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Preparation of bioplastics and chitosan with sorbitol plasticizer by varying starch and chitosan in the ratio of 30%: 70%, 40% : 60%, 50% : 50%, 60% : 40%, 70% : 30% and added sorbitol plasticizer with variations of 60% and 80%. Characterization was carried out on the composition of starch and chitosan with the addition of sorbitol plasticizer starting with physical and mechanical testing and obtained 2 bioplastics showing the highest elongation and tensile strength data obtained in sample BSB4 in the ratio of starch and chitosan 60%: 40% by adding 60% sorbitol plasticizer showed an elongation value of 21.68898% and a tensile strength of 1.7352 MPa and sample BSC1 with a ratio of starch and chitosan 30%: 70% with the addition of 80% sorbitol plasticizer resulted in an elongation value of 23.6926% and tensile strength of 2.3997 MPa. The biodegradability test on bioplastics showed a mass reduction for 4 weeks or 28 days with the highest percentage of each variation of starch and chitosan by adding sorbitol plasticizer reaching 19.38%. SEM results show that there is still mixing between starch and a less homogeneous solution as evidenced by several points on bioplastics that are still white, and the same groups are obtained between the constituents of bioplastics, namely O-H, C-H, and N-H.

High ionic conductivity polymer electrolytes are now of considerable interest due to their prospective uses in several electrochemical devices such as batteries, fuel cells, solar cells, and supercapacitors. Several approaches have been used to improve their ionic conductivity, including adding plasticizers, polymer blends, and nanocomposites. This work examined how the plasticizer D-sorbitol affected the ion transport in solid polymer electrolyte membranes made of polyvinyl alcohol (PVA) complexed with 30 wt% of LiI. The membranes were created with a D-sorbitol concentration of up to 55 wt% using the solution casting technique. The XRD structural study showed that the membranes’ amorphousness increased when the sorbitol content increased. The complexation between PVA and the additives was studied using UV–vis and FTIR analysis. Electric methods such as ac-impedance spectroscopy and linear sweep voltammetry were used to investigate the conductivity, decomposition voltage, ion transference number, dielectric constant ( ε′ ), dielectric loss factor ( ε″ ), and electric modulus (M) of the investigated membranes. The results indicated the interactions between LiI, PVA, and D-sorbitol plasticizer. The increase in D-sorbitol concentration affected the electrical properties and electrochemical stability window. The highest ionic transfer number value of 0.997 was obtained with 55 wt% of D-sorbitol at 30 °C. The UV–vis optical study revealed a direct allowed transition band with an optical energy gap decreased from 3.92 eV (for PL) to 3.82 eV (for PLS5).

There is an increased interest in the use of cellulose nanocrystal (CNC) films and coatings for a range of functional applications in the fields of material science, biomedical engineering, and pharmaceutical sciences. Most of these applications have been demonstrated on films and coatings produced using laboratory-scale batch processes, such as solvent casting, dip coating, or spin coating. For successful coating application of CNC suspensions using a high throughput process, several challenges need to be addressed: relatively high viscosity at low solids content, coating brittleness, and potentially poor adhesion to the substrate. This work aims to address these problems. The impact of plasticizer on suspension rheology, coating adhesion, and barrier properties was quantified, and the effect of different pre-coatings on the wettability and adhesion of CNC coatings to paperboard substrates was explored. CNC suspensions were coated onto pre-coated paperboard in a roll-to-roll process using a custom-built slot die. The addition of sorbitol reduced the brittleness of the CNC coatings, and a thin cationic starch pre-coating improved their adhesion to the paperboard. The final coat weight, dry coating thickness, and coating line speed were varied between 1–11 g/m 2 , 900 nm–7 µm, and 2.5–10 m/min, respectively. The barrier properties, adhesive strength, coating coverage, and smoothness of the CNC coatings were characterized. SEM images show full coating coverage at coat weights as low as 1.5 g/m 2 . With sorbitol as plasticizer and at coat weights above 3.5 g/m 2 , heptane vapor and water vapor transmission rates were reduced by as much as 99% and 75% respectively. Compared to other film casting techniques, the process employed in this work deposits a relatively thick coating in significantly less time, and may therefore pave the way toward various functional applications based on CNCs. Graphical abstract

