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Water pollution caused by organic dyes is one of the greatest threats to the ecosystem. The removal of dyes from water has remained a challenge for scientists. Recently, metal sulphides have emerged as a potential candidate for water remediation applications. The efficient charge transportation, greater surface-active sites, and low bandgap of metal sulphides make them an excellent choice of semiconductor photocatalysts for degradation of dyes. This review summarises the potential application of metal sulphides and their heterojunctions for the photocatalytic degradation of organic dyes from wastewater. A detailed study has been presented on the synthesis, basics of photodegradation and heterojunctions and photocatalytic activity. The effect of the use of templates, doping agents, synthesis route, and various other factors affecting the photocatalytic activity of metal sulphides have been summarised in this review. The synthesis techniques, characterisation techniques, mechanism of degradation of organic dyes by Z-scheme heterojunction photocatalyst, reusability and stability of metal sulphides, and the scope of future research are also discussed. This study indicates that Scopus-based core gathered data could be used to give an objective overview of the global dye degradation research from 2008 to 2023 (15 years). All data (articles, authors, keywords, and publications) is compiled in the Scopus database. For the bibliometric study, 1962 papers relevant to dye photodegradation by sulfide-based photocatalysts were found, and this number rises yearly. A bibliometric analysis provides a 15-year evaluation of the state-of-the-art research on the impact of metal sulfide-based photocatalysts on the photodegradation of dyes.

Microplastics are persistent anthropogenic pollutants which have become a global concern owing to their widespread existence and unfamiliar threats to the environment and living organisms. This study demonstrates the degradation of fragmented microplastics particularly low-density polyethylene (LDPE) film in water, through visible light-induced plasmonic photocatalysts comprising of platinum nanoparticles deposited on zinc oxide (ZnO) nanorods (ZnO-Pt). The ZnO-Pt nanocomposite photocatalysts were observed to have better degradation kinetics for a model organic dye (methylene blue) compared to bare ZnO nanorods, attributed to the plasmonic effects leading to better interfacial exciton separation and improved hydroxyl radical activity along with a 78% increase in visible light absorption. These demonstrations of the plasmonically enhanced photocatalyst enabled it to effectively degrade microplastic fragments as confirmed following the changes in carbonyl and vinyl indices in infrared absorption. In addition, visual proof of physical surface damage of the LDPE film establishes the efficacy of using plasmonically enhanced nanocomposite photocatalytic materials to tackle the microplastic menace using just sunlight for a clean and green approach towards mitigation of microplastics in the ecosystem.

Semiconductor-based photocatalytic reactions are a practical class of advanced oxidation processes (AOPs) to address energy scarcity and environmental pollution. By utilizing solar energy as a clean, abundant, and renewable source, this process offers numerous advantages, including high efficiency, eco-friendliness, and low cost. In this review, we present several methods to construct various photocatalyst systems with excellent visible light absorption and efficient charge carrier separation ability through the optimization of materials design and reaction conditions. Then it introduces the fundamentals of photocatalysis in both clean energy generation and environmental remediation. In the other parts, we introduce various approaches to enhance photocatalytic activity by applying different strategies, including semiconductor structure modification (e.g., morphology regulation, co-catalysts decoration, doping, defect engineering, surface sensitization, heterojunction construction) and tuning and optimizing reaction conditions (such as photocatalyst concentration, initial contaminant concentration, pH, reaction temperature, light intensity, charge-carrier scavengers). Then, a comparative study on the photocatalytic performance of the various recently examined photocatalysts applied in both clean energy production and environmental remediation will be discussed. To realize these goals, different photocatalytic reactions including H2 production via water splitting, CO2 reduction to value-added products, dye, and drug photodegradation to lessen toxic chemicals, will be presented. Subsequently, we report dual-functional photocatalysis systems for simultaneous energy production and pollutant photodegradation for efficient reactions. Then, a brief discussion about the industrial and economical applications of photocatalysts is described. The report follows by introducing the application of artificial intelligence and machine learning in the design and selection of an innovative photocatalyst in energy and environmental issues. Finally, a summary and future research directions toward developing photocatalytic systems with significantly improved efficiency and stability will be provided.

