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"Wu, B"
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Unmasking chloride attack on the passive film of metals
Nanometer-thick passive films on metals usually impart remarkable resistance to general corrosion but are susceptible to localized attack in certain aggressive media, leading to material failure with pronounced adverse economic and safety consequences. Over the past decades, several classic theories have been proposed and accepted, based on hypotheses and theoretical models, and oftentimes, not sufficiently nor directly corroborated by experimental evidence. Here we show experimental results on the structure of the passive film formed on a FeCr
15
Ni
15
single crystal in chloride-free and chloride-containing media. We use aberration-corrected transmission electron microscopy to directly capture the chloride ion accumulation at the metal/film interface, lattice expansion on the metal side, undulations at the interface, and structural inhomogeneity on the film side, most of which had previously been rejected by existing models. This work unmasks, at the atomic scale, the mechanism of chloride-induced passivity breakdown that is known to occur in various metallic materials.
Collecting experimental evidence of chloride ion attack on protective passive metallic films due to corrosion remains challenging. Here, the authors show that the boundaries between nanocrystals and amorphous regions in the passive film ease chloride transport even as they do not coincide with areas of high chloride concentration.
Journal Article
Enhanced corrosion resistance by engineering crystallography on metals
Nanometer-thick passive films, which impart superior corrosion resistance to metals, are degraded in long-term service; they are also susceptible to chloride-induced localized attack. Here we show, by engineering crystallographic configurations upon metal matrices adjacent to their passive films, we obtain great enhancement of corrosion resistance of FeCr15Ni15 single crystal in sulphuric acid, with activation time up to two orders of magnitude longer than that of the non-engineered counterparts. Meanwhile, engineering crystallography decreases the passive current density and shifts the pitting potential to noble values. Applying anodic polarizations under a transpassivation potential, we make the metal matrices underneath the transpassive films highly uneven with {111}-terminated configurations, which is responsible for the enhancement of corrosion resistance. The transpassivation strategy also works in the commercial stainless steels where both grain interior and grain boundaries are rebuilt into the low-energy configurations. Our results demonstrate a technological implication in the pretreatment process of anti-corrosion engineering.
Passive films on metal surfaces provide better corrosion resistance, but they can degrade in long-term service. Here the authors demonstrate a strategy to engineer crystallographic configuration at the metal/film interface to further improve corrosion resistance.
Journal Article
Autism-associated Dyrk1a truncation mutants impair neuronal dendritic and spine growth and interfere with postnatal cortical development
Autism is a prevailing neurodevelopmental disorder with a large genetic/genomic component. Recently, the dual-specificity tyrosine-(Y)-phosphorylation-regulated kinase 1 A (DYRK1A) gene was implicated as a risk factor for autism spectrum disorder (ASD). We identified five DYRK1A variants in ASD patients and found that the dose of DYRK1A protein has a crucial role in various aspects of postnatal neural development. Dyrk1a loss of function and gain of function led to defects in dendritic growth, dendritic spine development and radial migration during cortical development. Importantly, two autism-associated truncations, R205X and E239X, were shown to be Dyrk1a loss-of-function mutants. Studies of the truncated Dyrk1a mutants may provide new insights into the role of Dyrk1a in brain development, as well as the role of Dyrk1a loss of function in the pathophysiology of autism.
Journal Article
Dual heterogeneous structures lead to ultrahigh strength and uniform ductility in a Co-Cr-Ni medium-entropy alloy
Alloys with ultra-high strength and sufficient ductility are highly desired for modern engineering applications but difficult to develop. Here we report that, by a careful controlling alloy composition, thermomechanical process, and microstructural feature, a Co-Cr-Ni-based medium-entropy alloy (MEA) with a dual heterogeneous structure of both matrix and precipitates can be designed to provide an ultra-high tensile strength of 2.2 GPa and uniform elongation of 13% at ambient temperature, properties that are much improved over their counterparts without the heterogeneous structure. Electron microscopy characterizations reveal that the dual heterogeneous structures are composed of a heterogeneous matrix with both coarse grains (10∼30 μm) and ultra-fine grains (0.5∼2 μm), together with heterogeneous L1
2
-structured nanoprecipitates ranging from several to hundreds of nanometers. The heterogeneous L1
2
nanoprecipitates are fully coherent with the matrix, minimizing the elastic misfit strain of interfaces, relieving the stress concentration during deformation, and playing an active role in enhanced ductility.
Improving both strength and ductility simultaneously in structural metals and alloys remains a challenge. Here, the authors design a heterogeneous structure in a Co-Cr-Ni alloy that results in ultrahigh strength and significant uniform elongation.
Journal Article
Polar meron lattice in strained oxide ferroelectrics
A topological meron features a non-coplanar structure, whose order parameters in the core region are perpendicular to those near the perimeter. A meron is half of a skyrmion, and both have potential applications for information carrying and storage. Although merons and skyrmions in ferromagnetic materials can be readily obtained via inter-spin interactions, their behaviour and even existence in ferroelectric materials are still elusive. Here we observe using electron microscopy not only the atomic morphology of merons with a topological charge of 1/2, but also a periodic meron lattice in ultrathin PbTiO
3
films under tensile epitaxial strain on a SmScO
3
substrate. Phase-field simulations rationalize the formation of merons for which an epitaxial strain, as a single alterable parameter, plays a critical role in the coupling of lattice and charge. This study suggests that by engineering strain at the nanoscale it should be possible to fabricate topological polar textures, which in turn could facilitate the development of nanoscale ferroelectric devices.
