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Planar micro-supercapacitors show great potential as the energy storage unit in miniaturized electronic devices. Asymmetric structures have been widely inves- tigated in micro-supercapacitors, and carbon-based materials are commonly applied in the electrodes. To integrate different metal oxides in both electrodes in micro-supercapacitors, the critical challenge is the pairing of different faradic metal oxides. Herein, we propose a strategy of matching the voltage and capadtance of two faradic materials that are fully integrated into one high-performance asymmetric micro-supercapacitor by a facile and controllable fabrication process. The fabricated micro-supercapacitors employ MnO2 as the positive active material and Fe203 as the negative active material, respectively. The planar asymmetric micro-supercapacitors possess a high capacitance of 60 F-cm-3, a high energy density of 12 mW.h.cm-3, and a broad operation voltage range up to 1.2 V.

Structure units containing all-carbon quaternary stereogenic center are found in many bioactive natural products. However, enantioselective construction of this type of structure units has been a formidable challenge for synthetic community due to the steric hindrance enforced by all-carbon quatemary stereocenters. In this review, we present the achievements made by Chinese scientists in the area of asymmetric synthesis of all-carbon quaternary stereocenters in natural products during the past two years.

The sensitivity of TC intensification and track to the initial inner-core structure on a β plane is investigated using a numerical model. The results show that the vortex with large inner-core winds（CVEX-EXP） experiences an earlier intensification than that with small inner-core winds（CCAVE-EXP）, but they have nearly the same intensification rate after spin-up. In the early stage, the convective cells associated with surface heat flux are mainly confined within the inner-core region in CVEXEXP, whereas the vortex in CCAVE-EXP exhibits a considerably asymmetric structure with most of the convective vortices being initiated to the northeast in the outer-core region due to the β effect. The large inner-core inertial stability in CVEX-EXP can prompt a high efficiency in the conversion from convective heating to kinetic energy. In addition, much stronger straining deformation and PBL imbalance in the inner-core region outside the primary eyewall ensue during the initial development stage in CVEX-EXP than in CCAVE-EXP, which is conducive to the rapid axisymmetrization and early intensification in CVEX-EXP. The TC track in CVEX-EXP sustains a northwestward displacement throughout the integration, whereas the TC in CCAVE-EXP undergoes a northeastward recurvature when the asymmetric structure is dominant. Due to the enhanced asymmetric convection to the northeast of the TC center in CCAVE-EXP, a pair of secondary gyres embedded within the large-scale primary β gyres forms, which modulates the ventilation flow and thus steers the TC to move northeastward.

In this paper we continue the study of discontinuous Galerkin finite element methods for nonlinear diffusion equations following the direct discontinuous Galerkin （DDG） meth- ods for diffusion problems [17] and the direct discontinuous Galerkin （DDG） methods for diffusion with interface corrections [18]. We introduce a numerical flux for the test func- tion, and obtain a new direct discontinuous Galerkin method with symmetric structure. Second order derivative jump terms are included in the numerical flux formula and explicit guidelines for choosing the numerical flux are given. The constructed scheme has a sym- metric property and an optimal L2 （L2） error estimate is obtained. Numerical examples are carried out to demonstrate the optimal （k ＋ 1）th order of accuracy for the method with pk polynomial approximations for both linear and nonlinear problems, under one-dimensional and two-dimensional settings.

We used a two-dimensional quasi-geostrophic barotropic model simulation to study effects of an initial brows-like meso-scale vortex on tropical cyclone （TC） track. Our results show that the impact of each of the three foundational factors （the environ- mental current, the asymmetric structure and the asymmetric convection system） on TC track varies with time and the im- portance of each of the factors is different for the different TC motion time period. They show two kinds of the effects. One is a direct way. The asymmetric outer wind structure and the positive longitudinal wind speed averaged in radial-band （100-300） km in the period of （0-11） h are caused by the introduction of the initial brows-like meso-scale vortex, which results in TC track to turn to the north from the northwest directly. The other is an indirect influence. First, initial TC axisymmetric circula- tion becomes a non-axisyrnmetric circulation after the addition of the meso-scale vortex. The initial non-axisymmetric circula- tion experiences an axisymmetrizational process in the period of （0-11） h. Second, axisymmetrizationed TC horizontal size is enlarged after t=-12 h. Third, both the TC asymmetric structure and the TC energy dispersion induced-anticyclone are intensi- fied, which quickens the TC motion and results in the track to turn to the north indirectly. The TC motion is characterized by the unusual track under the direct and the indirect effect. The formation of the unusual track should be attributed to the com- mon effects of three factors, including the environmental flow, the TC asymmetric structure and the asymmetric convection

