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result(s) for
"Majee, Rahul"
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Value added transformation of ubiquitous substrates into highly efficient and flexible electrodes for water splitting
2018
Herein, we present an innovative approach for transforming commonly available cellulose paper into a flexible and catalytic current collector for overall water splitting. A solution processed soak-and-coat method of electroless plating was used to render a piece of paper conducting by conformably depositing metallic nickel nanoparticles, while still retaining the open macroporous framework. Proof-of-concept paper-electrodes are realized by modifying nickel-paper current collector with model electrocatalysts nickel-iron oxyhydroxide and nickel-molybdenum bimetallic alloy through electrodeposition route. The paper-electrodes demonstrate exceptional activities towards oxygen evolution reaction and hydrogen evolution reaction, requiring overpotentials of 240 and 32 mV at 50 and −10 mA cm
−2
, respectively, even as they endure extreme mechanical stress. The generality of this approach is demonstrated by fabricating similar electrodes on cotton fabric, which also show high activity. Finally, a two-electrode paper-electrolyzer is constructed which can split water with an efficiency of 98.01%, and exhibits robust stability for more than 200 h.
Water electrolysis provides a means to convert water into carbon-neutral fuels, but current devices are typically heavy, inflexible, or require costly substrates. Here, the authors transform paper and cotton fabrics into efficient, durable, and flexible supports for water-splitting electrocatalysts.
Journal Article
Fracture characteristics of rare-earth phosphate and silicate environmental barrier coatings under molten CMAS corrosion
2025
The fracture characteristics of rare-earth phosphate (LuPO
4
) and silicate (Lu
2
SiO
5
) environmental barrier coating (EBC) materials under molten calcium–magnesium aluminosilicate (CMAS) corrosion are analyzed. EBCs are crucial for protecting SiC-based ceramic matrix composite components in the hot section of gas turbine engines. Recently the rare-earth phosphates as EBC materials have shown better performance than third-generation rare-earth silicates under CMAS corrosion. However, the fracture of EBCs under CMAS corrosion during service remains a significant concern. This work investigates the fracture characteristics of LuPO
4
and Lu
2
SiO
5
using a combined experimental and computational approach. The computational model uses experimental micrographs and material properties obtained from fabricated EBC samples for fracture simulations. The simulation results are compared with experimental fracture toughness data and validated using statistical tests (
p
< 0.01). The results show significant degradation in fracture strength of EBC materials caused by CMAS penetration. EBC materials lost more than 40% of their initial fracture strength even at low penetration levels of 3% by volume. Simulation results show that LuPO
4
degraded more than Lu
2
SiO
5
. However, experimental observations from CMAS reaction tests demonstrate that LuPO
4
may exhibit higher fracture resistance than Lu
2
SiO
5
under similar CMAS corrosion conditions due to the formation of dense and thick passivation reaction layer. The insights gained from this study could be used to design EBCs with improved fracture resistance under CMAS corrosion.
Journal Article
CHARACTERIZATION OF FRACTION CONTAINING BETA ASARONE ISOLATED FROM ACORUS CALAMUS LINN. RHI- ZOMES AND STUDYING THE AMELIORATIVE EFFECT OF JUGLANS REGIA KERNEL OIL ON ITS ANTIEPILEPTIC PO- TENTIAL
2023
Sweet flag (Acorus calamus) has a long history of use in the treatment of a range of diseases, including inflammatory response, chest pain, digestive problems, and neurological disorders. The prime objective of the study is to isolate newer moieties from Acorus calamus (AC) rhizomes and to test their anticonvulsant potential with Juglans Regia Kernel Oil (Walnut Oil). Pharmacognostic standardization of AC rhizomes have been performed as per WHO guidelines of standardization. Methanolic extract of AC rhizomes was used for isolation of active moieties using column chromatography. Further, characterization of isolated moieties has been performed using UV, IR, 1H-NMR, C13- NMR and LCMS data. OECD 423 guidelines have been fol- lowed for the determination of oral acute toxicity. Swiss albino mice(n=6) were used for in-vivo studies. An- ticonvulsant study of isolated and characterized fraction of Beta Asarone was performed using scPTZ in- duced convulsion model. Pharmacognostic standardization of rhizomes showed results that fall within the pharmacopoeial limits. Spectral details of the fraction confirmed the identity as Beta Asarone. Juglans Regia Kernel oil and AC isolated fraction has shown a better ameliorative antiepileptic effect with prolonged time for seizure onset. Percentage protection has also been enhanced as compared to standard drug.
