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The analysis of micro- and nanoplastics (MNPs) in the environment is a critical objective due to their ubiquitous presence in natural habitats, as well as their occurrence in various food, beverage, and organism matrices. MNPs pose significant concerns due to their direct toxicological effects and their potential to serve as carriers for hazardous organic/inorganic contaminants and pathogens, thereby posing risks to both human health and ecosystem integrity. Understanding the fate of MNPs within wastewater treatment plants (WWTPs) holds paramount importance, as these facilities can be significant sources of MNP emissions. Additionally, during wastewater purification processes, MNPs can accumulate contaminants and pathogens, potentially transferring them into receiving water bodies. Hence, establishing a robust analytical framework encompassing sampling, extraction, and instrumental analysis is indispensable for monitoring MNP pollution and assessing associated risks. This comprehensive review critically evaluates the strengths and limitations of commonly employed methods for studying MNPs in wastewater, sludge, and analogous environmental samples. Furthermore, this paper proposes potential solutions to address identified methodological shortcomings. Lastly, a dedicated section investigates the association of plastic particles with chemicals and pathogens, alongside the analytical techniques employed to study such interactions. The insights generated from this work can be valuable reference material for both the scientific research community and environmental monitoring and management authorities. Graphical Abstract

Post‐consumer plastic film waste often carries organic and inorganic contaminants that challenge recycling processes and affect the quality of recycled products. An effective contaminant removal procedure through washing such single‐used plastic films (SUPFs) can address environmental and waste management concerns. This study compares the efficiency of different washing techniques in reducing SUPF contamination. To evaluate the efficacy of each washing technique, film samples collected from material recovery facilities are individually exposed to friction, ultrasonic‐assisted, and a combination of both washes. Thermal analysis indicates that the polymers' melting temperature, crystallization temperature, and crystallinity remain unaffected by the washing methods, demonstrating method aptness. Confocal laser scanning microscope images show that washing results in a cleaner sample surface. 91% ash reduction during the combined wash treatment indicates a high method efficiency compared to the individual friction and ultrasonic wash procedures. This is further validated by reducing characteristic contaminant IR bands (3600–3000, 1750–1600, and 1100–1000 cm−1). Elements of concern such as Cd, Cr, Hg, and Pb in SUPFs after each washing technique applied conform with regulations (<100 ppm) for packaging products. This research shows the novel ultrasonic washing reduces more contamination than friction with shorter wash times and no surfactants. Post‐consumer single‐used plastic film (SUPF) waste often carries organic/inorganic contaminants, challenging recycling processes and affecting the quality of recycled products. This study compares the efficiency of friction, ultrasonic‐assisted, and a combination of both washing techniques on film samples collected from material recovery facilities. The novel ultrasonic washing improves decontamination compared to the standard friction washing without any added substance.

In this bioremediation study, the fungus Penicillium sp. isolated from kefir grains was evaluated for its resistance to copper in the culture medium. Penicillium sp. was cultivated in liquid medium prepared using 2% malt-agar at pH 7.0. Biomass of the fungus was significantly reduced, but only when 800 mg·L−1 of Cu(NO3)2 copper nitrate was used. The effect on radial growth of the fungus in experiments combining different pH values and the inorganic contaminant showed an inhibition of 73% at pH 4.0, 75% at pH 7.0 and 77% at pH 9.0 in liquid medium. Thus, even though the growth of Penicillium sp. could be inhibited with relatively high doses of copper nitrate, images obtained with scanning electron microscopy showed the preservation of fungal cell integrity. Therefore, it can be concluded that Penicillium sp. isolated from kefir grains can survive while performing bioremediation to minimize the negative effects of copper on the environment through biosorption.

