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Both mantle plumes and passive margin extension have been recognized as crucial mechanisms governing intracontinental volcanism and lithospheric evolution. However, the synergistic interactions between these two processes in modulating lithospheric modification remain poorly constrained. The Leiqiong volcanic area (LQV), on the northern continental margin of the South China Sea, has witnessed intense volcanic activity since the late Cenozoic. Though geophysical imaging show mantle plume beneath LQV, limited resolution hinders our understanding of lithospheric modification and magmatic processes. In this study, analysis of teleseismic waveforms from newly deployed broadband stations reveals the lithospheric thinning to the south of LQV, crustal thinning, high stretching factors, high Vp/Vs ratios and crustal melting within LQV. In comparison with global hotspots modulating lithospheric architecture and melting, our results offer seismological evidence that passive margin dynamics rival mantle plumes in lithospheric modification, highlighting a plume‐lithosphere interaction that jointly drives volcanism and continental margin destabilization through multi‐mechanisms.

Zircon inheritance is a common phenomenon in igneous rocks, although more frequent in granitoids. Zircons inherited from granite magmas mostly come from the source, not from wall rocks or xenoliths. Consequently, they can provide invaluable information about the source materials, melting temperature, and melt segregation conditions. Miller et al. (Geology 31:529–532, 2003) divided granite rocks according to their zircon saturation temperature (TZr) into “hot” (TZr > 800 °C, with little or no inherited zircon) and “cold” (TZr < 800 °C; with abundant inherited zircon). Nevertheless, we have found that coeval and neighboring two-mica granites with TZr < 750 °C, presumably derived from similar sources, may have a radically different inheritance, from about 95 to near 0%. This paper aims to understand the reasons for these differences, in particular, and the survival of source zircons in granitoids, in general. To this end, we modeled the relationships between source composition, temperature, pressure, water content, zircon solubility, and melt fraction, on one hand; and melt production and zircon solution rates, on the other hand. Our results foresee that zircon survival during crustal melting is more probable if the source is a fertile peraluminous metasedimentary rock than if it is a metaluminous source with similar SiO2. Elevated zircon inheritance is characteristic of mid-crustal S-type, water-rich granite magmas generated within 4.5 and 6 kbar. Moderate or no inheritance is characteristic of water-poor granite magmas, because their sources require higher temperatures to produce the same melt fraction. Fast melt extraction does not cause perceptible effects on our models, because melt generation is slower than zircon dissolution, except in the case of crustal underplating by hot mafic magmas. We propose to refine the “hot” and “cold” classification by splitting the “cold” granites (TZr < 800 °C) into two categories, “dry” with little inheritance and “wet” with a very high zircon inheritance. Wet granites require a source water-fluxed from outside. They are characteristic of mid-crustal anatectic complexes with highly fertile gneisses alternating with unfertile mica-rich metapelites. We suggest that the extra water should come in most cases from dehydration reactions in the unfertile metasedimentary rocks beneath the crustal section undergoing anatexis.

The Velay anatectic dome in the Variscan French Massif Central exposes a low-pressure–high-temperature metamorphic sequence, which represents an ideal natural laboratory for documenting the behavior of rare-metals and fluxing elements during crustal melting. We investigated the silicate and bulk-rock geochemistry of sub- to suprasolidus metapelites and orthogneisses, as well as related granites, and performed forward thermodynamically constrained geochemical modeling to quantify the respective effects of melting pressure, temperature, H2O activity, and protolith composition on the Li and F contents of granitic melts. We find that biotite compositions are good proxies of melt compositional evolutions during prograde melting. The crystallization of peritectic cordierite at low pressure (< 5 kbar) and “water-fluxed” melting both inhibit the Li enrichment of anatectic melts. Metapelite-derived melts consistently show modest Li–F contents, and a decoupling is observed as melts with the highest Li concentrations (~ 200–400 ppm) are produced below 750 °C, whereas F-richest melts (~ 0.2–0.4 wt%) are produced above 750 °C near the biotite-out isograd. Peraluminous orthogneiss anatexis can generate a melt that is concomitantly enriched in both F (~ 0.3–1 wt%) and Li (~ 600–1350 ppm) at relatively low temperature (< 750 °C), which can evolve toward rare-metal granite compositions (~ 10,000 ppm Li; ~ 2 wt% F) after 80–90 wt% of fractional crystallization. Melting of felsic meta-igneous rocks followed by magmatic differentiation is thus a viable mechanism to form Li-F-rich rare-metal granites and pegmatites, providing a direct link between protracted crust recycling and rare-metal magmatism in late-orogenic settings.