The rapidly growing concern over the hazardous impact of phthalates on the environment and public health has led to a critical need for alternative and environmentally friendly plastics. Plasticizers developed from natural materials represent one possible solution. This paper explores four types of renewable feedstocks (sorbitol/polyols, glycerin, cardanol from cashew nutshell liquid, and limonene from citrus peels) as sources for developing alternative plasticizer systems. Key areas explored include the type of feedstock utilized, the methods used for extracting or processing the feedstocks, the nature of the chemical modification processes (e.g., esterification, epoxidation, etherification, or reactive grafting) applied to generate the respective plasticizers, and the resultant physical and mechanical properties. The performance of each plasticizer system in polymers such as PVC, PLA, and polysaccharide-based bioplastics is evaluated, alongside the compatibility with biological tissues, toxicological properties, biodegradability, and chemical migration into food simulants. The feasibility of each family of plasticizers is also assessed from an economic perspective, including availability of the feedstocks, economies of scale associated with large-volume production, and competitive pricing relative to established petroleum-derived plasticizers. Overall, sorbitol/polyol and glycerin derivative families have reached a level of maturity that provides a good balance of processability, food-contact safety, and biodegradability. Cardanol-based systems provide an attractive option where aromatic functional groups and combined plasticization–stabilization effects are needed. Limonene-derived plasticizer systems appear promising for use in PLA, but their broader utility may be limited by volatility, strong odors, and susceptibility to oxidation. Common issues identified across all four families include chemical migration into food products, regulatory approval, and the need for detailed life-cycle assessments.

The research included corn starch (CS) films using sorbitol (S), glycerol (G), and their combination (SG) as plasticizers at 30, 45, and 60 wt %, with a traditional solution casting technique. The introduction of plasticizer to CS film-forming solutions led to solving the fragility and brittleness of CS films. The increased concentration of plasticizers contributed to an improvement in film thickness, weight, and humidity. Conversely, plasticized films reduced their density and water absorption, with increasing plasticizer concentrations. The increase in the amount of the plasticizer from 30 to 60% showed a lower impact on the moisture content and water absorption of S-plasticized films. The S30-plasticized films also showed outstanding mechanical properties with 13.62 MPa and 495.97 MPa, for tensile stress and tensile modulus, respectively. Glycerol and-sorbitol/glycerol plasticizer (G and SG) films showed higher moisture content and water absorption relative to S-plasticized films. This study has shown that the amount and type of plasticizers significantly affect the appearances, physical, morphological, and mechanical properties of the corn starch biopolymer plastic.

Packaging materials based on biodegradable polymers are a viable alternative to replace conventional plastic packaging from fossil origin. The type of plasticizer used in these materials affects their functionality and performance. The effect of different plasticizers such as glycerol (GLY), sorbitol (SOR), and poly(ethylene glycol) (PEG) in concentrations of 5%, 10%, and 15% (w/w) on the structural features and functional properties of starch/PVOH/chitosan films was evaluated. The incorporation of a plasticizer increased the thickness of the biodegradable composite films. Furthermore, the material plasticized with 30% (w/w) sorbitol had the highest elongation at break, lowest water vapor permeability, and better thermal resistance. The results obtained in this study suggest that maize starch/PVOH/chitosan biodegradable composite films are a promising packaging material, and that sorbitol is the most suitable plasticizer for this formulation.

