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Compatibilization of Poly(Lactic Acid) (PLA)/Plasticized Cellulose Acetate Extruded Blends through the Addition of Reactively Extruded Comb Copolymers
by
Lazzeri, Andrea
, Rizzo, Sara
, Coltelli, Maria-Beatrice
, Signori, Francesca
, Fiori, Stefano
, Mallegni, Norma
in
Acids
/ Cellulose acetate
/ Chemical synthesis
/ compatibilization effect
/ compounding
/ Copolymers
/ Molecular weight
/ PLA blends
/ Polymerization
/ Polymers
/ reactive extrusion
/ rigid packaging
/ Solvents
/ Viscosity
2021
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Compatibilization of Poly(Lactic Acid) (PLA)/Plasticized Cellulose Acetate Extruded Blends through the Addition of Reactively Extruded Comb Copolymers
by
Lazzeri, Andrea
, Rizzo, Sara
, Coltelli, Maria-Beatrice
, Signori, Francesca
, Fiori, Stefano
, Mallegni, Norma
in
Acids
/ Cellulose acetate
/ Chemical synthesis
/ compatibilization effect
/ compounding
/ Copolymers
/ Molecular weight
/ PLA blends
/ Polymerization
/ Polymers
/ reactive extrusion
/ rigid packaging
/ Solvents
/ Viscosity
2021
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Compatibilization of Poly(Lactic Acid) (PLA)/Plasticized Cellulose Acetate Extruded Blends through the Addition of Reactively Extruded Comb Copolymers
by
Lazzeri, Andrea
, Rizzo, Sara
, Coltelli, Maria-Beatrice
, Signori, Francesca
, Fiori, Stefano
, Mallegni, Norma
in
Acids
/ Cellulose acetate
/ Chemical synthesis
/ compatibilization effect
/ compounding
/ Copolymers
/ Molecular weight
/ PLA blends
/ Polymerization
/ Polymers
/ reactive extrusion
/ rigid packaging
/ Solvents
/ Viscosity
2021
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Compatibilization of Poly(Lactic Acid) (PLA)/Plasticized Cellulose Acetate Extruded Blends through the Addition of Reactively Extruded Comb Copolymers
Journal Article
Compatibilization of Poly(Lactic Acid) (PLA)/Plasticized Cellulose Acetate Extruded Blends through the Addition of Reactively Extruded Comb Copolymers
2021
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Overview
In the perspective of producing a rigid renewable and environmentally friendly rigid packaging material, two comb-like copolymers of cellulose acetate (AC) and oligo(lactic acid) OLA, feeding different percentages of oligo(lactic acid) segments, were prepared by chemical synthesis in solvent or reactive extrusion in the melt, using a diepoxide as the coupling agent and were used as compatibilizers for poly(lactic acid)/plasticized cellulose acetate PLA/pAC blends. The blends were extruded at 230 °C or 197 °C and a similar compatibilizing behavior was observed for the different compatibilizers. The compatibilizer C1 containing 80 wt% of AC and 14 wt% of OLA resulted effective in compatibilization and it was easily obtained by reactive extrusion. Considering these results, different PLAX/pAC(100-X) compounds containing C1 as the compatibilizer were prepared by extrusion at 197 °C and tested in terms of their tensile and impact properties. Reference materials were the uncompatibilized corresponding blend (PLAX/pAC(100-X)) and the blend of PLA, at the same wt%, with C1. Significant increase in Young’s modulus and tensile strength were observed in the compatibilized blends, in dependence of their morphologic features, suggesting the achievement of an improved interfacial adhesion thanks to the occurred compatibilization.
Publisher
MDPI AG,MDPI
Subject
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