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Value added transformation of ubiquitous substrates into highly efficient and flexible electrodes for water splitting
Value added transformation of ubiquitous substrates into highly efficient and flexible electrodes for water splitting
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Value added transformation of ubiquitous substrates into highly efficient and flexible electrodes for water splitting
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Value added transformation of ubiquitous substrates into highly efficient and flexible electrodes for water splitting
Value added transformation of ubiquitous substrates into highly efficient and flexible electrodes for water splitting

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Value added transformation of ubiquitous substrates into highly efficient and flexible electrodes for water splitting
Value added transformation of ubiquitous substrates into highly efficient and flexible electrodes for water splitting
Journal Article

Value added transformation of ubiquitous substrates into highly efficient and flexible electrodes for water splitting

2018
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Overview
Herein, we present an innovative approach for transforming commonly available cellulose paper into a flexible and catalytic current collector for overall water splitting. A solution processed soak-and-coat method of electroless plating was used to render a piece of paper conducting by conformably depositing metallic nickel nanoparticles, while still retaining the open macroporous framework. Proof-of-concept paper-electrodes are realized by modifying nickel-paper current collector with model electrocatalysts nickel-iron oxyhydroxide and nickel-molybdenum bimetallic alloy through electrodeposition route. The paper-electrodes demonstrate exceptional activities towards oxygen evolution reaction and hydrogen evolution reaction, requiring overpotentials of 240 and 32 mV at 50 and −10 mA cm −2 , respectively, even as they endure extreme mechanical stress. The generality of this approach is demonstrated by fabricating similar electrodes on cotton fabric, which also show high activity. Finally, a two-electrode paper-electrolyzer is constructed which can split water with an efficiency of 98.01%, and exhibits robust stability for more than 200 h. Water electrolysis provides a means to convert water into carbon-neutral fuels, but current devices are typically heavy, inflexible, or require costly substrates. Here, the authors transform paper and cotton fabrics into efficient, durable, and flexible supports for water-splitting electrocatalysts.