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Eco-Friendly Synthesis of Some Thiosemicarbazones and Their Applications as Intermediates for 5-Arylazothiazole Disperse Dyes
by
Gaffer, Hatem
, Khalifa, Mohamed
in
5-arylazothiazoles
/ Coloring Agents - chemical synthesis
/ disperse dyes
/ Dyes
/ fastness properties
/ Green Chemistry Technology
/ phenacyl bromide
/ solid-solid reactions
/ Thiazoles - chemical synthesis
/ thiosemicarbazones
/ Thiosemicarbazones - chemical synthesis
2015
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Eco-Friendly Synthesis of Some Thiosemicarbazones and Their Applications as Intermediates for 5-Arylazothiazole Disperse Dyes
by
Gaffer, Hatem
, Khalifa, Mohamed
in
5-arylazothiazoles
/ Coloring Agents - chemical synthesis
/ disperse dyes
/ Dyes
/ fastness properties
/ Green Chemistry Technology
/ phenacyl bromide
/ solid-solid reactions
/ Thiazoles - chemical synthesis
/ thiosemicarbazones
/ Thiosemicarbazones - chemical synthesis
2015
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Eco-Friendly Synthesis of Some Thiosemicarbazones and Their Applications as Intermediates for 5-Arylazothiazole Disperse Dyes
by
Gaffer, Hatem
, Khalifa, Mohamed
in
5-arylazothiazoles
/ Coloring Agents - chemical synthesis
/ disperse dyes
/ Dyes
/ fastness properties
/ Green Chemistry Technology
/ phenacyl bromide
/ solid-solid reactions
/ Thiazoles - chemical synthesis
/ thiosemicarbazones
/ Thiosemicarbazones - chemical synthesis
2015
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Eco-Friendly Synthesis of Some Thiosemicarbazones and Their Applications as Intermediates for 5-Arylazothiazole Disperse Dyes
Journal Article
Eco-Friendly Synthesis of Some Thiosemicarbazones and Their Applications as Intermediates for 5-Arylazothiazole Disperse Dyes
2015
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Overview
The solid-solid reactions of thiosemicarbazide with 4-formylantipyrine, 2-acetylpyrrole and camphor were performed to afford the thiosemicarbazones 1–3 which underwent hetero-cyclization with phenacyl bromide to furnish the corresponding thiazole derivatives 4–6. The yields of the reactions are quantitative in all cases and the products do not require further purification. A series of 5-arylazo-2-(substituted ylidene-hydrazinyl)-thiazole dyes 7–9 was then prepared by diazo coupling of thiazole derivatives 4–6 with several diazonium chlorides. The synthesized dyes were applied as disperse dyes for dyeing polyester fabric. The dyed fabrics exhibit good washing, perspiration, sublimation and light fastness properties, with little variation in their moderate to good rubbing fastness.
Publisher
MDPI AG,MDPI
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