Journal Article

Characterization and Rationalization of Microstructural Evolution in GRCop-84 Processed by Laser-Powder Bed Fusion (L-PBF)

Lass, Eric A, Jones, Zachary C, Minneci, Robert P, Rawn, Claudia J, Gradl, Paul R, Bunn, Jeffrey R, Babu, Sudarsanam S, Ellis, David L, Haines, Michael P, Choo, Hahn

2024

Overview

Prismatic geometries of GRCop-84 [Cu-8Cr-4Nb (at. pct)] were built with laser-powder bed fusion (L-PBF) process. The samples were sectioned parallel or perpendicular to the build direction and characterized in the as-built and after post-processing with a hot-isostatically pressing (HIP) treatment. The microstructure and phase evolutions were evaluated with optical microscopy, scanning electron microscopy (SEM), electron backscattered diffraction (EBSD), and high-temperature X-ray diffraction (HTXRD) up to 1223 K. The samples in the as-built conditions exhibited predominantly columnar epitaxial and misoriented Cu-FCC grains. The microstructure evolutions are discussed based on locations within the overall build geometry, the dynamics of small melt pool shape and sectioning effects. The above grain structure did not change significantly during post-process HIP treatment. The stability of this FCC grain structure is attributed to the formation of primary stable Cr2Nb (Laves phase) during L-PBF, even before the emergence of FCC grains from liquid. The stability of Cr2Nb in both as-built and HIPed samples were evaluated using high-temperature X-ray diffraction measurements and compared with that of gas-atomized powder. The significance of these results is discussed with reference to aerospace applications.

• Publisher: Springer Nature B.V
• Subject: Atomizing / Beds (process engineering) / Electron backscatter diffraction / Grain structure / High temperature / Laves phase / Melt pools / Melting / Microscopy / Microstructure / Optical microscopy / Powder beds / Shape effects / Stability analysis / X-ray diffraction