Journal Article
Development of Herbal Ayurvedic Formulation as Digestive Tablets, Evaluation of it’s Pharmaceutical, Pharmacognostic Parameters and Screening of its Antioxidant Potential
2021
Herbal digestive tablets are meant for treating indigestion problems. The indigestion problem is one of the major problems of all (the) ages of human beings. As trends for eating fast foods is increasing, simultaneously the improper digestion also tends to increase. There are a number of digestive tablets in the market but in attempt to improve their taste the actual motto behind their use is masked. To combat the indigestion problems, in the present study an attempt has been made to formulate, develop and evaluate herbal digestive tablets. The formula of the digestive tablet has been decided after deep review of Ayurvedic formulary of India. The ingredients of this formulation have been procured from authentic sources. The wet granulation method was used to prepare the granules for punching the tablets. After preparation, the herbal digestive tablets were subjected to various pharmaceutical evaluations and quality control evaluations as per the guidelines from World Health Organization (WHO). The formulation was also subjected to antioxidant screening using Phosphomolybdenum method. The digestive tablets are obtained as light brown-colored round tablets with pleasant odour and spicy taste with an average size of 8mm and smooth edges. Maximum extractive value was observed as 34% in methanol with a total ash value of 10.16%. Other parameters reported as bitterness value- 0.69 units, volatile oil content-8%, loss on drying- 12.3%, swelling and foaming index of 0.27 and less than 100 respectively. The tablets showed a total antioxidant potential of 0.51mg/mg as Ascorbic acid equivalent. Tablets also pass various pharmaceutical evaluation parameters like hardness, friability, weight variation, and disintegration test. Herbal digestive tablets have very excellent taste due to less bitter drugs. The tablet formula can be applied to prepare large scale production of digestive tablets.
Journal Article
Swarm UAVs Communication
by
Chatterjee, Sayan
,
Saha, Rahul
,
Mandal, Srilekha
in
Algorithms
,
Communication
,
Computer architecture
2024
The advancement in cyber-physical systems has opened a new way in disaster management and rescue operations. The usage of UAVs is very promising in this context. UAVs, mainly quadcopters, are small in size and their payload capacity is limited. A single UAV can not traverse the whole area. Hence multiple UAVs or swarms of UAVs come into the picture managing the entire payload in a modular and equiproportional manner. In this work we have explored a vast topic related to UAVs. Among the UAVs quadcopter is the main focus. We explored the types of quadcopters, their flying strategy,their communication protocols, architecture and controlling techniques, followed by the swarm behaviour in nature and UAVs. Swarm behaviour and a few swarm optimization algorithms has been explored here. Swarm architecture and communication in between swarm UAV networks also got a special attention in our work. In disaster management the UAV swarm network must have to search a large area. And for this proper path planning algorithm is required. We have discussed the existing path planning algorithm, their advantages and disadvantages in great detail. Formation maintenance of the swarm network is an important issue which has been explored through leader-follower technique. The wireless path loss model has been modelled using friis and ground ray reflection model. Using this path loss models we have managed to create the link budget and simulate the variation of communication link performance with the variation of distance.
Fracture Characteristics of Rare-earth Phosphate under Molten Calcium Magnesium Aluminosilicate Corrosion
2024
The fracture characteristics of LuPO4 rare-earth phosphate environmental barrier coating (EBC) material under molten calcium-magnesium aluminosilicate (CMAS) corrosion is quantified. EBCs are crucial for protecting SiC-based ceramic matrix composite components in the hot section of gas turbine engines. Recent research has highlighted the potential of rare-earth phosphates as better EBC materials than third-generation rare-earth silicates for CMAS corrosion resistance. However, the fracture of EBCs under CMAS corrosion during service remains a significant concern. This work investigates the fracture behavior of LuPO4 using mesoscale simulation and experiments. The model uses micrographs taken from fabricated EBC samples for mesoscale fracture simulations. The simulation results are compared with experimental fracture toughness data and validated using statistical tests (p<0.01). The simulation results and experimental observations demonstrate that LuPO4 may exhibit higher fracture resistance than Lu2SiO5 rare-earth silicate under similar CMAS corrosion conditions, offering potential insights for future EBC design and development.