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Observation of tunable band gap and anisotropic Dirac semimetal state in black phosphorus
by
Choi, Hyoung Joon
, Baik, Seung Su
, Sohn, Yeongsup
, Kim, Jimin
, Park, Byeong-Gyu
, Kim, Keun Su
, Park, Soohyung
, Ryu, Sae Hee
, Yi, Yeonjin
, Denlinger, Jonathan
in
Anisotropy
/ Band structure of solids
/ Dispersion
/ Electronic structure
/ Electronics
/ Metalloids
/ Phosphorus
/ Semiconductors
2015
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Observation of tunable band gap and anisotropic Dirac semimetal state in black phosphorus
by
Choi, Hyoung Joon
, Baik, Seung Su
, Sohn, Yeongsup
, Kim, Jimin
, Park, Byeong-Gyu
, Kim, Keun Su
, Park, Soohyung
, Ryu, Sae Hee
, Yi, Yeonjin
, Denlinger, Jonathan
in
Anisotropy
/ Band structure of solids
/ Dispersion
/ Electronic structure
/ Electronics
/ Metalloids
/ Phosphorus
/ Semiconductors
2015
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Observation of tunable band gap and anisotropic Dirac semimetal state in black phosphorus
by
Choi, Hyoung Joon
, Baik, Seung Su
, Sohn, Yeongsup
, Kim, Jimin
, Park, Byeong-Gyu
, Kim, Keun Su
, Park, Soohyung
, Ryu, Sae Hee
, Yi, Yeonjin
, Denlinger, Jonathan
in
Anisotropy
/ Band structure of solids
/ Dispersion
/ Electronic structure
/ Electronics
/ Metalloids
/ Phosphorus
/ Semiconductors
2015
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Observation of tunable band gap and anisotropic Dirac semimetal state in black phosphorus
Journal Article
Observation of tunable band gap and anisotropic Dirac semimetal state in black phosphorus
2015
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Overview
Black phosphorus consists of stacked layers of phosphorene, a two-dimensional semiconductor with promising device characteristics. We report the realization of a widely tunable band gap in few-layer black phosphorus doped with potassium using an in situ surface doping technique. Through band structure measurements and calculations, we demonstrate that a vertical electric field from dopants modulates the band gap, owing to the giant Stark effect, and tunes the material from a moderate-gap semiconductor to a band-inverted semimetal. At the critical field of this band inversion, the material becomes a Dirac semimetal with anisotropic dispersion, linear in armchair and quadratic in zigzag directions. The tunable band structure of black phosphorus may allow great flexibility in design and optimization of electronic and optoelectronic devices.
Publisher
American Association for the Advancement of Science
Subject
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