The formation of major granite-hosted Sn and/or W deposits and lithium–cesium–tantalum (LCT) type pegmatites in the Acadian, Variscan, and Alleghanian orogenic belts of Europe and Atlantic Northern America involves weathering-related Sn and W enrichment in the sedimentary debris of the Cadomian magmatic arc and melting of these sedimentary source rocks during later tectonic events, followed by magmatic Sn and W enrichment. We suggest that within this, more than 3,000-km long late Paleozoic belt, large Sn and/or W deposits are only found in regions where later redeposition of the Sn–W-enriched weathered sediments, followed by tectonic accumulation, created large volumes of Sn–W-enriched sedimentary rocks. Melting of these packages occurred both during the formation of Pangea, when continental collision subjected these source rocks to high-grade metamorphism and anatexis, and during post-orogenic crustal extension and mantle upwelling. The uncoupling of source enrichment and source melting explains (i) the diachronous occurrence of tin granites and LCT pegmatites in this late Paleozoic orogenic belt, (ii) the occurrence of Sn and/or W mineralizations and LCT pegmatites on both sides of the Rheic suture, and (iii) the contrasting tectonic setting of Sn and/or W mineralizations within this belt. Source enrichment, sedimentary and tectonic accumulation of the source rocks, and heat input to mobilize metals from the source rocks are three unrelated requirements for the formation of Sn and/or W granites. They are the controlling features on the large scale. Whether a particular granite eventually generates a Sn and/or W deposit depends on local conditions related to source melting, melt extraction, and fractionation processes.

Pegmatitic dyke-like carbonate rocks mainly composed of very coarse-grained calcite, are a rare type of carbonate rocks found in some of orogenic belts in the world. These specific carbonate rocks generally occur intimately with high-temperature granulites and marbles. In the Proterozoic Highland Complex of Sri Lanka which is a segment of the Mozambique suture, they are associated with marbles and granitic pegmatites, and intercalated with high-grade calc-silicate gneisses and highly folded ortho- and para-gneisses. These pegmatitic carbonate rocks do not show any signs of metamorphic or deformed overprint, but instead well preserve igneous textures and contain various silicate crustal xenoliths. The calcite crystals occur as euhedral to subhedral grains and are large in size from 1 to 15 cm. The diverse colors of calcite from white to yellow and blue derive from mineral inclusions and their own compositions. Non-carbonate minerals, commonly present in typical carbonatites such as phlogopite, apatite, clinopyroxene, olivine, plagioclase, iron oxides and spinel, are all found in the rocks. Meanwhile, a skarn-type assemblage of wollastonite, garnet, clinopyroxene and sulfide occurs in contact between the carbonate rocks and gneiss xenoliths, which probably resulted from antiskarn reactions. Chemical compositions of major constituent minerals (calcite, dolomite and apatite) of the carbonate rocks are intermediate between typical marbles and mantle-derived carbonatites and akin to crustal-origin carbonatites worldwide. We thus classify the studied rocks as ‘anatectic carbonatite pegmatite’, and suggest that they originated from the melting of a mixture of marbles and surrounding silicate rocks at crustal levels during high-temperature metamorphism.

The Cenozoic Alpine, and Paleozoic Variscan and eo-Variscan collisional belts are compared in the framework of the Wilson cycle considering differences between cold and hot orogens. The W. Alps result of the opening and closure of the Liguro-Piemonte ocean, whereas the Paleozoic Eo-variscan and Variscan orogenies document multiple ocean openings and collisions in space and a polyorogenic history in time. Jurassic or Early Ordovician break-up of Pangea or Pannotia megacontinents led to the formation of passive continental margins, and the opening of Liguro-Piemonte, or Rheic, Tepla-Le Conquet, and Medio-European oceans, respectively. In Paleozoic or Mesozoic, microcontinents such as Apulia and Sesia or Armorica and Saxo-Thuringia were individualized. The oceanic convergence stage was associated with the development of arcs and back-arc basins in the Variscan belt but magmatic arcs are missing in the W. Alps, and inferred in the Eo-variscan one. Though the nappe stack is mainly developed in the subducted European or Gondwana crust in the western Alps and Eo-variscan cases, the Moldanubian nappes formed in the upper plate in the Variscan case. The Alpine and Variscan metamorphic evolutions occurred under ca. 8 °C/km and 30 °C/km gradients, respectively. During the late- to post-orogenic stages, all belts experienced “unthickening” accommodated by extensional tectonics, metamorphic retrogression, and intramontane basin opening. The importance of crustal melting, represented by migmatites, granites, and hydrothermal circulations in the Variscan and Eo-Variscan belts is the major difference with the W. Alpine one. The presence, or absence, of a previous Variscan or Cadomian continental basement might have also influenced the rheological behavior of the crust.

