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"Dyes"
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The art and science of natural dyes : principles, experiments, and results
\"This long-awaited guide serves as a tool to explain the general principles of natural dyeing, and to help dyers to become more accomplished at their craft through an increased understanding of the process. Photos of more than 450 samples demonstrate the results of actual dye tests, and detailed information covers every aspect of natural dyeing including theory, fibers, mordants, dyes, printing, organic indigo vats, finishing, and the evaluation of dye fastness. Special techniques of printing and discharging indigo are featured as well. The book is intended for dyers and printers who wish to more completely understand the \"why\" and the \"how,\" while ensuring safe and sustainable practices. Written by a textile engineer and chemist (Boutrup) and a textile artist and practitioner (Ellis), its detailed and tested recipes for every process, including charts and comparisons, make it the ideal resource for dyers with all levels of experience.\" -- Publisher's description
DE LA CIRCULACIÓN A LA PRODUCCIÓN: EL CAPITAL GENOVÉS Y LA INDUSTRIA DEL TINTE EN MURCIA (1380-1470)
by
Fazzini, Mauro
in
Dyes
2023
Frente a este planteamiento, nos serviremos de los novedosos aportes de Jairus Banaji, quien destaca el desarrollo de funciones productivas por parte del capital comercial. Specifically, we will examine the way in which Genoese capital uses its condition of monopoly importer of dyes to try to displace the local master dyers of the city management of dyes. The empirical analysis will lead us away from the assumptions of traditional Marxist historiography that establish a rigid separation between circulation and production. Si bien allí poseen depósitos, la mayor parte es almacenada directamente en la capital del reino, tanto por razones de seguridad como por la mayor actividad comercial que ello permite.15 Tanto en Cartagena como en Murcia, los genoveses disponen de factores al frente de los depósitos.
Journal Article
Eco colour : botanical dyes for beautiful textiles
\"Dying with plants is a kind of botanical alchemy, and in Eco Colour, artistic dyer and colorist India Flint teaches you how to cull and use leaves, roots, and flowers to color your cloth and yarn. From whole-dyed cloth and applied color to prints and layered dye techniques, India describes only ecologically sustainable plant-dye methods using renewable resources and takes the path of doing the least possible harm to the dyer, the end user of the object, and the environment. Recipes include a number of entirely new processes developed by India herself, as well as guidelines for plant collection, directions for distillation of nontoxic mordants, and methodologies for applying plant dyes. Eco Colour inspires both the novice home dyer and textile professional seeking to extend their skills using India's successful methods for achieving ecologically friendly, stunning color.\"--Publisher description.
Near-infrared fluorescence for detection of sentinel lymph nodes in women with cervical and uterine cancers (FILM): a randomised, phase 3, multicentre, non-inferiority trial
2018
Accurate identification of sentinel lymph nodes in patients with cancer improves detection of metastatic disease and decreases surgical morbidity. We sought to establish whether indocyanine green fluorescent dye is non-inferior to isosulfan blue dye in detecting sentinel lymph nodes in women with cervical and uterine cancers.
In this non-inferiority, within-patient comparison study, patients aged 18 years or older with clinical stage I endometrial or cervical cancer undergoing curative surgery were randomly assigned 1:1 to lymphatic mapping with isosulfan blue dye (visualised by white light) followed by indocyanine green (visualised by near-infrared imaging), or indocyanine green followed by isosulfan blue dye. Permuted block randomisation with stratification by study site was done with a computerised random number generator. All participants were masked to their randomisation assignment until after the procedure; however, investigators were not masked to the procedure used. Laparoscopic surgery with the PINPOINT near-infrared fluorescence imaging system (Stryker, Kalamazoo, MI, USA) was used in all cases. The primary outcome was efficacy of intraoperative indocyanine green with near-infrared fluorescence imaging versus that of isosulfan blue dye in the identification of lymph nodes, defined as the number of lymph nodes identified by indocyanine green and isosulfan blue dye, respectively (and confirmed as lymphoid tissue by histology), divided by the number of lymph nodes identified intraoperatively and excised. The study had a 5% non-inferiority margin needed to show non-inferiority of the frequency of lymph node detection with indocyanine green to that with isosulfan blue dye with 80% power at a 5% two-sided significance level. Analyses were done in both per-protocol and modified intention-to-treat populations. The trial was registered with ClinicalTrials.gov, number NCT02209532, and is completed and closed.
Between Dec 21, 2015, and June 19, 2017, 180 patients were enrolled and randomly assigned to the two groups (90 to each group); 176 patients received the intervention and were evaluable (modified intention-to-treat population). 13 patients with major protocol violations were subsequently excluded from the per-protocol population. 517 sentinel nodes were identified in the per-protocol population (n=163), of which 478 (92%) were confirmed to be lymph nodes on pathological processing: 219 (92%) of 238 nodes that were both blue and green, all seven nodes that were blue only, and 252 (95%) of 265 nodes that were green only (p=0·33). Seven sentinel lymph nodes were neither blue nor green but were removed for appearing suspicious or enlarged on visual examination. In total, 471 (97%) of 485 lymph nodes were identified with the green dye and 226 (47%) with the blue dye (difference 50%, 95% CI 39–62; p<0·0001). In the modified intention-to-treat population (n=176), 545 nodes were identified, of which 513 (94%) were confirmed to be lymph nodes on pathological processing: 229 (92%) of 248 nodes that were both blue and green, all nine nodes that were blue only, and 266 (95%) of 279 nodes that were green only (p=0·30). Nine sentinal lymph nodes were neither blue nor green but were removed for appearing suspicious or enlarged on visual examination. 495 (96%) of 513 nodes were identified with the green dye and 238 (46%) with the blue dye (50%, 39–61; p<0·0001).