Microplastics (MPs) are distributed in a wide range of aquatic and terrestrial ecosystems throughout the planet. They are known to adsorb hazardous substances and can transfer them across the trophic web. To eliminate MPs pollution in an environmentally friendly process, we propose using a photocatalytic process that can easily be implemented in wastewater treatment plants (WWTPs). As photocatalysis involves the formation of reactive species such as holes (h+), electrons (e−), hydroxyl (OH●), and superoxide ion (O2●−) radicals, it is imperative to determine the role of those species in the degradation process to design an effective photocatalytic system. However, for MPs, this information is limited in the literature. Therefore, we present such reactive species’ role in the degradation of high-density polyethylene (HDPE) MPs using C,N-TiO2. Tert-butanol, isopropyl alcohol (IPA), Tiron, and Cu(NO3)2 were confirmed as adequate OH●, h+, O2●− and e− scavengers. These results revealed for the first time that the formation of free OH● through the pathways involving the photogenerated e− plays an essential role in the MPs’ degradation. Furthermore, the degradation behaviors observed when h+ and O2●− were removed from the reaction system suggest that these species can also perform the initiating step of degradation.

In this work, a series of BiOCl/CoTiO3 composites with different composite ratios were successfully synthesized via an in-situ growth method. The characterization results showed that the incorporation of CoTiO3, which possesses a narrow band gap, could significantly enhance the photo responsiveness of BiOCl and the close contact interface between CoTiO3 and BiOCl facilitated the separation of photogenerated carriers. Tetracycline hydrochloride (TC) was selected as a probe molecule to evaluate the photocatalytic properties of the composites. Upon irradiation for 120 min, the composites exhibited a photodegradation rate of TC that reached 70.8%. Through the free radical capture experiment, it was confirmed that both •O2− and h+ play key roles in the photocatalytic degradation of TC by composite materials. Furthermore, the relationship between the interfacial structure and photocatalytic performance was elucidated, providing a theoretical foundation for the design and synthesis of novel optical composites and their application in the field of photocatalysis.

A type of two-dimensional/zero-dimensional/two-dimensional face-to-face contact g-C3N4@Au@Bi4Ti3O12 heterojunction ternary composite photocatalyst has been developed by coupling Bi4Ti3O12 nanosheets with g-C3N4 nanosheets face-to-face and sandwiching Au nanoparticles between them. The as-prepared photocatalysts were systematically investigated using various characterization techniques including x-ray powder diffraction analysis, ultraviolet–visible diffuse reflectance spectroscopy, Fourier-transform infrared spectroscopy, scanning electron microscopy, transmission electron microscopy, and x-ray photoelectron spectroscopy. Degradation experiments were carried out to study the removal of rhodamine B from water under simulated sunlight, revealing that the g-C3N4@Au@Bi4Ti3O12 composite photocatalysts exhibited greatly enhanced photodegradation performance compared with bare Bi4Ti3O12 or g-C3N4 nanosheets, and moreover excellent photocatalytic stability during repeated dye degradation with recycling. The underlying photodegradation mechanism of the g-C3N4@Au@Bi4Ti3O12 composite photocatalysts was systematically investigated and is discussed herein.

With the increasing demand for polymers, white pollution has become a serious concern all around the world. The admirable degradation methods of them are desirable for overcoming this problem. In the past several decades, numerous researches on polymer degradation have been reported. This review commits to different degradation strategies of polymers and four main degradation protocols firstly, including photodegradation, oxidative degradation, catalytic degradation, and biodegradation, are demonstrated in detail. Secondly, some specific samples are discussed for each kind of degradation. Finally, the outlook and future of polymer degradation are proposed. In particular, the comprehensive comparison of different degradation methods is covered to provide the best choice for dealing with different polymers wastes. These will be beneficial to the development of processing plastic and conversion of polymer wastes.

