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The intriguing many-body phases of quantum matter arise from the interplay of particle interactions, spatial symmetries, and external fields. Generating these phases in an engineered system could provide deeper insight into their nature. Using superconducting qubits, we simultaneously realize synthetic magnetic fields and strong particle interactions, which are among the essential elements for studying quantum magnetism and fractional quantum Hall phenomena. The artificial magnetic fields are synthesized by sinusoidally modulating the qubit couplings. In a closed loop formed by the three qubits, we observe the directional circulation of photons, a signature of broken time-reversal symmetry. We demonstrate strong interactions through the creation of photon vacancies, or ‘holes’, which circulate in the opposite direction. The combination of these key elements results in chiral ground-state currents. Our work introduces an experimental platform for engineering quantum phases of strongly interacting photons. Superconducting circuits, coupled to form a ring in which a photonic excitation can circulate between sites, are established as a versatile platform for studying the interplay of strong particle interactions and external fields.

The realization of a quantum kicked top provides evidence for ergodic dynamics and thermalization in a small quantum system consisting of three superconducting qubits. Statistical mechanics is founded on the assumption that all accessible configurations of a system are equally likely. This requires dynamics that explore all states over time, known as ergodic dynamics. In isolated quantum systems, however, the occurrence of ergodic behaviour has remained an outstanding question 1 , 2 , 3 , 4 . Here, we demonstrate ergodic dynamics in a small quantum system consisting of only three superconducting qubits. The qubits undergo a sequence of rotations and interactions and we measure the evolution of the density matrix. Maps of the entanglement entropy show that the full system can act like a reservoir for individual qubits, increasing their entropy through entanglement. Surprisingly, these maps bear a strong resemblance to the phase space dynamics in the classical limit; classically, chaotic motion coincides with higher entanglement entropy. We further show that in regions of high entropy the full multi-qubit system undergoes ergodic dynamics. Our work illustrates how controllable quantum systems can investigate fundamental questions in non-equilibrium thermodynamics.

Superconducting quantum circuits are used to directly observe and characterize topological phase transitions; this approach promises to be a powerful and general platform for characterizing topological phenomena in quantum systems. Lab demonstrations of the topological Haldane model The quantum Hall effect leads to topologically protected edge states, and for a long time was thought to exclusively emerge in the presence of an external magnetic field. But in 1988, Duncan Haldane proposed a model in which this exotic electronics structure arises without this requirement. He proposed that, in a honeycomb lattice with a staggered flux, the necessary ingredients for a quantum Hall effect would be inherent in the material itself. The principles behind this concept were later recruited to design topological insulators, but in its original expression, the Haldane model has not been observed in the laboratory. In this issue of Nature , two groups report on progress connected to the Haldane model. Gregor Jotzu et al . report the first realization of the Haldane model and Pedram Roushan et al . show how it can be precisely measured. Jotzu et al . use ultracold fermions to realize the breaking of time-reversal and inversion symmetry — the two main requirements of the model — by implementing a circular modulation of the lattice position and an energy offset between neighbouring sites. Roushan et al . use superconducting quantum circuits — a Josephson junction sandwiched between superconducting electrodes — to realize a non-interacting form of the Haldane model with a single qubit and an interacting two-qubit model through a new experimental setup called 'gmon' coupling architecture. Their setup allows them to characterize both cases by measuring the Berry curvature, a feature that all topological structures have in common. Topology, with its abstract mathematical constructs, often manifests itself in physics and has a pivotal role in our understanding of natural phenomena. Notably, the discovery of topological phases in condensed-matter systems has changed the modern conception of phases of matter 1 , 2 , 3 , 4 , 5 . The global nature of topological ordering, however, makes direct experimental probing an outstanding challenge. Present experimental tools are mainly indirect and, as a result, are inadequate for studying the topology of physical systems at a fundamental level. Here we employ the exquisite control afforded by state-of-the-art superconducting quantum circuits to investigate topological properties of various quantum systems. The essence of our approach is to infer geometric curvature by measuring the deflection of quantum trajectories in the curved space of the Hamiltonian 6 . Topological properties are then revealed by integrating the curvature over closed surfaces, a quantum analogue of the Gauss–Bonnet theorem. We benchmark our technique by investigating basic topological concepts of the historically important Haldane model 7 after mapping the momentum space of this condensed-matter model to the parameter space of a single-qubit Hamiltonian. In addition to constructing the topological phase diagram, we are able to visualize the microscopic spin texture of the associated states and their evolution across a topological phase transition. Going beyond non-interacting systems, we demonstrate the power of our method by studying topology in an interacting quantum system. This required a new qubit architecture 8 , 9 that allows for simultaneous control over every term in a two-qubit Hamiltonian. By exploring the parameter space of this Hamiltonian, we discover the emergence of an interaction-induced topological phase. Our work establishes a powerful, generalizable experimental platform to study topological phenomena in quantum systems.

