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Gas Diffusion in Coal Powders is a Multi-rate Process
by
Dentz, Marco
, Mathias, Simon A.
, Liu, Qingquan
in
Civil Engineering
/ Classical and Continuum Physics
/ Coal
/ Diffusion coefficient
/ Diffusion rate
/ Earth and Environmental Science
/ Earth Sciences
/ Gaseous diffusion
/ Geotechnical Engineering & Applied Earth Sciences
/ Hydrogeology
/ Hydrology/Water Resources
/ Industrial Chemistry/Chemical Engineering
/ Initial pressure
/ Oxidation
/ Pressure dependence
/ Probability density functions
/ Surface diffusion
/ Time dependence
2020
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Gas Diffusion in Coal Powders is a Multi-rate Process
by
Dentz, Marco
, Mathias, Simon A.
, Liu, Qingquan
in
Civil Engineering
/ Classical and Continuum Physics
/ Coal
/ Diffusion coefficient
/ Diffusion rate
/ Earth and Environmental Science
/ Earth Sciences
/ Gaseous diffusion
/ Geotechnical Engineering & Applied Earth Sciences
/ Hydrogeology
/ Hydrology/Water Resources
/ Industrial Chemistry/Chemical Engineering
/ Initial pressure
/ Oxidation
/ Pressure dependence
/ Probability density functions
/ Surface diffusion
/ Time dependence
2020
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Do you wish to request the book?
Gas Diffusion in Coal Powders is a Multi-rate Process
by
Dentz, Marco
, Mathias, Simon A.
, Liu, Qingquan
in
Civil Engineering
/ Classical and Continuum Physics
/ Coal
/ Diffusion coefficient
/ Diffusion rate
/ Earth and Environmental Science
/ Earth Sciences
/ Gaseous diffusion
/ Geotechnical Engineering & Applied Earth Sciences
/ Hydrogeology
/ Hydrology/Water Resources
/ Industrial Chemistry/Chemical Engineering
/ Initial pressure
/ Oxidation
/ Pressure dependence
/ Probability density functions
/ Surface diffusion
/ Time dependence
2020
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Journal Article
Gas Diffusion in Coal Powders is a Multi-rate Process
2020
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Overview
Gas migration in coal is strongly controlled by surface diffusion of adsorbed gas within the coal matrix. Surface diffusion coefficients are obtained by inverse modelling of transient gas desorption data from powdered coals. The diffusion coefficient is frequently considered to be dependent on time and initial pressure. In this article, it is shown that the pressure dependence can be eliminated by performing a joint inversion of both the diffusion coefficient and adsorption isotherm. A study of the log–log slope of desorbed gas production rate against time reveals that diffusion within the individual coal particles is a multi-rate process. The application of a power-law probability density function of diffusion rates enables the determination of a single gas diffusion coefficient that is constant in both time and initial pressure.
Publisher
Springer Netherlands,Springer Nature B.V
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