Background and aims Re-vegetation of mining-impacted landscapes reduces transport of toxic elements while improving soil fertility. This study evaluated whether the planting of a native perennial grass with a consortium of diazotrophic microbial endophytes and municipal waste compost—alone and in combination—enhanced plant growth while stabilizing metal(loids) in dolomite-amended tailings from a historically mined polymetallic mineral deposit. Methods We grew Bouteloua curtipendula seedlings in tailings with hazardous concentrations of As, Cd, Pb, Mn, and Zn. We evaluated how plant growth, organic matter accumulation, and major, minor, and trace element mobilization and phytostabilization responded to microbial endophyte and/or compost amendments after the 45-day growth experiment. Results Although most of the added endophytes were not uniquely identified, the best plant growth and fertility outcomes were achieved with a combination of amendments: dolomite to reduce acidity, compost to increase nitrogen, and a mixed consortium endophyte seed coating to synergistically increase organic carbon and grass biomass yields. Compost reduced shoot and root concentrations—but not yields—of contaminant metals. Endophytes increased foliar Cd, Co, Mn, and Pb yields but mobilized Pb and Zn from the tailings. Root stabilization of Cd, Co, Mn did not require amendments. Conclusion The most effective means of revegetating these acidic, polymetallic tailings with the native B. curtipendula is with a simultaneous dolomite, compost, and endophyte seed treatment. Due to potential phosphate solubilization and siderophore production by this consortium of endophytes, strategies to capture solubilized metal(loids) may be needed for sulfidic tailings with metal(loids) associated with mobile mineral phases.

This paper presents an analysis of contaminants generated from large-scale, laboratory-based, underground coal gasification (UCG) experiments using a high-rank coal from the South Wales Coalfield. The experiments were performed at atmospheric and elevated pressures (30 bar) by varying the oxidants’ composition. The experiments were designed to predict the amount of produced water and contaminants generated at each stage of the operating conditions. The mass balance of water supplied and produced in the experiments was accounted for. Chemical analyses of produced water, char and ash contents were performed to quantify the inorganic and organic chemical parameters. Most of the contaminant concentrations in the produced water from the 30-bar pressure experiment were lower than the concentrations generated from the atmospheric pressure experiment. The measured concentrations of the inorganic chemical species and the inorganic parameters of the coal seam water from the South Wales Coalfield were used in theoretical calculations to predict the dominant equilibrium species concentrations in a hypothetical scenario of effluent contaminated groundwater. The biodegradation of organic contaminants such as phenol, benzene and sorbed fractions of inorganic contaminants from the produced water on iron oxide in the ash residue was predicted using existing biotransformation kinetics and surface complexation models, respectively. The biodegradation of phenol and benzene would be a slow process even at optimum conditions and the iron oxide left in the cavity can act as a sorbent for a few inorganic species. The evidence from the present study suggests future work towards (i) developing an appropriate water treatment process during gas cleaning, (ii) operational procedure (pressure and proportions of oxidant) and (iii) developing UCG-specific experimental prediction of contaminant transportation and transformation kinetics.

The long-term sustainability of the global water supply, with a paramount emphasis on cleanliness and safety, stands as a formidable challenge in our modern era. In response to this pressing issue, adsorption techniques have emerged as pivotal and widely recognized solutions for the removal of hazardous pollutants, with a particular emphasis on lead adsorption from wastewater. This comprehensive review explores the relentless advancements made in the adsorption domain, highlighting innovations using separation and purification techniques that surpass traditional metal oxide-based adsorbents. Of particular note is the growing exploration of alternative materials, such as starch, chitosan, nanoscale structures like zeolites and metal-organic frameworks, magnetic materials, and carbon-based substances for the development of inorganic adsorbents. These materials, with their remarkable capacity for nanoscale structural adjustment, possess extraordinary capabilities for effective contaminant removal, facilitating swift water purification. The literature survey for this review was conducted using the Google Scholar engine, with “adsorbents for lead remediation” as the starting keywords, resulting in approximately 6000 papers. The search was refined to focus on the last three years and specifically targeted review papers which are most relevant to lead remediation. More than 100 papers were analysed to investigate various techniques, surface modifications, and adsorbent materials for managing inorganic pollutants in water. This review also illuminates research limitations, with a specific focus on starch-based adsorbents in lead remediation. As we progress towards practical commercial applications, this review identifies challenges associated with the development of inorganic adsorbents and provides invaluable insights into future prospects. Surface modification emerges as a promising path, with the potential to substantially enhance adsorption capacity, potentially doubling or even quadrupling it. Moreover, the adsorbents demonstrate impressive regenerative capabilities, maintaining up to 90% regeneration efficiency after multiple cycles. In conclusion, starch-based adsorbents show considerable potential as effective agents for lead purification from aquatic environments. Nevertheless, the need for further research persists, emphasizing the optimization of the adsorption process and exploring the long-term stability of starch-based adsorbents in real-world scenarios.