Unidirectional acoustic transmission has been investigated in an asymmetric bull＇s eye structure, which consistes of a sub- wavelength hole with concentric grooves on one side of a thin steel plate. When acoustic waves impinge normally on the groove side of the asymmetric structure, a strong acoustic transmitted energy flux is observed in the frequency range of 400-450 kHz, while there is no obvious transmitted energy flux in the same frequency range if the acoustic waves impinge normally on the other side. Thus, a remarkable unidirectional acoustic transmission behavior is exhibited by the current struc- ture. With changing the period of the grooves, it is found that the transmitted acoustic energy flux keeps unchanged while the frequency of the transmitted waves can be modified. The experiments are performed, which has confirmed the unidirectional acoustic transmission behavior in the asymmetric bull＇s eye structure. The asymmetric bull＇s eye structure may have potential application in ultrasound diagnosis and therapy.

The precipitation during landfall of typhoon Haitang （2005） showed asymmetric structures （left side/right side of the track）. Analysis of Weather Research and Forecasting model simulation data showed that rainfall on the right side was more than 15 times stronger than on the left side. The causes were analyzed by focusing on comparing the water vapor flux, stability and upward motion between the two sides. The major results were as follows： （1） Relative humidity on both sides was over 80%, whereas the convergence of water vapor flux in the lower troposphere was about 10 times larger on the right side than on the left side. （2） Both sides featured conditional symmetric instability [MPV （moist potential vorticity） 〈0], but the right side was more unstable than the left side. （3） Strong （weak） upward motion occurred throughout the troposphere on the right （left） side. The Q vector diagnosis suggested that large-scale and mesoscale forcing accounted for the difference in vertical velocity. Orographic lift and surface friction forced the development of the asymmetric precipitation pattern. On the right side, strong upward motion from the forcing of different scale weather systems and topography caused a substantial release of unstable energy and the transportation of water vapor from the lower to the upper troposphere, which produced torrential rainfall. However, the above conditions on the left side were all much weaker, which led to weaker rainfall. This may have been the cause of the asymmetric distribution of rainfall during the landfall of typhoon Haitang.

Single crystals of K3Y3（BO3）4 were grown using the KBO2, LiF, and Li2CO3 as the fluxes by the top-seed solution method. The K3Y3（BO3）4 can be an excellent host for doping of Yb3＋, because there are six low-symmetric yttrium atoms in one unit-cell of K3Y3（B 03）4. The growth of K3Y3（BO3）4 was studied in detail, and a good crystal with sizes of 24 mm × 15 mm× 8 mm was grown successfully below 900 ℃. Some characteristics, such as the X-ray dif- fraction, infrared spectroscopy, and thermal analysis, were also performed.

Ultraslow-light effects in two-dimensional hexagonal-lattice coupled waveguide with moon-like scat- terers were theoretically studied using the plane-wave expansion method. For symmetric structures, simulations showed that slow light with high group index can be achieved by shifting the scatterers and adjusting the radius of moon-like scatterers. The maximum group index was over 8.0 × 10^4. For asymmetric structures, simulations showed that slow light with flat band and high group index can be obtained by shifting the scatterers, adjusting the radius of moon-like scatterers, and rotating the scatterers. The maximum group index was over 5.7 ×10^5 with a ＂saddle-like＂ relationship between the frequency and group index.

In view of the recognition of the importance of the interdependent behavior of strength and stiffness of walltype structural elements,the seismic demand of plan-asymmetric systems is revisited.Useful strength distribution strategies,i.e.,＇Center of Strength-Center of Mass（CV-CM） coinciding＇ and ＇Balanced Center of Strength-Center of Resistance（CVCR）＇ are adopted.Design charts for the seismic demand of classical uni-directionally and bi-directionally asymmetric systems are developed in a simple unified format.A conceptual framework is also outlined to conveniently apply the design charts.Illustrations are included to explain the use of the current recommendations in practical design.The study also highlights the relative performance of ＇CV-CM coinciding＇ and ＇Balanced CV-CR＇ criteria.