Journal Article

Characterization of Polyurethane Shape Memory Polymer and Determination of Shape Fixity and Shape Recovery in Subsequent Thermomechanical Cycles

Staszczak, Maria, Pieczyska, Elżbieta Alicja, Golasiński, Karol Marek, Matsui, Ryosuke, Urbański, Leszek, Nabavian Kalat, Mana, Takeda, Kohei

2022

Overview

Multifunctional polyurethane shape memory polymers (PU-SMPs) have been of increasing interest in various applications. Here we report structure characterization, detailed methodology, and obtained results on the identification of functional properties of a thermoset PU-SMP (MP4510) with glass transition temperature of 45 °C. The stable, chemically crosslinked network of this thermoset PU-SMP results in excellent shape memory behavior. Moreover, the proximity of the activation temperature range of this smart polymer to room and body temperature enables the PU-SMP to be used in more critical industrial applications, namely fast-response actuators. The thermomechanical behavior of a shape memory polymer determines the engineering applications of the material. Therefore, investigation of the shape memory behavior of this class of commercial PU-SMP is of particular importance. The conducted structural characterization confirms its shape memory properties. The shape fixity and shape recovery properties were determined by a modified experimental approach, considering the polymer’s sensitivity to external conditions, i.e., the temperature and humidity variations. Three thermomechanical cycles were considered and the methodology used is described in detail. The obtained shape fixity ratio of the PU-SMP was approximately 98% and did not change significantly in the subsequent cycles of the thermomechanical loading due to the stability of chemical crosslinks in the thermoset materials structure. The shape recovery was found to be approximately 90% in the first cycle and reached a value higher than 99% in the third cycle. The results confirm the effect of the thermomechanical training on the improvement of the PU-SMP shape recovery after the first thermomechanical cycle as well as the effect of thermoset material stability on the repeatability of the shape memory parameters quantities.

• Publisher: MDPI AG,MDPI
• Subject: Accuracy / Actuators / Body temperature / Crosslinking / Glass transition temperature / Industrial applications / Investigations / Materials recovery / Polymer industry / Polymers / Polyurethane resins / Polyurethanes / Scanning electron microscopy / Shape memory / Structural analysis / Thermomechanical properties