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Synthesis and characterization of BiOCl/CoTiO3 composites for enhanced photocatalytic degradation of organic pollutants
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Synthesis and characterization of BiOCl/CoTiO3 composites for enhanced photocatalytic degradation of organic pollutants
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Journal Article
Synthesis and characterization of BiOCl/CoTiO3 composites for enhanced photocatalytic degradation of organic pollutants
2025
Overview
In this work, a series of BiOCl/CoTiO3 composites with different composite ratios were successfully synthesized via an in-situ growth method. The characterization results showed that the incorporation of CoTiO3, which possesses a narrow band gap, could significantly enhance the photo responsiveness of BiOCl and the close contact interface between CoTiO3 and BiOCl facilitated the separation of photogenerated carriers. Tetracycline hydrochloride (TC) was selected as a probe molecule to evaluate the photocatalytic properties of the composites. Upon irradiation for 120 min, the composites exhibited a photodegradation rate of TC that reached 70.8%. Through the free radical capture experiment, it was confirmed that both •O2− and h+ play key roles in the photocatalytic degradation of TC by composite materials. Furthermore, the relationship between the interfacial structure and photocatalytic performance was elucidated, providing a theoretical foundation for the design and synthesis of novel optical composites and their application in the field of photocatalysis.
Publisher
IOP Publishing
Subject
