nonlinear response compared with SnS2. Our results create a solid ground for current and next-generation SnS2- and SnSe2-based devices.
Journal Article
Broadband Optical Properties of Bi2Se3
by
Ermolaev, Georgy A.
,
Vyslanko, Ivan S.
,
Tselin, Andrey P.
in
Approximation
,
Biosensors
,
Bonding strength
2023
Materials with high optical constants are of paramount importance for efficient light manipulation in nanophotonics applications. Recent advances in materials science have revealed that van der Waals (vdW) materials have large optical responses owing to strong in-plane covalent bonding and weak out-of-plane vdW interactions. However, the optical constants of vdW materials depend on numerous factors, e.g., synthesis and transfer method. Here, we demonstrate that in a broad spectral range (290–3300 nm) the refractive index n and the extinction coefficient k of Bi2Se3 are almost independent of synthesis technology, with only a ~10% difference in n and k between synthesis approaches, unlike other vdW materials, such as MoS2, which has a ~60% difference between synthesis approaches. As a practical demonstration, we showed, using the examples of biosensors and therapeutic nanoparticles, that this slight difference in optical constants results in reproducible efficiency in Bi2Se3-based photonic devices.
Journal Article
Optical Constants and Structural Properties of Epitaxial MoS2 Monolayers
by
Ermolaev, Georgy A.
,
Romanov, Roman I.
,
Volkov, Valentyn S.
in
Atomic force microscopy
,
Atomic properties
,
Chemical synthesis
2021
Two-dimensional layers of transition-metal dichalcogenides (TMDs) have been widely studied owing to their exciting potential for applications in advanced electronic and optoelectronic devices. Typically, monolayers of TMDs are produced either by mechanical exfoliation or chemical vapor deposition (CVD). While the former produces high-quality flakes with a size limited to a few micrometers, the latter gives large-area layers but with a nonuniform surface resulting from multiple defects and randomly oriented domains. The use of epitaxy growth can produce continuous, crystalline and uniform films with fewer defects. Here, we present a comprehensive study of the optical and structural properties of a single layer of MoS2 synthesized by molecular beam epitaxy (MBE) on a sapphire substrate. For optical characterization, we performed spectroscopic ellipsometry over a broad spectral range (from 250 to 1700 nm) under variable incident angles. The structural quality was assessed by optical microscopy, atomic force microscopy, scanning electron microscopy, and Raman spectroscopy through which we were able to confirm that our sample contains a single-atomic layer of MoS2 with a low number of defects. Raman and photoluminescence spectroscopies revealed that MBE-synthesized MoS2 layers exhibit a two-times higher quantum yield of photoluminescence along with lower photobleaching compared to CVD-grown MoS2, thus making it an attractive candidate for photonic applications.
Journal Article
Stability Enhancement and Bifurcation Mitigation in Nonlinear Inner Plate Oscillations Through PD Control
by
Amer, Yasser A.
,
Hussein, Rageh K.
,
EL-Sayed, Ashraf Taha
in
Aerodynamics
,
Bifurcations
,
Cantilever plates
2025
Axially moving wings offer remarkable aerodynamic efficiency and adaptability; however, they are highly susceptible to detrimental vibrations that may compromise flight stability and structural integrity. Previous studies have mainly focused on simplified linear models or passive control approaches, leaving the nonlinear dynamic behavior and active vibration suppression insufficiently addressed. To overcome these limitations, this study models the wing as a simplified cantilever plate and investigates its nonlinear dynamics under varying load conditions. A proportional–derivative (PD) controller is employed, and approximate analytical solutions to the governing equations are derived using the multiple-scale perturbation method (MSPM). The system’s response under primary resonance is analyzed through frequency response and bifurcation studies, while stability is assessed using the Routh–Hurwitz criterion. Analytical findings are validated with numerical simulations in MATLAB R2023b. Furthermore, the influence of key structural parameters on system dynamics and controller performance is examined. The results demonstrate that the PD controller effectively suppresses vibrations, offering a reliable solution for enhancing the stability of axially moving wing systems.
Journal Article
Controlling the Generator in a Series of Hybrid Electric Vehicles Using a Positive Position Feedback Controller
by
Amer, Yasser A.
,
Alluhydan, Khalid
,
EL-Sayed, Ashraf Taha
in
Automobiles, Electric
,
Control algorithms
,
Controllers
2024
This study investigates the effectiveness of positive position feedback (PPF) in reducing vibration amplitudes in an electric vehicle generator, specifically at super harmonic resonance (SHR) with 1:1 Internal Resonance (IR). Here is a breakdown. Simplified Model: The study uses a simplified nonlinear dynamic model (one degree of freedom, up to fifth-order nonlinear components) with external force, analyzed using the Multiple Time Scales Method (MTSM) with a first-order approximation. Focus on Resonance: The primary focus is on understanding the system’s behavior at SHR with 1:1 IR and how PPF can mitigate vibrations in this specific scenario. Frequency Response and Controller Influence: Frequency response functions are used to analyze the system’s stability with PPF, examining how different controller parameters affect the main system’s dynamics. Validation: Numerical solutions, obtained using the fourth-order Runge–Kutta method (‘RK-4’), are used to demonstrate and evaluate the system’s amplitude with and without PPF. The analytical and numerical results show strong agreement, validating the model’s accuracy. In essence, the research explores using PPF as a vibration control strategy in a specific resonance condition within an electric vehicle generator, using a combination of analytical and numerical methods for analysis and validation.
Journal Article
Bridging the scalability gap in van der Waals light guiding with high refractive index MoTe 2
2025
van der Waals transition metal dichalcogenides, distinguished by a high refractive index and giant optical anisotropy, are promising materials for integrated photonic devices. However, their superior optical properties are nowadays limited to exfoliated samples with only a micrometer scale, whereas industrial integration requires at least cm-scale dimensions. Here, we resolve this problem for MoTe 2 by demonstrating that chemical vapor deposition synthesis can provide an identical optical response to the benchmark exfoliated samples in a broad spectral range (250–5,000 nm). It allows us to show high-performance waveguiding properties of MoTe 2 with a subwavelength footprint of ∼ λ /8 for telecommunication wavelengths. Therefore, our findings reveal MoTe 2 as an ideal platform for the next-generation nanophotonics.
Journal Article
Chemical and Technological Studies on Manufactured Segments from Juices of Opuntia, Pumpkin and White Mulberry
by
Mohammed, Nahed S
,
El-Sayed, Marwa A
,
El-Sadq, Hanan R
in
التراكيب الكيميائية
,
التكنولوجيا الكيميائية
,
عصائر الفاكهة
2020
The aim of this study is to make slices of fruit juices and their mixture as the life span of this fruit is short. It contains nutrients and anti-oxidants. Therefore, a different preservation method was searched for the use of these juices and turn them into slides so that they can be retrieved again in the form of juices. The chemical composition and the total content of phenols and antioxidants were studied. The results demonstrated that there is a direct relationship between the phenol content and the antioxidant, natural oxidation.
Journal Article