Indocyanine green dye with near-infrared fluorescence imaging identified more sentinel nodes than isosulfan blue dye in women with cervical and uterine cancers, with no difference in the pathological confirmation of nodal tissue between the two mapping substances.
Novadaq.
Journal Article
The handbook of natural plant dyes : personalize your craft with organic colors from acorns, backberries, coffee, and other everyday ingredients
Through step-by-step instructions and color-saturated photographs, textile designer Sasha Duerr explains the basics of making and using natural plant dye, from gathering materials and making the dyes to simple ideas for how to use them. --from publisher description
A general method to improve fluorophores for live-cell and single-molecule microscopy
2015
A simple and general chemical structure change to a panel of cell-permeable small-molecule fluorophores increases their brightness and photostability, which will enable improved single-molecule studies and super-resolution imaging.
Specific labeling of biomolecules with bright fluorophores is the keystone of fluorescence microscopy. Genetically encoded self-labeling tag proteins can be coupled to synthetic dyes inside living cells, resulting in brighter reporters than fluorescent proteins. Intracellular labeling using these techniques requires cell-permeable fluorescent ligands, however, limiting utility to a small number of classic fluorophores. Here we describe a simple structural modification that improves the brightness and photostability of dyes while preserving spectral properties and cell permeability. Inspired by molecular modeling, we replaced the
N
,
N
-dimethylamino substituents in tetramethylrhodamine with four-membered azetidine rings. This addition of two carbon atoms doubles the quantum efficiency and improves the photon yield of the dye in applications ranging from
in vitro
single-molecule measurements to super-resolution imaging. The novel substitution is generalizable, yielding a palette of chemical dyes with improved quantum efficiencies that spans the UV and visible range.
Journal Article
A zwitterionic near-infrared fluorophore for real-time ureter identification during laparoscopic abdominopelvic surgery
by
Terwisscha van Scheltinga, Anton G.
,
Kuil, Joeri
,
Holman, Fabian A.
in
692/308/2779/109
,
692/698/1864/1861
,
692/700/1421
2019
Iatrogenic injury of the ureters is a feared complication of abdominal surgery. Zwitterionic near-infrared fluorophores are molecules with geometrically-balanced, electrically-neutral surface charge, which leads to renal-exclusive clearance and ultralow non-specific background binding. Such molecules could solve the ureter mapping problem by providing real-time anatomic and functional imaging, even through intact peritoneum. Here we present the first-in-human experience of this chemical class, as well as the efficacy study in patients undergoing laparoscopic abdominopelvic surgery. The zwitterionic near-infrared fluorophore ZW800-1 is safe, has pharmacokinetic properties consistent with an ideal blood pool agent, and rapid elimination into urine after a single low-dose intravenous injection. Visualization of structure and function of the ureters starts within minutes after ZW800-1 injection and lasts several hours. Zwitterionic near-infrared fluorophores add value during laparoscopic abdominopelvic surgeries and could potentially decrease iatrogenic urethral injury. Moreover, ZW800-1 is engineered for one-step covalent conjugatability, creating possibilities for developing novel targeted ligands.
Iatrogenic injury of the ureters is a feared complication of laparoscopic abdominal surgery. Here the authors present the NIR fluorophore ZW800-1 as an intraoperative imaging agent for ureter mapping, showing its safety, pharmacokinetic properties, and efficacy in healthy volunteers and patients undergoing abdominopelvic surgery.
Journal Article
The wild dyer : a maker's guide to natural dyes with projects to create and stitch
Fabrics colored with natural dyes have a beauty and subtlety all of their own. Onion and avocado skins, chamomile and birch bark, and nettles and acorns can produce lovely, ethereal colors and effects. The Wild Dyer demystifies this eco-conscious art, focusing on foraging and growing dying materials; repurposing kitchen trimmings; making and using long-lasting dyes; and creating stitched projects.
Bright photoactivatable fluorophores for single-molecule imaging
2016
Photoactivatable derivatives of the bright and photostable Janelia Fluor dyes enable improved multicolor single-particle tracking and facile localization microscopy in cells.
Small-molecule fluorophores are important tools for advanced imaging experiments. We previously reported a general method to improve small, cell-permeable fluorophores which resulted in the azetidine-containing 'Janelia Fluor' (JF) dyes. Here, we refine and extend the utility of these dyes by synthesizing photoactivatable derivatives that are compatible with live-cell labeling strategies. Once activated, these derived compounds retain the superior brightness and photostability of the JF dyes, enabling improved single-particle tracking and facile localization microscopy experiments.
Journal Article