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Synergistic Effect between Piperazine Pyrophosphate and Melamine Polyphosphate in Flame Retardant Coatings for Structural Steel
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Synergistic Effect between Piperazine Pyrophosphate and Melamine Polyphosphate in Flame Retardant Coatings for Structural Steel
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Synergistic Effect between Piperazine Pyrophosphate and Melamine Polyphosphate in Flame Retardant Coatings for Structural Steel
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Journal Article
Synergistic Effect between Piperazine Pyrophosphate and Melamine Polyphosphate in Flame Retardant Coatings for Structural Steel
2022
Overview
Piperazine pyrophosphate (PAPP) combined with melamine polyphosphate (MPP) was adopted to prepare a waterborne fire retardant intumescent coating (IC) for structural steel. Silicone acrylic emulsion was used as binder. In the 2-h torch test, PAPP/MPP-IC coating presented excellent fire resistance performance. The equilibrium temperature at the backside of the steel board decreased to 170 °C with protection of MPP/PAPP-IC, compared with 326 °C of APP/PER/MEL-IC. After 72-h water immersion, MPP/PAPP-IC could still provide sufficient thermal isolation, but APP/PER/MEL-IC failed the test. The water absorption of the MPP/PAPP coating was also reduced. The thermogravimetric analysis measured that the PAPP/MPP-IC had unique initial decomposition temperature of 296 °C and higher residue of 33.8 wt%, which demonstrated better thermal stability and fire retardancy in condensed phase. In addition, Scanning Electron Microscope (SEM) images illustrated that the structure of the carbon layer formed by MPP/PAPP-IC was dense, complete and consistent, indicating the improvement of mechanical strength and thermal isolation of the char. The synergistic effect between piperazine and phosphoric acid groups in MPP/PAPP contributed to the superior flame retardancy. Consequently, MPP/PAPP-IC was much more efficient than the traditional APP/PER/MEL-IC. This work provides a novel way for designing flame retardant coatings for structural steel with excellent comprehensive performance.