Industrial effluents containing dyes are the dominant pollutants, making the drinking water unfit. Among the dyes, methylene orange (MO) dye is mutagenic, carcinogenic and toxic to aquatic organisms. Therefore, its removal from water bodies through effective and economical approach is gaining increased attention in the last decades. Photocatalytic degradation has the ability to convert economically complex dye molecules into non-toxic and smaller species via redox reactions, by using photocatalysts. g-C[sub.3] N[sub.4] is a metal-free n-type semiconductor, typical nonmetallic and non-toxici polymeric photocatalyst. It widely used in photocatalytic materials, due to its easy and simple synthesis, fascinating electronic band structure, high stability and abundant availability. As a photocatalyst, its major drawbacks are its limited efficiency in separating photo-excited electron–hole pairs, high separated charge recombination, low specific surface area, and low absorption coefficient. In this review, we report the recent modification strategies adopted for g-C[sub.3] N[sub.4] for the efficient photodegradation of MO dye. The different modification approaches, such as nanocomposites and heterojunctions, as well as doping and defect introductions, are briefly discussed. The mechanism of the photodegradation of MO dye by g-C[sub.3] N[sub.4] and future perspectives are discussed. This review paper will predict strategies for the fabrication of an efficient g-C[sub.3] N[sub.4] -based photocatalyst for the photodegradation of MO dye.

Two titania photocatalysts have been prepared using the sol–gel method using TiCl4 as a precursor, and two different alcohols, namely, ethanol or propanol (Et or Pr). The main aim of this work was to study the effect of the nature of the alcohol on the chemical, structural and photocatalytic properties for paracetamol photodegradation of the final solids. The TiCl4/alcohol molar ratio to obtain the corresponding alkoxides (TiEt and TiPr) was 1/10. These alkoxides were calcined at 400 °C to prepare the oxide catalysts (named as TiEt400 and TiPr400). Powder X-ray diffraction (PXRD) of the original samples showed the presence of anatase diffraction peaks in sample TiPr, while TiEt is a completely amorphous material. Contrary to commercial TiO2-P25, the PXRD diagrams of the calcined samples showed anatase as the exclusive crystalline phase in both solids. The specific surface area (SBET) of sample TiPr400 was larger than that of sample TiEt400, and both larger than that of TiO2-P25. The three solids have been tested in the photodegradation of paracetamol in aqueous solution. It has been established that the alcohol used influences the properties and catalytic activity of the final oxides. The synthesized solids exhibit a higher activity than commercial TiO2-P25, because of their structural characteristics and larger SBET.

Plastic waste becomes an immediate threat to our society with ever-increasing negative impacts on our environment and health by entering our food chain. Sunlight is known to be the natural energy source that degrades plastic waste at a very slow rate. Mimicking the role of sunlight, the photocatalytic degradation process could significantly accelerate the degradation rate thanks to the photocatalyst that drastically facilitates the photochemical reactions involved in the degradation process. This mini review begins with an introduction to the chemical compositions of the common plastic waste. The mechanisms of photodegradation of polymers in general were then revisited. Afterwards, a few photocatalysts were introduced with an emphasis on titanium dioxide (TiO2), which is the most frequently used photocatalyst. The roles of TiO2 photocatalyst in the photodegradation process were then elaborated, followed by the recent advances of photocatalytic degradation of various plastic waste. Lastly, our perspectives on the future research directions of photocatalytic plastic degradation are present. Herein, the importance of catalytic photodegradation is emphasized to inspire research on developing new photocatalysts and new processes for decomposition of plastic waste, and then to increase its recycling rate particularly in the current pandemic with the ever-increasing generation of plastic waste.