We present elemental and Sr–Nd–Pb isotopic data for the magmatic suite (~79 Ma) of the Harşit pluton, from the Eastern Pontides (NE Turkey), with the aim of determining its magma source and geodynamic evolution. The pluton comprises granite, granodiorite, tonalite and minor diorite (SiO 2  = 59.43–76.95 wt%), with only minor gabbroic diorite mafic microgranular enclaves in composition (SiO 2  = 54.95–56.32 wt%), and exhibits low Mg# (<46). All samples show a high-K calc-alkaline differentiation trend and I-type features. The chondrite-normalized REE patterns are fractionated [(La/Yb) n  = 2.40–12.44] and display weak Eu anomalies (Eu/Eu* = 0.30–0.76). The rocks are characterized by enrichment of LILE and depletion of HFSE. The Harşit host rocks have weak concave-upward REE patterns, suggesting that amphibole and garnet played a significant role in their generation during magma segregation. The host rocks and their enclaves are isotopically indistinguishable. Sr–Nd isotopic data for all of the samples display I Sr  = 0.70676–0.70708, ε Nd (79 Ma) = −4.4 to −3.3, with T DM  = 1.09–1.36 Ga. The lead isotopic ratios are ( 206 Pb/ 204 Pb) = 18.79–18.87, ( 207 Pb/ 204 Pb) = 15.59–15.61 and ( 208 Pb/ 204 Pb) = 38.71–38.83. These geochemical data rule out pure crustal-derived magma genesis in a post-collision extensional stage and suggest mixed-origin magma generation in a subduction setting. The melting that generated these high-K granitoidic rocks may have resulted from the upper Cretaceous subduction of the Izmir–Ankara–Erzincan oceanic slab beneath the Eurasian block in the region. The back-arc extensional events would have caused melting of the enriched subcontinental lithospheric mantle and formed mafic magma. The underplating of the lower crust by mafic magmas would have played a significant role in the generation of high-K magma. Thus, a thermal anomaly induced by underplated basic magma into a hot crust would have caused partial melting in the lower part of the crust. In this scenario, the lithospheric mantle-derived basaltic melt first mixed with granitic magma of crustal origin at depth. Then, the melts, which subsequently underwent a fractional crystallization and crustal assimilation processes, could ascend to shallower crustal levels to generate a variety of rock types ranging from diorite to granite. Sr–Nd isotope modeling shows that the generation of these magmas involved ~65–75% of the lower crustal-derived melt and ~25–35% of subcontinental lithospheric mantle. Further, geochemical data and the Ar–Ar plateau age on hornblende, combined with regional studies, imply that the Harşit pluton formed in a subduction setting and that the back-arc extensional period started by least ~79 Ma in the Eastern Pontides.

Anatectic magmas form plutons or accumulate in the core of anatectic domes. Both scenarios have distinct implications on the behaviour of the continental crust during orogenic evolution from collision to collapse. Considering a stepwise extraction of melt, we simulate the evolution of anatectic melt and of solid residues produced in the crust from collision to collapse using thermodynamic modelling. We also simulate the effect of entrainment of source material (restite-unmixing and peritectic assemblage entrainment) on the compositional range of the resulting magmas. The results are then compared to the compositions of lower crustal xenoliths and of peraluminous granites in both plutons and anatectic dome in the southeastern French Massif Central (SE-FMC). From our calculations, we identify two type of anatectic melts (1) cool-and-wet produced at low-temperature (< 800 °C) which release fluids during crystallisation and (2) hot-and-dry produced at high-temperature (> 750 °C) which only release fluids at the end of crystallisation. When emplaced around 0.4 GPa, cold-and-wet melts are produced by muscovite-dehydration melting reactions; hot-and-dry are produced by biotite-dehydration melting. In the SE-FMC, the Velay dome is cored by the Velay granite, intruded by small bodies of Velay leucogranite and surrounded by plutons made of either two mica leucogranite (MPG) or cordierite-bearing granite (CPG). MPG and Velay leucogranite compositions are best reproduced by cool-and-wet magmas. CPG and Velay granite compositions are best reproduced by hot-and-dry magmas. Melt extraction after biotite dehydration melting leaves residues that are similar in composition to lower-crustal xenoliths. Magmas forming plutons migrate freely toward the upper crust forming plutons with distinct compositions. On the contrary, to form a dome, magmas are retained on the way up. The emplacement and accumulation of magma at deeper level enhances (or trigger) melting due to the addition of heat (from hot-and-dry) and fluids (from cool-and-wet). The accumulation of magma and the in situ melting increases melt fraction and has consequence to weaken the middle crust and leads to the formation of an anatectic dome. We suggest that magmas are retained due to lithological heterogeneities in the crust. In the case of the Velay dome, a large orthogneiss formation similar to the Velay orthogneiss formation may have played that role.