Chemical synthesis typically relies on reactions that generate complexity through elaboration of simple starting materials. Less common are deconstructive strategies toward complexity—particularly those involving carbon-carbon bond scission. Here, we introduce one such transformation: the hydrodealkenylative cleavage of C(sp³)–C(sp²) bonds, conducted below room temperature, using ozone, an iron salt, and a hydrogen atom donor. These reactions are performed in nonanhydrous solvents and open to the air; reach completion within 30 minutes; and deliver their products in high yields, even on decagram scales. We have used this broadly functionality tolerant transformation to produce desirable synthetic intermediates, many of which are optically active, from abundantly available terpenes and terpenoid-derived precursors. We have also applied it in the formal total syntheses of complex molecules.

Changes in digestive enzyme activity and histology were studied in Atractosteus tropicus embryos, larvae and juvenile periods. Alkaline protease, chymotrypsin, carboxypeptidase A, lipase and α-amylase were detected in all periods and gradually increased until reaching the maximum peak in juveniles; meanwhile, acid protease was first detected at 5 days after hatching (dah) when first feeding started and trypsin and leucine aminopeptidase activities were detected from 19 dah, their values being increased gradually until reaching a maximum value at 31 dah. Acid and alkaline phosphatase activities increased from yolk-sac absorption (3 dah) until day 31 after hatching. Zymogram for acid protease showed two bands in active forms (0.4 and 0.5 Rfs) from day 5 after hatching and a third protease form (0.3 Rf) that appears at 31 dah. Two active forms (26.3 and 24.9 kDa) were detected using SDS-PAGE alkaline proteases zymogram at 5 dah, and an additional active form (44.1 kDa) was detected at 7 dah. Regarding the histological development of the digestive system, the exocrine pancreas containing zymogen granules was already visible at 3 dah, whereas at 5 dah first gastric glands were already detected in the stomach. Between 7 and 9 dah, the digestive tract of A. tropicus resembled that of a juvenile specimen with a well-developed and short oesophagus, stomach divided into a glandular and non-glandular (pyloric) stomach, folded intestine with pyloric caeca and a well-developed spiral valve (posterior intestine). Considering this, larvae of A. tropicus are capable of digesting several foods from yolk absorption (3 dah), maximizing its activities at 15 dah, age at which the organisms maximize its capability to absorb nutrients from diets provided.

This paper presents the development of handmade paper from fique residues, evaluating its technical and environmental viability through a scientific approach aimed at supporting low-income rural communities. The residues were characterized to assess their suitability for papermaking, with fiber crystallinity and chemical structure analyzed using X-ray diffraction (XRD) and ATR-FTIR spectroscopy. Pulps were produced from fique fibers and a 30:70 fique fiber–bagasse blend using a chemical-free mechanical pulping process, designed for easy implementation in rural settings. The effects of dyeing on pulp performance were also examined, and environmental impacts were assessed through a Life-Cycle Assessment (LCA). The average fiber length, diameter, and lumen of fique fibers were 1.83 mm, 26.5 μm, and 17.4 μm, respectively. Handsheets from fique pulp achieved a tensile index of 13.0 N·m/g and a burst index of 1.42 kPa·m2/g, while the fique fiber–bagasse blend reached 11.09 N·m/g and 1.05 kPa·m2/g. The corresponding sheet densities were 0.316 and 0.380 g/cm3. The dyeing process led to a reduction in the mechanical strength of the handmade paper. Environmental analysis indicated that fique tow fiber has a more favorable impact profile than other non-wood alternatives, such as aquatic weed fiber. Compared to results from similar studies, fique demonstrates strong potential as a high-quality, sustainable raw material for artisanal papermaking. These findings support its application in decentralized, eco-friendly production systems, contributing to rural development and circular economy strategies.

Ecosystems are shaped by physical, chemical, and biological drivers, which affect the quality and quantity of basal energy sources, with impacts that cascade to higher trophic levels. In coastal, shelf, and marine habitats, terrestrial-derived organic matter (ter-OM) can be a key driver of ecosystem structure and function. Climate change is expected to alter land–ocean connectivity in many regions, with a broad range of potential consequences for impacted ecosystems, particularly in the coastal zone. The benthic compartment is an important link between the large organic carbon pools stored on land and the marine environment. At the same time, the macrofauna plays a key role in the processing, biological uptake, and fate of ter-OM in the aquatic environment, with implications for coastal ecosystem functioning, benthic–pelagic coupling, carbon burial, and biogeochemical cycles. However, information about relationships between land–ocean connectivity (including ter-OM loads) and coastal benthic community responses remains spread across disciplines, and a broad perspective on the potential impacts of a changing climate is still missing. Here, we explore the interplay between benthic macrofaunal communities and ter-OM through a paired narrative and research weaving analysis, which combines systematic mapping and bibliometric analysis. The review describes the past development and status of the research field as well as the lack of information in some geographical regions and habitats worldwide. We highlight the role of macrofauna in carbon cycling and the growing evidence that ter-OM plays a key role in the structure and function of benthic communities, not strictly limited to estuarine habitats. Climate change poses challenges for the prediction of future ter-OM fluxes and potential macrofauna responses to this additional stressor, thus requiring new methodological approaches (e.g., multimarker approaches for OM characterization) and long-term monitoring programs across different habitats and spatiotemporal scales.

