Asset Details
Do you wish to reserve the book?
Enhanced Catalytic Performance on UiO-67(Zr) Prepared with the Aid of Vapor by Acid Treatment for Oxidative Desulfurization of Fuel Oil
Hey, we have placed the reservation for you!
By the way, why not check out events that you can attend while you pick your title.
Oops! Something went wrong.
Looks like we were not able to place the reservation. Kindly try again later.
Are you sure you want to remove the book from the shelf?
Enhanced Catalytic Performance on UiO-67(Zr) Prepared with the Aid of Vapor by Acid Treatment for Oxidative Desulfurization of Fuel Oil
Do you wish to request the book?
Enhanced Catalytic Performance on UiO-67(Zr) Prepared with the Aid of Vapor by Acid Treatment for Oxidative Desulfurization of Fuel Oil
Please be aware that the book you have requested cannot be checked out. If you would like to checkout this book, you can reserve another copy
We have requested the book for you!
Your request is successful and it will be processed during the Library working hours. Please check the status of your request in My Requests.
Oops! Something went wrong.
Looks like we were not able to place your request. Kindly try again later.
Journal Article
Enhanced Catalytic Performance on UiO-67(Zr) Prepared with the Aid of Vapor by Acid Treatment for Oxidative Desulfurization of Fuel Oil
2026
Overview
UiO-67(Zr), as a member of Zr-based metal–organic frameworks (MOFs), has attracted much attention owing to its merits, involving large surface area, high pore volume, and good structural stability. However, it is generally inactive in many catalytic reactions due to a lack of active sites. In this work, we report a new strategy, combining vapor-assisted synthesis with acid treatment to create abundant active sites in UiO-67(Zr), resulting from defects. The effects of some synthetic parameters were systematically investigated. As a result, an optimized material named UiO-67(Zr)-V-0.5FA-H, obtained by acid-treating UiO-67(Zr) and prepared with the addition of 0.5 mL formic acid via a vapor-assisted method, exhibited outstanding catalytic performance in the oxidation of dibenzothiophene (DBT), which can completely oxidize DBT in 9 min at 30 °C using H2O2 as the oxidant. The calculated turnover frequency reached 150.4 h−1, surpassing those of most reported Zr-MOFs catalysts. In addition, it is demonstrated that UiO-67(Zr)-V-0.5FA-H is a heterogeneous catalyst and can be reused without obvious activity loss.