We report on the oxygen isotope composition of Jurassic rhyolites from a silicic large igneous province, the Chon Aike Province (Patagonia, Argentina). Quartz is shown to have refractory behavior with respect to diffusional oxygen isotope exchange, making it a robust tracer of magmatic processes. Detailed secondary ion mass spectroscopy (SIMS) transects across 24 quartz crystals reveal homogeneous, but elevated, oxygen isotope values (10.9-12.5 ppm). None of the analyzed grains display distinct discontinuities in 18O values. Late hydrothermal exchange is limited to a few tens of micrometers next to cracks, some grain boundaries, and inclusions. No correlation with igneous zoning as revealed by cathodoluminescence (CL) was found. Finally, quartz crystals display little to no inter-grain variability at a sample or outcrop scale. Zircons (7.5-10.1 ppm), in contrast, display significant inter-crystalline oxygen isotopic heterogeneity (>2.0 ppm) at a sample scale, but core-rim analyses reveal no systematic variations. This is interpreted to confirm the antecrystic nature of zircons, while quartz crystals mostly are phenocrysts. The studied quartz and zircon provide, hence, complementary information on the evolution of the magmatic system of the Chon Aike Province. Zircon likely captures information about the deeper source region, in contrast to quartz that will record the last stages of the magmatic system and thus might provide important information on the buildup and duration of magma chamber processes in the upper crust. The data illustrate that quartz-in the absence of recrystallization-can retain its magmatic signature and is thus a useful tracer of pre-eruptive magmatic processes. The high δ18O values of both zircon and quartz require a significant (>50%) crustal-most likely sedimentary-contribution in the melt formation process, either via assimilation or anatexis. This conclusion yields new constraints on petrological models for the Chon Aike Province.

Lunar silicic rocks were first identified by granitic fragments found in samples brought to Earth by the Apollo missions, followed by the discovery of silicic domes on the lunar surface through remote sensing. Although these silicic lithologies are thought to make up a small portion of the lunar crust, their presence indicates that lunar crustal evolution is more complex than originally thought. Models currently used to describe the formation of silicic lithologies on the Moon include in situ differentiation of a magma, magma differentiation with silicate liquid immiscibility, and partial melting of the crust. This study focuses on testing a crustal melting model through partial melting experiments on compositions representing lithologies spatially associated with the silicic domes. The experiments were guided by the results of modeling melting temperatures and residual melt compositions of possible protoliths for lunar silicic rocks using the thermodynamic modeling software, rhyolite-MELTS. Rhyolite-MELTS simulations predict liquidus temperatures of 950-1040 °C for lunar granites under anhydrous conditions, which guided the temperature range for the experiments. Monzogabbro, alkali gabbronorite, and KREEP basalt were identified as potential protoliths due to their ages, locations on the Moon (i.e., located near observed silicic domes), chemically evolved compositions, and the results from rhyolite-MELTS modeling. Partial melting experiments, using mixtures of reagent grade oxide powders representing bulk rock compositions of these rock types, were carried out at atmospheric pressure over the temperature range of 900-1100 °C. Because all lunar granite samples and remotely sensed domes have an elevated abundance of Th, some of the mixtures were doped with Th to observe its partitioning behavior. Run products show that at temperatures of 1050 and 1100 °C, melts of the three protoliths are not silicic in nature (i.e., they have <63 wt% SiO2). By 1000 °C, melts of both monzogabbro and alkali gabbronorite approach the composition of granite, but are also characterized by immiscible Si-rich and Fe-rich liquids. Furthermore, Th strongly partitions into the Fe-rich, and not the Si-rich glass in all experimental runs. Our work provides important constraints on the mechanism of silicic melt formation on the Moon. The observed high-Th content of lunar granite is difficult to explain by silicate liquid immiscibility, because through this process, Th is not fractionated into the Si-rich phase. Results of our experiments and modeling suggests that silicic lunar rocks could be produced from monzogabbro and alkali gabbronorite protoliths by partial melting at T < 1000 °C. Additionally, we speculate that at higher pressures (P ≥ 0.005 GPa), the observed immiscibility in the partial melting experiments would be suppressed.