Nutrient release from the sediments in shallow eutrophic estuaries may counteract reductions of the external nutrient load and prevent or prolong ecosystem recovery. The magnitude and temporal dynamics of this potential source, termed internal nutrient loading, is poorly under\\\-stood. We quantified the internal nutrient loading driven by microbial mineralization of accumulated organic N (ON) and P (OP) in sediments from a shallow eutrophic estuary (Odense Fjord, Denmark). Sediments were collected from eight stations within the system and nutrient production and effluxes were measured over a period of ~ 2 years. Dissolved inorganic nitrogen (DIN) effluxes were high initially but quickly faded to low and stable levels after 50–200 days, whereas PO43− effluxes were highly variable in the different sediments. Mineralization patterns suggested that internal N loading would quickly (< 200 days) fade to insignificant levels, whereas internal PO43− loading could be sustained for extended time (years). When results from all stations were combined, internal N loading and P loading from the fjord bottom was up to 121 × 103 kg N yr−1 (20 kg N ha−1 yr−1) and 22 × 103 kg P yr−1 (3.6 kg P ha−1 yr−1) corresponding to 6 (N) and 36% (P) of the external nutrient loading to the system. We conclude that the internal N loading resulting from degradation of accumulated ON is low in shallow eutrophic estuaries, whereas microbial mineralization of accumulated OP is a potential source of P. Overall it appears that, in N-limited eutrophic systems, internal nutrient resulting from mineralization of ON and OP in sediments is of minor importance.

Tropical gar (Atractosteus tropicus) is an economically and socially important freshwater species from Southeastern Mexico, with a high aquaculture potential. With this in mind, the purpose of this study was to characterize the digestive proteases of tropical gar juveniles through biochemical and electrophoretic analyses. Twenty specimens with an average weight of 73.6 ± 12.7 g were used to obtain stomach and intestinal tissue from which multienzymatic extracts were prepared. The general activities of the acid and alkaline proteases were evaluated, as well as the specific activities of trypsin, chymotrypsin, leucine aminopeptidase and carboxypeptidase A. The effect of the pH and temperature on the proteases was also analyzed, together with the composition of the multienzymatic extracts using protease inhibitors and electrophoretic tests. Results showed that A. tropicus have a functional stomach in which protein hydrolysis starts with pepsin and which contains endo- and exopeptidases (trypsin, chymotrypsin, leucine aminopeptidase and carboxypeptidase A) and proteases that are resistant to high temperatures (45 and 55 °C for alkaline and acid proteases, respectively) and pH values. Using zymogram technique, we found two acid protease isoforms (0.35 and 0.71 rf) and five alkaline protease isoforms (83.7, 43.7, 27.5, 24.0 and 19.4 kDa), which decrease or disappear with the different inhibitors. Thus, this species is considered to be a carnivore capable of adapting to its environment by consuming different types of proteins from preys and also could adapt rapidly to consume a compound diet with different animal protein sources.

Magnetic paper sheets were prepared from bleached sugarcane bagasse fibers and cobalt ferrite nanoparticles by lumen loading method. Sugarcane bagasse is an important fibrous raw material widely used worldwide for papermaking, whereas cobalt ferrite nanoparticles is an appropriate material for fibers modification given their magnetic properties. Cobalt ferrite nanoparticles were synthetized by coprecipitation method and coated with silica by hydrolysis and condensation of tetraethyl orthosilicate (TEOS) molecules. Then, silica coated magnetic nanoparticles were functionalized with polyethylenimine (PEI), as retention aid, by electrostatic bonding. It was observed that the loading degree of magnetic fibers depends on nanoparticles concentration and PEI dosage, which was determined by thermogravimetric analysis (TGA). Scanning electron microscope (SEM) shows the deposition of coated nanoparticles on the surface and into macropores of fibers. All samples exhibited ferromagnetic behavior. The coercivity values of magnetic fibers are higher than 0.2 kOe. This indicates that these fibers could be used to produce paper for magnetic recording purposes. Magnetic papers with 10 and 20% of modified fibers were manufactured. Brightness and tensile index of papers were decreased with the rise of loading degree. CIEL*a*b analysis shows the color differences between unmodified and modified papers.