In this study, sugar palm starch (SPS) films were developed using glycerol (G), sorbitol (S) or their combination (GS) as plasticizers at the ratio of 15, 30 and 45 (wt)% using casting technique. The addition of plasticizers to SPS film-forming solutions helped to overcome the brittle and fragile nature of unplasticized SPS films. Increased plasticizer concentration resulted to an increase in film thickness, moisture content and solubility. On the contrary, density and water absorption of plasticized films decreased with increasing plasticizer concentration. Raising the plasticizer content from 15 to 45 % showed less effect on the moisture content and water absorption of S-plasticized films. Films containing glycerol and glycerol-sorbitol plasticizer (G, and GS) demonstrated higher moisture content, solubility and water absorption capacity compared to S-plasticized films. The results obtained in this study showed that plasticizer type and concentration significantly improves film properties and enhances their suitability for food packaging applications.

This research investigated effect of morphological, mechanical and physical properties on biodegradable plastic made from porang starch with chitosan using, sorbitol plasticizer at concentration 60 and 80 wt%, with the addition of glycerol plasticizer at various concentrations (0%, 25%, 50%, 75%, 100%), made using the melt intercalation method with a gelatinization temperature of 80°C and drying temperature of 70°C. Plasticizer was added to improve flexibility and water absorption of biodegradable plastic properties. Increasing the concentration of the plasticizer resulted in an increase in the elongation of the biodegradable plastic. The biodegradable plastic showed greater tensile strength before addition glycerol plasticizer 1,9191 MPa at 60% concentration and 1,3018 MPa at 80%. Conversely, the addition of 100% glycerol concentration showed an increase in elongation of 77.7764% at 60% sorbitol and 171.0562 at 80% sorbitol. SEM characterization results still showed agglomeration and FTIR not showed any new functional groups. The results of this research indicate that the percentage and kind of plasticizer influence the physical, mechanical, morphological and degradation properties to porang starch biodegradable plastics.

The aim of this work was to use glycerol (Gly) and sorbitol (Sor) as plasticizers with oxidized starch potato (OS) to produce biodegradable and environmentally friendly films, and to demonstrate the resulting physicochemical and functional viability without subtracting the organoleptic characteristics of the food. Analyses by water vapor permeability (WVP), attenuated total reflection Fourier transform infrared spectra (ATR-FTIR), scanning electron microscopy (SEM), tensile strength (TS), and transparency (UV) showed that the best film result was with 1.5 g of Gly and 2.0 g of Sor, conferred shine, elasticity 19.42 ± 6.20%, and mechanical support. The starch oxidized to 2.5%, contributing a greater transparency of 0.33 ± 0.12 and solubility of 78.90 ± 0.94%, as well as less permeability to water vapor 6.22 ± 0.38 gmm−2 d−1 kPa−1. The films obtained provide an alternative for use in food due to their organic compounds, excellent visual presentation, and barrier characteristics that maintain their integrity and, therefore, their functionality.

The paper presents the production of thermoplastic starch (TPS) mixtures using potato starch and two types of plasticizers: glycerol and sorbitol. The effects of plasticizers, citric acid, organically modified montmorillonite clay nanofiller (OMMT) and an additive based on ultrahigh molecular weight siloxane polymer on the structure and physical–mechanical and thermal properties of TPS samples were analysed. Starch mixtures plasticized with glycerol were obtained, where the starch/glycerol mass ratio was 70:30, as well as starch mixtures plasticized with glycerol and sorbitol, with a starch/glycerol/sorbitol mass ratio of 60:20:20. The starch gelatinization process to obtain TPS was carried out in a Brabender Plasti-Corder internal mixer at 120 °C, with a mixing speed of 30–80 rpm, for 10 min. The obtained results indicate that by adding 2% (weight percentage) of citric acid to the TPS mixtures, there is an improvement in the physical–mechanical properties, as well as structural changes that can indicate both cross-linking reactions by esterification in stages and depolymerisation reactions. The sample of TPS plasticized with glycerol, which contains OMMT, shows an increase in tensile strength by 34.4%, compared to the control sample.