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Compressibility of hingganite-(Y): high-pressure single crystal X-ray diffraction study
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Compressibility of hingganite-(Y): high-pressure single crystal X-ray diffraction study
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Journal Article
Compressibility of hingganite-(Y): high-pressure single crystal X-ray diffraction study
2020
Overview
Behaviour of hingganite-(Y), Y
2
□Be
2
Si
2
O
8
(OH)
2
, on compression to 47 GPa has been studied by synchrotron-based in situ high-pressure single-crystal X-ray diffraction at room temperature in a diamond anvil cell. In the studied pressure range no obvious phase transitions have been observed. The compression of hingganite-(Y) crystal structure is anisotropic, with
b
axis showing the maximal compressibility. A fit of the experimental pressure–volume data by the Birch-Murnaghan third-order equation of state yielded the bulk modulus of 131(2) GPa and its pressure first derivative of 3.5(2). The difference between high-pressure behaviour of hingganite-(Y) and structurally related datolite is governed by the different chemical nature of interlayer cations.
Publisher
Springer Berlin Heidelberg,Springer Nature B.V
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