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Research on properties of DO3- and B2-type ordered alloys and disordered alloys in Nb-Mo alloy system in BCC structure
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Research on properties of DO3- and B2-type ordered alloys and disordered alloys in Nb-Mo alloy system in BCC structure
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Journal Article
Research on properties of DO3- and B2-type ordered alloys and disordered alloys in Nb-Mo alloy system in BCC structure
2011
Overview
Based on the idea of systematic science of alloys, we derived the interaction equations of binary alloys in BCC structure in this paper. According to the basic information of characteristic atoms sequences and characteristic crystals sequences of Nb-Mo alloy system and the concentrations of characteristic atoms of Nb-Mo alloy system, the properties of DO3-Nb3Mo type ordered alloys, B2-NbMo type ordered alloys and DO3-NbMo3 type ordered alloys and disordered alloys were calculated. The results show that the properties of ordered alloys exhibit stronger variations than those of disordered Nb(1−x)Mox alloys when approaching the stoichiometric ratio, whereas the opposite trend occurs when deviating from the stoichiometric ratio. The main reason is that the ordering degree is maximal at the stoichiometric ratio while it decreases linearly when deviating from stoichiometric ratio. On the contrary, the number of bonding electrons among atoms increases with the simultaneous decreasing of the nearly free electrons, which shortens the bond lengths and thus strengthens the crystal bonding.
Publisher
Springer Nature B.V
Subject