The European sturgeon, Acipenser sturio, is a highly endangered species that almost disappeared in the last decades. Thanks to yearly restocking of the population, this species is still found in the Gironde estuary (France), where juveniles grow during several years before leaving to the ocean. The aims of this study were to evaluate the pressure exerted on these fish by known organic and inorganic contaminants during their stay at the Gironde estuary, and to get information on the fish's health in this context. Monthly captures over the year 2014 provided 87 fish from the cohorts 2012 and 2013 mainly, and from cohorts 2008, 2009, and 2011, all fish born in hatchery. We report the very first analyses of contaminant levels and of biological markers measured in the blood of these fish.

Heavy metals are one of the most hazardous inorganic contaminants of both water and soil environment composition. Normally, heavy metals are non-biodegradable in nature because of their long persistence in the environment. Trace amounts of heavy metal contamination may pose severe health problems in human beings after prolonged consumption. Many instrumental techniques such as atomic absorption spectrophotometry, inductively coupled plasma-mass spectrometry, X-ray fluorescence, neutron activation analysis, etc. have been developed to determine their concentration in water as well as in the soil up to ppm, ppb, or ppt levels. Recent advances in these techniques along with their respective advantages and limitations are being discussed in the present paper. Moreover, some possible remedial phytoremediation approaches (phytostimulation, phytoextraction, phyotovolatilization, rhizofiltration, phytostabilization) have been presented for the removal of the heavy metal contamination from the water and soil environments.

Although the EU is a major producer of honey, commercial production is often insufficient to meet market demand and, as a result, honey is often imported into the EU from extra-EU countries that lack regulatory standards for food safety and quality. Since honey is a matrix highly susceptible to contamination, monitoring the quality and safety of extra-EU honey is of significant importance to show potential safety gaps. Hence, aim of the study was to monitor the mineral profile of monofloral and multifloral honeys from different regions of North (provinces of Tiaret and Laghouat) and South Algeria (province of Tindouf). In almost all the samples, Mg, Fe, Zn, Cd and Pb were found at levels exceeding the limits set for honey by the Codex Alimentarius and European Regulation 915/2023. In addition, a PCA analysis pointed out that the analysis of the element profile was useful to discriminate Algerian honeys more on the basis of geographical than botanical origin. The dietary exposure assessment indicates that the investigated honeys can be safely consumed in quantities comparable to those considered in Europe (1.8 g/day) and North Africa (0.3 g/day). Hopefully, data from this study may solicit the Algerian government to set regulatory limits on inorganic elements in honey and align with other international standards, to create a harmonized network able to improve the safety of this food.

Rapid increases in human populations and development has led to a significant exploitation of natural resources around the world. On the other hand, humans have come to terms with the consequences of their past mistakes and started to address current and future resource utilization challenges. Today’s primary challenge is figuring out and implementing eco-friendly, inexpensive, and innovative solutions for conservation issues such as environmental pollution, carbon neutrality, and manufacturing effluent/wastewater treatment, along with xenobiotic contamination of the natural ecosystem. One of the most promising approaches to reduce the environmental contamination load is the utilization of algae for bioremediation. Owing to their significant biosorption capacity to deactivate hazardous chemicals, macro-/microalgae are among the primary microorganisms that can be utilized for phytoremediation as a safe method for curtailing environmental pollution. In recent years, the use of algae to overcome environmental problems has advanced technologically, such as through synthetic biology and high-throughput phenomics, which is increasing the likelihood of attaining sustainability. As the research progresses, there is a promise for a greener future and the preservation of healthy ecosystems by using algae. They might act as a valuable tool in creating new products.