Merons are topological structures, but these have yet to be directly observed in ferroelectrics. Here, by epitaxially straining PbTiO
3
on a SmScO
3
substrate, electron microscopy and phase-field modelling allow the morphology and distribution of merons to be observed.
Journal Article
Spatial and temporal patterns of greenhouse gas emissions from Three Gorges Reservoir of China
Anthropogenic activity has led to significant emissions of greenhouse gas (GHG), which is thought to play important roles in global climate changes. It remains unclear about the kinetics of GHG emissions, including carbon dioxide (CO2), methane (CH4) and nitrous Oxide (N2O) from the Three Gorges Reservoir (TGR) of China, which was formed after the construction of the famous Three Gorges Dam. Here we report monthly measurements for one year of the fluxes of these gases at multiple sites within the TGR region, including three major tributaries, six mainstream sites, two downstream sites and one upstream site. The tributary areas have lower CO2 fluxes than the main storage; CH4 fluxes in the tributaries and upper reach mainstream sites are relative higher. Overall, TGR showed significantly lower CH4 emission rates than most new reservoirs in temperate and tropical regions. We attribute this to the well-oxygenated deep water and high water velocities that may facilitate the consumption of CH4. TGR's CO2 fluxes were lower than most tropical reservoirs and higher than most temperate systems. This could be explained by the high load of labile soil carbon delivered through erosion to the Yangtze River. Compared to fossil-fuelled power plants of equivalent power output, TGR is a very small GHG emitter – annual CO2-equivalent emissions are approximately 1.7% of that of a coal-fired generating plant of comparable power output.
Journal Article
Clinical Laboratory Practice Recommendations for the Use of Cardiac Troponin in Acute Coronary Syndrome: Expert Opinion from the Academy of the American Association for Clinical Chemistry and the Task Force on Clinical Applications of Cardiac Bio-Markers of the International Federation of Clinical Chemistry and Laboratory Medicine
This document is an essential companion to the third iteration of the National Academy of Clinical Biochemistry [NACB,8 now the American Association for Clinical Chemistry (AACC) Academy] Laboratory Medicine Practice Guidelines (LMPG) on cardiac markers. The expert consensus recommendations were drafted in collaboration with the International Federation of Clinical Chemistry and Laboratory Medicine Task Force on Clinical Applications of Bio-Markers (IFCC TF-CB). We determined that there is sufficient clinical guidance on the use of cardiac troponin (cTn) testing from clinical practice groups. Thus, in this expert consensus document, we focused on clinical laboratory practice recommendations for high-sensitivity (hs)-cTn assays. This document utilized the expert opinion class of evidence to focus on the following 10 topics: (a) quality control (QC) utilization, (b) validation of the lower reportable analytical limits, (c) units to be used in reporting measurable concentrations for patients and QC materials, (d) 99th percentile sex-specific upper reference limits to define the reference interval; (e) criteria required to define hs-cTn assays, (f) communication with clinicians and the laboratory's role in educating clinicians regarding the influence of preanalytic and analytic problems that can confound assay results, (g) studies on hs-cTn assays and how authors need to document preanalytical and analytical variables, (h) harmonizing and standardizing assay results and the role of commutable materials, (i) time to reporting of results from sample receipt and sample collection, and (j) changes in hs-cTn concentrations over time and the role of both analytical and biological variabilities in interpreting results of serial blood collections.
Journal Article
Diversity in Clinical and Biomedical Research: A Promise Yet to Be Fulfilled
Esteban Gonzalez Burchard and colleagues explore how making medical research more diverse would aid not only social justice but scientific quality and clinical effectiveness, too.Esteban Gonzalez Burchard and colleagues explore how making medical research more diverse would aid not only social justice but scientific quality and clinical effectiveness, too.
Journal Article
One-dimensional photonic bound states in the continuum
In 1985 Fridriech and Wintgen proposed a mechanism for bound states in the continuum based on full destructive interference of two resonances which can be easily applied to the two- and three-dimensional wave systems. Here we explicitly show that this mechanism can be realized in one-dimensional quantum potential well, owing to destructive interference of electron paths with different spin in tilted magnetic field. Due to one-by-one correspondence between the spin of the electron and the polarization state of light, we have found numerous bound states in the continuum in the one-dimensional photonic system and experimentally confirmed them. The experimental set-up consists of the one-dimensional photonic crystal conjugated with a liquid-crystalline anisotropic defect layer and covered by metal film.
Bound states in the continuum have recently found application to sensing, lasing and optoelectronics, but have not been realised in 1D. Here, destructive interference of electron spin in a tilted magnetic field is shown to give rise to bound states in the continuum of a 1D layered photonic crystal.
Journal Article